摘要:
A negative electrode for use in a secondary battery is disclosed, comprising milled carbon fibers derived from mesophase pitch wherein the milled carbon fibers each has a fiber cut surface and a fiber axis intersecting with each other at cross angles, the smaller one thereof being at least 65.degree. on the average. This negative electrode does not suffer from property deterioration, irrespective of multiple repetitions of charge and discharge, from which a nonaqueous-electrolyte-loaded lithic secondary battery having excellent cycle characteristics can be fabricated.
摘要:
A negative electrode for use in a secondary battery which comprises milled graphite fibers derived from mesophase pitch each having circumferential, upper end and lower end faces, the milled graphite fibers each being composed of graphite layers having therebetween voids as inlets and outlets for lithium ions, all of the circumferential, upper end and lower end faces having openings of the voids between the graphite layers, which serve as inlets or outlets for lithium ions. This negative electrode for use in a secondary battery can be utilized to provide a lithium secondary battery of nonaqueous electrolyte which has large charge and discharge capacities and which permits setting the current density at charge or discharge high.
摘要:
The present invention provides a nonaqueous electrolyte secondary battery, comprising an electrode group including a positive electrode, a negative electrode including a material for absorbing-desorbing lithium ions, and a separator arranged between the positive electrode and the negative electrode, a nonaqueous electrolyte impregnated in the electrode group and including a nonaqueous solvent and a lithium salt dissolved in the nonaqueous solvent, and a jacket for housing the electrode group and having a thickness of 0.3 mm or less, wherein the nonaqueous solvent γ-butyrolactone in an amount larger than 50% by volume and not larger than 95% by volume based on the total amount of the nonaqueous solvent.
摘要:
The present invention provides a nonaqueous electrolyte secondary battery, comprising an electrode group including a positive electrode, a negative electrode including a material for absorbing-desorbing lithium ions, and a separator arranged between the positive electrode and the negative electrode, a nonaqueous electrolyte impregnated in the electrode group and including a nonaqueous solvent and a lithium salt dissolved in the nonaqueous solvent, and a jacket for housing the electrode group and having a thickness of 0.3 mm or less, wherein the nonaqueous solvent &ggr;-butyrolactone in an amount larger than 50% by volume and not larger than 95% by volume based on the total amount of the nonaqueous solvent.
摘要:
A lithium secondary battery having a high capacity and excellent in charge-discharge efficiency, cycle life, flatness of a discharge voltage, and rapid charge-discharge cycle characteristics is disclosed. This lithium secondary battery includes a positive electrode housed in a case, a negative electrode housed in the case and containing a carbonaceous material which has an exothermic peak at 700.degree. C. or more when measured by a differential thermal analysis and an intensity ratio P.sub.101 /P.sub.100 of a (101) diffraction peak P.sub.101 to a (100) diffraction peak P100 of a graphite structure, obtained by X-ray diffraction analysis, of 0.7 to 2.2, and absorbs and desorbs lithium ions, a separator housed in the case so as to be arranged between the positive and negative electrodes, and a nonaqueous electrolyte contained in the case.
摘要:
There is proposed a non-aqueous electrolyte secondary battery having an electrode assembly which is impregnated with a non-aqueous electrolyte solution, wherein the battery can be made thin while maintaining improved capacity, large-current characteristics and cycle life.The non-aqueous electrolyte secondary battery comprises a positive electrode, a negative electrode, a separator and a non-aqueous electrolyte solution. The production process of the battery comprises steps of preparing an electrode assembly by interposing a separator between a positive electrode and a negative electrode, impregnating the electrode assembly with an organic solvent which can dissolve the binder of the positive- and/or negative electrodes, bonding the positive electrode and the separator together and bonding the negative electrode and the separator together by drying the electrode assembly, and impregnating the electrode assembly with a non-aqueous electrolyte solution.
摘要:
There is proposed a non-aqueous electrolyte secondary battery having an electrode assembly which is impregnated with a non-aqueous electrolyte solution, wherein the battery can be made thin while maintaining improved capacity, large-current characteristics and cycle life. The non-aqueous electrolyte secondary battery comprises a positive electrode, a negative electrode, a separator and a non-aqueous electrolyte solution. The production process of the battery comprises steps of preparing an electrode assembly by interposing a separator between a positive electrode and a negative electrode, impregnating the electrode assembly with an organic solvent which can dissolve the binder of the positive- and/or negative electrodes, bonding the positive electrode and the separator together and bonding the negative electrode and the separator together by drying the electrode assembly, and impregnating the electrode assembly with a non-aqueous electrolyte solution.
摘要:
The present invention provides a nonaqueoxus electrolyte secondary battery, comprising an electrode group including a positive electrode, a negative electrode including a material for absorbing-desorbing lithium ions, and a separator arranged between the positive electrode and the negative electrode, a nonaqueous electrolyte impregnated in the electrode group and including a nonaqueous solvent and a lithium salt dissolved in the nonaqueous solvent, and a jacket for housing the electrode group and having a thickness of 0.3 mm or less, wherein the nonaqueous solvent γ-butyrolactone in an amount larger than 50% by volume and not larger than 95% by volume based on the total amount of the nonaqueous solvent.
摘要:
Provided is a nonaqueous electrolyte secondary battery, comprising an electrode group including a positive electrode, a negative electrode, and a porous separator interposed between the positive electrode and the negative electrode, the pores of the porous separator being closed when heated, a nonaqueous electrolyte held by the porous separator, and a jacket formed of a sheet including a thermoplastic resin layer forming at least a portion of the inner surface, having the electrode group housed therein, and having mutually facing regions of the thermoplastic resin layer heat-sealed to each other to seal the electrode group therein, wherein the positive electrode, the negative electrode and the separator are made integral, and the thermoplastic resin layer has a melting point higher than a pore-closing initiating temperature of the porous separator at which the pores of the separator begin to be closed.
摘要:
The present invention provides a nonaqueous electrolyte secondary battery, comprising a jacket having a wall thickness not larger than 0.25 mm, a positive electrode housed in the jacket and containing a positive electrode active material, a negative electrode housed in the jacket and containing a negative electrode active material, and a nonaqueous electrolyte housed in the jacket, wherein the positive electrode active material comprises at least one kind of oxide selected from the group consisting of an oxide containing an element M, Li and Ni and an oxide containing an element M, Li, Ni and Co, the element M being at least one element selected from the group consisting of Al, B, Sn and Nb, and the pH of the positive electrode active material falls within a range of between 10 and 12.