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    Polymerization catalyst for polyesters, polyesters produced with the same and process for producing polyesters
    1.
    发明授权
    Polymerization catalyst for polyesters, polyesters produced with the same and process for producing polyesters 有权
    用于聚酯的聚合催化剂，用其制备的聚酯和用于生产聚酯的方法

    公开(公告)号：US07199212B2

    公开(公告)日：2007-04-03

    申请号：US10169491

    申请日：2000-12-25

    申请人： Takahiro Nakajima ,  Kenichi Tsukamoto ,  Shoichi Gyobu ,  Maki Sato

    发明人： Takahiro Nakajima ,  Kenichi Tsukamoto ,  Shoichi Gyobu ,  Maki Sato

    IPC分类号： C08G63/78 ,  C08F4/00

    CPC分类号： C08G63/84 ,  C08G63/83 ,  C08G63/863

    摘要： A novel polymerization catalyst for polyesters, which does not contain any germanium or antimony compound as the main component; polyesters produced with the catalyst; and a process for producing polyesters. This polymerization catalyst is excellent in catalytic activity, little causes thermal degradation of polyesters in melt molding even when neither deactivated nor removed, and can give thermally stable polyesters which little generate foreign matter and are excellent in transparency and color. The polymerization catalyst is one which contains as the first metal-containing component at least one member selected from the group consisting of aluminum and aluminum compounds and which gives polyethylene terephthalate (PET) having a thermal stability parameter (TS) satisfying the relationship: (1) TS

    摘要翻译： 用于聚酯的新型聚合催化剂，其不含有锗或锑化合物作为主要成分; 用催化剂生产的聚酯; 和聚酯的制造方法。 该聚合催化剂的催化活性优异，即使既不失活也不被除去，熔融成型中聚酯的热降解很少，并且可以得到几乎不产生异物并且透明性和颜色优异的热稳定性聚酯。 聚合催化剂是含有选自铝和铝化合物中的至少一种元素作为第一含金属成分的聚合催化剂，并且其具有满足以下关系的热稳定性参数（TS）的聚对苯二甲酸乙二醇酯（PET）：（1 ）TS <0.3。

    Heat-shrinkable polyester films
    3.
    发明授权
    Heat-shrinkable polyester films 有权
    热收缩聚酯薄膜

    公开(公告)号：US06465063B1

    公开(公告)日：2002-10-15

    申请号：US09967963

    申请日：2001-10-02

    申请人： Satoshi Hayakawa ,  Maki Sato ,  Shoichi Gyobu ,  Norimi Tabota ,  Katsuya Ito

    发明人： Satoshi Hayakawa ,  Maki Sato ,  Shoichi Gyobu ,  Norimi Tabota ,  Katsuya Ito

    IPC分类号： B23B2700

    CPC分类号： C08J5/18 ,  B29C55/08 ,  B29K2067/00 ,  B29K2995/0049 ,  C08J2367/02 ,  Y10T428/1328 ,  Y10T428/1331 ,  Y10T428/31786

    摘要： Heat-shrinkable polyester films, each having a heat shrinkability of 40% or higher in the main shrinkage direction of the film after treatment in hot water at 80° C. for 10 seconds, the change of heat shrinkability in the main shrinkage direction of the film after treatment in hot water at 55-75° C. for 10 seconds before and after the film is left under an atmosphere at 40° C. for 160 hours being 15% or lower, exhibit beautiful shrinkage finish in appearance involving only rare occurrence of shrinkage spots, wrinkles, strains, folding and other defects during shrinkage in the step of shrinking with hot air, and in particular, exhibit a quite small lowering in shrinkage finish after a lapse of time for storage and have low spontaneous shrinkability; therefore, these films are suitably used for applications such as labels and cap seals.

    摘要翻译： 在80℃的热水中处理10秒后，膜的主收缩方向的热收缩率为40％以上的热收缩性聚酯膜，在主收缩方向上的热收缩率的变化为 薄膜在热水中在55-75℃下处理10秒，该膜在40℃的气氛下放置160小时，为15％或更低，在外观上仅显现出罕见的收缩率 在用热空气收缩的步骤中收缩期间的收缩斑点，皱纹，应变，折叠等缺陷，特别是在经过保存时间后，收缩率的降低显着降低，自发收缩性低; 因此，这些膜适用于诸如标签和盖子密封件的应用。

    Organophosphorous composition, method of producing organophosphorous compound, polyester composition and method of producing the same
    5.
    发明授权
    Organophosphorous composition, method of producing organophosphorous compound, polyester composition and method of producing the same 有权
    有机磷组合物，生产有机磷化合物的方法，聚酯组合物及其制备方法

    公开(公告)号：US06245880B1

    公开(公告)日：2001-06-12

    申请号：US09679466

    申请日：2000-10-04

    申请人： Hideo Takeuchi ,  Maki Sato ,  Shoichi Gyobu

    发明人： Hideo Takeuchi ,  Maki Sato ,  Shoichi Gyobu

    IPC分类号： C08G6368

    CPC分类号： C08K5/5393 ,  C07F9/657172 ,  C07F9/65719 ,  C08K5/5313 ,  C08L67/02

    摘要： A polyester having a good color tone can be obtained by using, as an ester-forming component, a compound derived from an organophosphorous composition comprising an organophosphorous compound represented by the general formula (1): wherein R1 and R2 represent an organic group or a halogen atom, and m and n represent an integer of 0 to 4, provided that R1 and R2 may be the same or different when m or n is an integer of 2 to 4, and a divalent metallic compound in an amount more than 30 ppm and not more than 2300 ppm in terms of a divalent metal based on the organophosphorous compound.

    摘要翻译： 通过使用衍生自由通式（1）表示的有机亚磷化合物的有机亚磷组合物衍生的化合物作为酯形成成分可以得到具有良好色调的聚酯：其中R1和R2表示有机基团或 卤素原子，m和n表示0〜4的整数，条件是当m或n为2〜4的整数时，R 1和R 2可以相同或不同，二价金属化合物的含量大于30ppm 以有机磷化合物为基准的二价金属换算为2300ppm以下。

    POLYESTER POLYMERIZATION CATALYST, POLYESTER PRODUCED BY USING THE SAME, AND A PROCESS FOR PRODUCING POLYESTER
    7.
    发明申请
    POLYESTER POLYMERIZATION CATALYST, POLYESTER PRODUCED BY USING THE SAME, AND A PROCESS FOR PRODUCING POLYESTER 有权
    聚酯聚合催化剂，使用它们生产的聚酯，以及生产聚酯的方法

    公开(公告)号：US20070149757A1

    公开(公告)日：2007-06-28

    申请号：US11677901

    申请日：2007-02-22

    申请人： Takahiro NAKAJIMA ,  Ken-ichi Tsukamoto ,  Shoichi Gyobu ,  Mitsuyoshi Kuwata

    发明人： Takahiro NAKAJIMA ,  Ken-ichi Tsukamoto ,  Shoichi Gyobu ,  Mitsuyoshi Kuwata

    IPC分类号： C08G63/00

    CPC分类号： C08G63/87 ,  C08G63/82 ,  C08G63/84

    摘要： The present invention provides processes for producing polyester. In one of the embodiments, the invention provides a process for producing polyester, comprising adding a catalyst in a polycondensation reaction, esterification reaction or transesterification reaction between components comprising at least a polyfunctional alcohol and at least a polyfunctional carboxylic acid or ester-forming derivative of a polyfunctional carboxylic acid to produce the polyester; and obtaining the polyester, wherein the polymerization catalyst comprises an aluminum substance and a phosphorus compound, wherein the aluminum substance is selected from the group consisting of aluminum hydroxide and aluminum alkoxides, and wherein the phosphorus compound has an aromatic ring structure.

    摘要翻译： 本发明提供生产聚酯的方法。 在其中一个实施方案中，本发明提供了一种生产聚酯的方法，包括在缩聚反应中加入催化剂，在至少包含多官能醇和至少多官能羧酸或成酯衍生物的成分之间进行酯化反应或酯交换反应 多官能羧酸以制备聚酯; 得到聚酯，其中聚合催化剂包含铝物质和磷化合物，其中铝物质选自氢氧化铝和烷氧基铝，其中磷化合物具有芳环结构。

    Polyester polymerization catalyst, polyester produced by using the same, and a process for producing polyester
    9.
    发明授权
    Polyester polymerization catalyst, polyester produced by using the same, and a process for producing polyester 有权
    聚酯聚合催化剂，使用该聚酯制成的聚酯，以及聚酯的制造方法

    公开(公告)号：US08293862B2

    公开(公告)日：2012-10-23

    申请号：US11677901

    申请日：2007-02-22

    申请人： Takahiro Nakajima ,  Ken-ichi Tsukamoto ,  Shoichi Gyobu ,  Mitsuyoshi Kuwata

    发明人： Takahiro Nakajima ,  Ken-ichi Tsukamoto ,  Shoichi Gyobu ,  Mitsuyoshi Kuwata

    IPC分类号： C08G63/84 ,  C08G63/86 ,  B01J31/18 ,  B01J31/00

    CPC分类号： C08G63/87 ,  C08G63/82 ,  C08G63/84

    摘要： The present invention provides processes for producing polyester. In one of the embodiments, the invention provides a process for producing polyester, comprising adding a catalyst in a polycondensation reaction, esterification reaction or transesterification reaction between components comprising at least a polyfunctional alcohol and at least a polyfunctional carboxylic acid or ester-forming derivative of a polyfunctional carboxylic acid to produce the polyester; and obtaining the polyester, wherein the polymerization catalyst comprises an aluminum substance and a phosphorus compound, wherein the aluminum substance is selected from the group consisting of aluminum hydroxide and aluminum alkoxides, and wherein the phosphorus compound has an aromatic ring structure.

    摘要翻译： 本发明提供生产聚酯的方法。 在其中一个实施方案中，本发明提供了一种生产聚酯的方法，包括在缩聚反应中加入催化剂，在至少包含多官能醇和至少多官能羧酸或成酯衍生物的成分之间进行酯化反应或酯交换反应 多官能羧酸以制备聚酯; 得到聚酯，其中聚合催化剂包含铝物质和磷化合物，其中铝物质选自氢氧化铝和烷氧基铝，其中磷化合物具有芳环结构。