公开(公告)号：US4968725A

公开(公告)日：1990-11-06

申请号：US221549

申请日：1988-07-20

申请人： Nobuhiro Mukai ,  Hitoshi Ige ,  Takayuki Makino ,  Junko Atarashi

发明人： Nobuhiro Mukai ,  Hitoshi Ige ,  Takayuki Makino ,  Junko Atarashi

IPC分类号： A61K6/00 ,  A61K6/09

CPC分类号： A61K6/0023

摘要： Disclosed are dental adhesive compositions consisting essentially of(a) at least one urethane prepolymer containing one or more isocyanate groups, or a blend of the urethane prepolymer and an inert diluent;(b) at least one radical-polymerizable unsaturated monomer;(c) a photopolymerization initiator;and, if desired,(d) a polymerizable phosphoric ester compound having a specific structure.These dental adhesive compositions can be used to bond a restorative material to dentin without requiring any troublesome pretreatment with an etching agent such as phosphoric acid, and can exhibit bonding power sufficient for practical purposes.

公开(公告)号：US5151479A

公开(公告)日：1992-09-29

申请号：US511742

申请日：1990-04-20

申请人： Nobuhiro Mukai ,  Hitoshi Ige ,  Takayuki Makino ,  Junko Atarashi

发明人： Nobuhiro Mukai ,  Hitoshi Ige ,  Takayuki Makino ,  Junko Atarashi

IPC分类号： A61K6/00 ,  A61K6/09

CPC分类号： A61K6/0023

摘要： This invention provides dental adhesive compositions consisting essentially of(a) an aliphatic amine salt of a polymerizable phosphoric ester, as represented by the formula ##STR1## where R and R' are specific radicals; (b) at least one radical-polymerizable unsaturated monomer; and(c) a radical polymerization initiator. These compositions are useful in bonding living dental tissue restoration materials to living tooth tissues, particularly to dentin.

公开(公告)号：US5008300A

公开(公告)日：1991-04-16

申请号：US405891

申请日：1989-09-11

申请人： Takayuki Makino ,  Nobuhiro Mukai ,  Hitoshi Ige

发明人： Takayuki Makino ,  Nobuhiro Mukai ,  Hitoshi Ige

IPC分类号： A61C13/225 ,  A61K6/00 ,  A61K6/09

CPC分类号： A61K6/0023 ,  Y10S522/908

摘要： A visible light ray-curable monomeric composition for fastening loose teeth, comprising: a filler component consisting of fine, solid particles having an average size of 0.01 to 100 .mu.m and in an amount of 40% to 85% based on the weight of the total weight of the composition; a polyfunctional monomer component consisting of a radical-polymerizable, polyfunctional monomer; a monofunctional monomer consisting of a radical-polymerizable, monofunctional monomer; and a photopolymerization initiator; having a viscosity of 1,000 to 500,000 cps at a temperature of 25.degree. C., and contained in a light-shielded container.

公开(公告)号：US4983644A

公开(公告)日：1991-01-08

申请号：US340804

申请日：1989-04-20

申请人： Nobuhiro Mukai ,  Hitoshi Ige ,  Takayuki Makino ,  Junko Atarashi

发明人： Nobuhiro Mukai ,  Hitoshi Ige ,  Takayuki Makino ,  Junko Atarashi

IPC分类号： A61C5/08 ,  A61K6/00 ,  A61K6/09 ,  C08F2/46 ,  C08G18/10 ,  C08G18/67 ,  C08G18/77 ,  C08G18/81 ,  C09J175/00 ,  C09J175/04

CPC分类号： C08G18/81 ,  A61K6/0023 ,  A61K6/09 ,  C08G18/10

摘要： A dental adhesive composition containing as major components:(a) at least one isocyanate-group-containing urethane prepolymer,(b) at least one isocyanate-group-containing silane compound,(c) at least one radical-polymerizable unsaturated monomer, and(d) at least one initiator selected from the group consisting of redox polymerization initiators and photopolymerization initiatorsis disclosed.This composition is excellent in bonding properties when it is used to bond a living dental tissue with a restoring material such as a metal, organic polymer, and ceramic. Also, this adhesive composition does not require a troublesome pretreatment of the restoring material with an etching agent such as phosphoric acid when the restorating material is required to bond to the living tissue.

公开(公告)号：US4762863A

公开(公告)日：1988-08-09

申请号：US84096

申请日：1987-08-11

申请人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

发明人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

IPC分类号： A61K6/083 ,  A61K6/09 ,  A61K6/08

CPC分类号： A61K6/09 ,  A61K6/083

摘要： Disclosed is a photopolymerizable dental composition consisting essentially of (A) a composite filler obtained by non-catalytically polymerizing a carboxylic acid monomer with a vinyl monomer in a polymerization system having an inorganic compound dispersed therein; (B) a monomer mixture composed of 2,2-bis[4-(methacryloxyethoxy)phenyl]propane, at least one hexafunctional urethane methacrylate having an isocyanuric acid skeleton, and an ethylenic vinyl monomer diluent; and (C) a photopolymerization initiator. The composite resin obtained by curing this dental composition has high mechanical strength and good water resistance.

公开(公告)号：US5155252A

公开(公告)日：1992-10-13

申请号：US564878

申请日：1990-08-09

申请人： Naoki Yamamoto ,  Nobuhiro Mukai ,  Hitoshi Ige ,  Masao Kobayashi ,  Junko Atarashi

发明人： Naoki Yamamoto ,  Nobuhiro Mukai ,  Hitoshi Ige ,  Masao Kobayashi ,  Junko Atarashi

IPC分类号： A61K6/083 ,  C07C69/54

CPC分类号： C07C69/54 ,  A61K6/083

摘要： A material for dentistry having a low odor, a low stimulation and a proper dough stage time is here disclosed which is prepared by blending a monomer selected from the group consisting of (meth)acrylate compounds represented by the general formula ##STR1## R.sub.1 is a hydrogen atom or a methyl group, each of R.sub.3, R.sub.6 and R.sub.10 is an alkyl group, and each of R.sub.2, R.sub.5, R.sub.8 and R.sub.9 is an alkylene group) and (meth)acrylate dimers.

公开(公告)号：US4783501A

公开(公告)日：1988-11-08

申请号：US898496

申请日：1986-08-21

申请人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

发明人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

IPC分类号： C08F2/44 ,  C08F292/00 ,  C08K3/02

CPC分类号： C08F292/00

摘要： A method for preparing a polymeric composition in which an inorganic compound is firmly consolidated in an organic polymer, which comprises polymerizing at least one radical polymerizable vinyl monomer in an aqueous medium polymerization system comprising an inorganic compound dispersed in the presence of an organic acid monomer or organic acid salt monomer, by using a radical polymerization initiator.

摘要翻译： 一种制备聚合物组合物的方法，其中无机化合物牢固地固结在有机聚合物中，其包括在包含在有机酸单体存在下分散的无机化合物的水性介质聚合体系中聚合至少一种可自由基聚合的乙烯基单体，或 有机酸盐单体，通过使用自由基聚合引发剂。

公开(公告)号：US5296513A

公开(公告)日：1994-03-22

申请号：US915880

申请日：1992-07-20

申请人： Hitoshi Ige ,  Nobuhiro Mukai ,  Naoto Ohsuga

发明人： Hitoshi Ige ,  Nobuhiro Mukai ,  Naoto Ohsuga

IPC分类号： A61K6/083 ,  A61K6/08 ,  C08F20/10

CPC分类号： A61K6/083

摘要： Disclosed is a process for producing dental polymeric shaped articles resistant to the adhesion of plaque which comprises the steps of shaping and curing a dental composition containing a monomer having at least one (meth)acryloyloxy group, and bringing the cured product into contact with a halogen or a halogen compound. Also disclosed is a dental composition comprising a monomer having at least one (meth)acryloyloxy group and a polymerization initiator, which is characterized by having added thereto at least one of a halogen and a halogen compound. When cured, this dental composition produces dental polymeric shaped articles resistant to the adhesion of plaque.

摘要翻译： 本发明公开了一种抗粘附斑块的牙科用聚合物制品的制造方法，该方法包括以下步骤：使包含具有至少一个（甲基）丙烯酰氧基的单体的牙科用组合物成形和固化，并使固化产物与卤素接触 或卤素化合物。 还公开了包含具有至少一个（甲基）丙烯酰氧基的单体和聚合引发剂的牙科用组合物，其特征在于向其中加入至少一种卤素和卤素化合物。 当固化时，该牙科组合物产生耐牙菌斑粘附的牙科聚合物形状制品。

公开(公告)号：US4910251A

公开(公告)日：1990-03-20

申请号：US246737

申请日：1988-09-20

申请人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

发明人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

IPC分类号： C08F2/44 ,  C08F292/00

CPC分类号： C08F292/00

摘要： A method for preparing a polymeric composition in which an inorganic compound is firmly consolidated in an organic polymer, which comprises polymerizing at least one radical polymerizable vinyl monomer in an aqueous medium polymerization system comprising an inorganic compound dispersed in the presence of an organic acid monomer or organic acid salt monomer, by using a radical polymerization initiator.

公开(公告)号：US5182332A

公开(公告)日：1993-01-26

申请号：US561178

申请日：1990-08-01

申请人： Naoki Yamamoto ,  Nobuhiro Mukai ,  Hitoshi Ige ,  Junko Atarashi

发明人： Naoki Yamamoto ,  Nobuhiro Mukai ,  Hitoshi Ige ,  Junko Atarashi

IPC分类号： A61K6/083 ,  A61K6/09 ,  A61K6/093 ,  C08F285/00

CPC分类号： C08F285/00 ,  A61K6/083 ,  A61K6/09 ,  Y10S522/908 ,  Y10S525/937

摘要： Disclosed is a dental composition comprising a (meth)acrylic ester compound as the principal component and containing a polymerization initiator, which is characterized by having incorporated therein a grafted rubber obtained by polymerizing at least one ethylenically unsaturated monomer in the presence of a rubber. This dental composition can be cured to yield a cured product having excellent strength properties and, therefore, is particularly useful in applications such as a molar restoration material and a denture base resin.