公开(公告)号：US20070048616A1

公开(公告)日：2007-03-01

申请号：US11376092

申请日：2006-03-16

申请人： Takefumi Okumura ,  Shin Nishimura ,  Norio Iwayasu ,  Kazushige Kohno ,  Shoichi Yokoyama ,  Masato Mizutani ,  Tetsuya Itoh

发明人： Takefumi Okumura ,  Shin Nishimura ,  Norio Iwayasu ,  Kazushige Kohno ,  Shoichi Yokoyama ,  Masato Mizutani ,  Tetsuya Itoh

IPC分类号： H01M10/40

CPC分类号： H01M10/0565 ,  H01M2300/0085

摘要： The present invention provides a high-power secondary battery using a gel electrolyte comprising a polymer matrix, which is obtained by polymerizing a polymerizable functional group-terminated borate represented by formula (1) or a mixture composed of a borate represented by formula (2) and a borate represented by formula (3), an electrolytic salt, and further a nonaqueous solvent: wherein Z1, Z2, and Z3 each independently represent a polymerizable functional group or a hydrocarbon group having 1 to 10 carbon atoms, provided that an average mole of the hydrocarbon group having 1 to 10 carbon atoms is 1.0 to 2.5 per the three groups of Z1, Z2 and Z3; AO represents an oxyalkylene group having 2 to 4 carbon atoms; 1, m, and n are each independently an average number of moles of the oxyalkylene group added of 0 to 100, provided that 1+m+n is 1 to 300; and B represents a boron atom; and wherein Z4, Z5, and Z6 each independently represent a polymerizable functional group; AO represents an oxyalkylene group having 2 to 4 carbon atoms; p, q, r, α, β, and γ are each independently an average number of moles of the oxyalkylene group added of 0 to 100, provided that p+q+r is 1 to 300, and α+β+γ is 1 to 300; X1, X2, and X3 each independently represent a hydrocarbon group having 1 to 10 carbon atoms; and B represents a boron atom.

摘要翻译： 本发明提供一种使用包含聚合物基质的凝胶电解质的高功率二次电池，该聚合物基质通过聚合由式（1）表示的聚合性官能团封端的硼酸盐或由式（2）表示的硼酸盐组成的混合物而获得， 和由式（3）表示的硼酸盐，电解质盐，以及非水溶剂：其中Z 1，Z 2，Z 3和Z 3 >各自独立地表示可聚合官能团或具有1-10个碳原子的烃基，条件是每1-3个Z 1的碳原子数为1〜10的烃基的平均摩尔数为1.0〜2.5， SUP>，Z 2和Z 3; AO表示碳原子数2〜4的氧化烯基， 1，m和n各自独立地为0〜100的氧化烯基的平均摩尔数，条件是1 + m + n为1〜300。 B表示硼原子; 并且其中Z 4，Z 5和Z 6各自独立地表示可聚合官能团; AO表示碳原子数2〜4的氧化烯基， p，q，r，α，β和γ各自独立地为0〜100的氧化烯基的平均摩尔数，条件是p + q + r为1〜300，α+β+γ为1 至300; X 1，X 2和X 3各自独立地表示具有1至10个碳原子的烃基; B表示硼原子。

公开(公告)号：US08192871B2

公开(公告)日：2012-06-05

申请号：US12388580

申请日：2009-02-19

申请人： Hiroshi Haruna ,  Kazushige Kohno ,  Eiji Seki ,  Yoshiaki Kumashiro

发明人： Hiroshi Haruna ,  Kazushige Kohno ,  Eiji Seki ,  Yoshiaki Kumashiro

IPC分类号： H01M4/13

CPC分类号： H01M10/0525 ,  H01M10/0569 ,  H01M10/446 ,  H01M2300/004 ,  Y10T29/4911

摘要： To provide a lithium secondary battery which suppresses a decrease in the charge and discharge efficiency during a battery storage test and which is excellent in maintaining the battery capacity after the storage test. There are disclosed a nonaqueous lithium battery, comprising: a positive electrode active material comprising a lithium-containing oxide capable of inserting and detaching lithium ions; a negative electrode active material comprising a carbon material capable of inserting and detaching lithium ions; and an electrolytic solution containing a lithium ion, wherein the surface of the negative electrode active material after initializing charging is coated with a compound derived from vinylene carbonate, and wherein a weight power density of the lithium battery is no less than 100 Wh/kg, and a method of producing a nonaqueous lithium battery comprising a step of sealing a positive electrode active material, a negative electrode active material, and a nonaqueous electrolytic solution using a sealed container, wherein a predetermined amount of vinylene carbonate is added into the nonaqueous electrolytic solution, and the initializing charging is carried out to form a coating on the surface of the negative electrode active material, the coating being derived from the vinylene carbonate.

摘要翻译： 提供一种锂二次电池，其抑制电池存储试验期间的充放电效率的降低，并且在保存试验后保持电池容量优异。 公开了一种非水锂电池，其包括：正极活性物质，其包含能够插入和分离锂离子的含锂氧化物; 包含能够插入和分离锂离子的碳材料的负极活性材料; 以及含有锂离子的电解液，其中，初始化充电后的负极活性物质的表面涂布有碳酸亚乙烯酯衍生的化合物，其中锂电池的重量功率密度为100Wh / kg以上， 以及一种制造非水锂电池的方法，包括使用密封容器密封正极活性物质，负极活性物质和非水电解液的步骤，其中将预定量的碳酸亚乙烯酯加入到非水电解液 ，并进行初始化充电以在负极活性材料的表面上形成涂层，该涂层源自碳酸亚乙烯酯。

公开(公告)号：US20090220862A1

公开(公告)日：2009-09-03

申请号：US12372751

申请日：2009-02-18

申请人： Tatsuya Toyama ,  Kazushige Kohno

发明人： Tatsuya Toyama ,  Kazushige Kohno

IPC分类号： H01M4/50

CPC分类号： H01M4/131 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  Y02T10/7011

摘要： To provide a lithium secondary battery excellent in the life characteristic and the power density. A lithium secondary battery, comprising: a positive electrode capable of intercalating and deintercalating lithium; and an negative electrode capable of intercalating and deintercalating lithium, wherein the positive electrode contains a manganese-containing positive electrode active material of a spinel structure and an oxide that coats the surface of this positive electrode active material, wherein the oxide contains a metallic element, wherein the metallic element forms a solid solution with the positive electrode active material, and wherein the atomic concentration of the metallic element is approximately 0 at depths of from 50 to 100 nm from an external surface of the negative electrode.

摘要翻译： 提供寿命特性和功率密度优异的锂二次电池。 一种锂二次电池，包括：能够插入和脱嵌锂的正极; 以及能够嵌入和脱嵌锂的负极，其中所述正极含有尖晶石结构的含锰正极活性物质和涂覆所述正极活性物质的表面的氧化物，其中所述氧化物含有金属元素， 其中所述金属元素与所述正极活性物质形成固溶体，并且其中所述金属元素的原子浓度在距所述负极的外表面50至100nm的深度处大约为0。

公开(公告)号：US08883358B2

公开(公告)日：2014-11-11

申请号：US13807028

申请日：2010-07-02

申请人： Shin Takahashi ,  Kazuhiro Yoshida ,  Kazushige Kohno

发明人： Shin Takahashi ,  Kazuhiro Yoshida ,  Kazushige Kohno

IPC分类号： H01M12/08 ,  H01M4/90 ,  H01M10/052 ,  H01M4/38 ,  H01M4/86

CPC分类号： H01M12/08 ,  H01M4/38 ,  H01M4/382 ,  H01M4/8615 ,  H01M4/8647 ,  H01M4/8668 ,  H01M4/90 ,  H01M4/9016 ,  H01M10/052 ,  H01M2004/8689 ,  Y02E60/128 ,  Y02E60/50 ,  Y02T10/7011

摘要： An object of the invention is to reduce the charging overvoltage by using a positive electrode member which does not contain a carbon material that causes the generation of lithium carbonate (Li2CO3), and which comprises a metal porous material, thereby suppressing the formation of lithium carbonate (Li2CO3). The metal air secondary battery of the invention is characterized by having a negative electrode member which has metal ions occluded therein and emits metal ions, a positive electrode member which ionizes oxygen, and a separator which is impregnated with an electrolyte and disposed between the negative electrode member and the positive electrode member, wherein the carbon weight in the total weight of a carrier, a catalyst, and a binder constituting the positive electrode member is 50% or less.

摘要翻译： 本发明的目的是通过使用不含碳酸锂（Li 2 CO 3）的碳材料的正极构件来减少充电过电压，并且包括金属多孔材料，从而抑制碳酸锂的形成 （Li 2 CO 3）。 本发明的金属空气二次电池的特征在于，具有在其内吸附有金属离子而发出金属离子的负极部件，将氧离子化的正极部件和浸渍有电解质的隔膜配置在负极 构件和正极构件，其中构成正极构件的载体，催化剂和粘合剂的总重量中的碳重量为50％以下。

公开(公告)号：US20130101907A1

公开(公告)日：2013-04-25

申请号：US13807028

申请日：2010-07-02

申请人： Shin Takahashi ,  Kazuhiro Yoshida ,  Kazushige Kohno

发明人： Shin Takahashi ,  Kazuhiro Yoshida ,  Kazushige Kohno

IPC分类号： H01M12/08

CPC分类号： H01M12/08 ,  H01M4/38 ,  H01M4/382 ,  H01M4/8615 ,  H01M4/8647 ,  H01M4/8668 ,  H01M4/90 ,  H01M4/9016 ,  H01M10/052 ,  H01M2004/8689 ,  Y02E60/128 ,  Y02E60/50 ,  Y02T10/7011

摘要： An object of the invention is to reduce the charging overvoltage by using a positive electrode member which does not contain a carbon material that causes the generation of lithium carbonate (Li2CO3), and which comprises a metal porous material, thereby suppressing the formation of lithium carbonate (Li2CO3). The metal air secondary battery of the invention is characterized by having a negative electrode member which has metal ions occluded therein and emits metal ions, a positive electrode member which ionizes oxygen, and a separator which is impregnated with an electrolyte and disposed between the negative electrode member and the positive electrode member, wherein the carbon weight in the total weight of a carrier, a catalyst, and a binder constituting the positive electrode member is at least 50% or less.

摘要翻译： 本发明的目的是通过使用不含碳酸锂（Li 2 CO 3）的碳材料的正极构件来减少充电过电压，并且包括金属多孔材料，从而抑制碳酸锂的形成 （Li 2 CO 3）。 本发明的金属空气二次电池的特征在于，具有在其内吸附有金属离子而发出金属离子的负极部件，将氧离子化的正极部件和浸渍有电解质的隔膜配置在负极 构件和正极构件，其中构成正极构件的载体，催化剂和粘合剂的总重量中的碳重量为至少50％以下。

公开(公告)号：US20110281178A1

公开(公告)日：2011-11-17

申请号：US13105066

申请日：2011-05-11

申请人： Toshiyuki KOBAYASHI ,  Kazushige Kohno

发明人： Toshiyuki KOBAYASHI ,  Kazushige Kohno

IPC分类号： H01M10/056

CPC分类号： H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M10/4235 ,  H01M2300/0028 ,  H01M2300/0031 ,  H01M2300/0042

摘要： A nonaqueous electrolyte and a lithium-ion secondary battery using the same, wherein a mixture of a cyclic carbonate, a chain carbonate, a first phosphoric acid ester wherein bonding between carbons is a single bond, and a second phosphoric acid ester wherein bonding between carbons contains a double bond is used as the nonaqueous electrolyte. It is desirable that the first phosphoric acid ester is a trimethyl phosphate. In addition, it is desirable that the second phosphoric acid ester is a dimethylisopropenyl phosphate.

摘要翻译： 一种非水电解质和使用该非水电解质的锂离子二次电池，其中环状碳酸酯，链状碳酸酯，碳键合为单键的第一磷酸酯和碳键之间的第二磷酸酯的混合物 含有双键作为非水电解质。 第一磷酸酯是磷酸三甲酯是理想的。 此外，优选第二磷酸酯是二甲基异丙烯基磷酸酯。

公开(公告)号：US08029934B2

公开(公告)日：2011-10-04

申请号：US11782008

申请日：2007-07-24

申请人： Hiroshi Haruna ,  Eiji Hoshi ,  Kazushige Kohno

发明人： Hiroshi Haruna ,  Eiji Hoshi ,  Kazushige Kohno

IPC分类号： H01M6/16 ,  H01M6/04

CPC分类号： H01M10/0567 ,  H01M4/131 ,  H01M4/133 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0569 ,  Y02T10/7011

摘要： The present invention provides a battery that experiences a small degree of temporal change from the initial battery properties over the long term storage period of the battery. Specifically, the present invention provides a lithium secondary battery, in which a positive electrode capable of storing and releasing lithium and a negative electrode capable of storing and releasing lithium are formed via an electrolyte, wherein: the electrolyte comprises a cyclic solvent and a chain-type solvent and contains a compound having a boron-oxygen bond (B—O) and a carbon-carbon double bond (C═C).

摘要翻译： 本发明提供了一种电池，其在电池的长期存储期间经历与初始电池性质的小的时间变化程度。 具体而言，本发明提供一种锂二次电池，其中通过电解质形成能够储存和释放锂的正极和能够储存和释放锂的负极，其中：所述电解质包含环状溶剂和链状 - 并含有具有硼 - 氧键（B-O）和碳 - 碳双键（C = C）的化合物。

公开(公告)号：US20140113195A1

公开(公告)日：2014-04-24

申请号：US14126200

申请日：2011-06-13

申请人： Kazushige Kohno

发明人： Kazushige Kohno

IPC分类号： H01M4/525

CPC分类号： H01M4/525 ,  C01G49/0027 ,  C01P2002/72 ,  H01M2/0222 ,  H01M4/364 ,  H01M4/485 ,  H01M10/052 ,  Y02T10/7011

摘要： Disclosed is a negative electrode active material for lithium-ion secondary batteries which contributes to high capacity, high energy density, and safety and a lithium-ion secondary battery provided with the negative electrode active material. The negative electrode active material is an oxide containing Li and Fe and having crystalline and amorphous phases of LiFeO2 such that there is a specific ratio ranging from 13.2 to 100 between peak value of X-ray diffraction due to the plane of the crystalline phase and peak value of X-ray diffraction due to the amorphous phase. The negative electrode active material is produced by preparing a mixture of LiOH.H2O and FeOOH and heating it together with distilled water in an autoclave at 180 to 220° C. for 10 to 20 hours, thereby giving an oxide having the crystalline and amorphous phases of LiFeO2 or an oxide having the crystalline and amorphous phases of LiFeO2 and LiFe5O8.

摘要翻译： 公开了一种用于锂离子二次电池的负极活性物质，其具有高容量，高能量密度和安全性，以及具有负极活性物质的锂离子二次电池。 负极活性物质是含有Li和Fe的氧化物，其具有LiFeO 2的结晶相和非晶相，使得由于结晶相的平面而产生的X射线衍射的峰值与峰的峰值之间的特定比例为13.2〜100 由于非晶相的X射线衍射值。 负极活性物质是通过制备LiOH·H 2 O和FeOOH的混合物，并在高压釜中与蒸馏水一起在180〜220℃下加热10〜20小时，得到具有结晶相和非晶相的氧化物 的LiFeO 2或具有LiFeO 2和LiFe 5 O 8的结晶相和非晶相的氧化物。

公开(公告)号：US20130189591A1

公开(公告)日：2013-07-25

申请号：US13877687

申请日：2011-08-19

申请人： Katsunori Nishimura ,  Yoshiaki Kumashiro ,  Kazushige Kohno ,  Toshiyuki Kobayashi

发明人： Katsunori Nishimura ,  Yoshiaki Kumashiro ,  Kazushige Kohno ,  Toshiyuki Kobayashi

IPC分类号： H01M10/056

CPC分类号： H01M10/056 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/4235 ,  H01M2300/0037 ,  H01M2300/004 ,  H01M2300/0042 ,  Y02T10/7011

摘要： The present invention aims to improve the fire resistance of an electrolytic solution used for a lithium-ion battery and improve the life characteristics of the lithium-ion battery. In the lithium ion battery of the present invention, specific amounts of ethylene carbonate and dimethyl carbonate are used for a non-aqueous electrolytic solution, and trimethyl phosphate is added thereto. Specifically, the non-aqueous electrolytic solution contains 60 vol % or more of ethylene carbonate (EC) and dimethyl carbonate (DMC). The volume ratio of DMC to the sum of EC and DMC is 0.3 to 0.6, and the non-aqueous electrolytic solution contains 3 to 5 wt % of trimethyl phosphate (TMP) with respect to the total weight of the non-aqueous electrolytic solution. Such a non-aqueous electrolytic solution has an effect of improving the self-fire extinguishing property, and thus improves the safety of the lithium-ion battery.

摘要翻译： 本发明旨在提高用于锂离子电池的电解液的耐火性，并提高锂离子电池的使用寿命。 在本发明的锂离子电池中，对于非水电解液使用碳酸亚乙酯和碳酸二甲酯的特定量，并向其中加入磷酸三甲酯。 具体地说，非水电解液含有60体积％以上的碳酸亚乙酯（EC）和碳酸二甲酯（DMC）。 DMC与EC和DMC的总和的体积比为0.3〜0.6，相对于非水电解液的总重量，非水电解液含有3〜5重量％的磷酸三甲酯（TMP）。 这样的非水电解液具有提高自熄灭性的效果，提高了锂离子电池的安全性。

公开(公告)号：US20130122371A1

公开(公告)日：2013-05-16

申请号：US13736191

申请日：2013-01-08

申请人： Tatsuya Toyama ,  Kazushige Kohno

发明人： Tatsuya Toyama ,  Kazushige Kohno

IPC分类号： H01M4/131

CPC分类号： H01M4/131 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  Y02T10/7011

摘要： To provide a lithium secondary battery excellent in the life characteristic and the power density. A lithium secondary battery, comprising: a positive electrode capable of intercalating and deintercalating lithium; and an negative electrode capable of intercalating and deintercalating lithium, wherein the positive electrode contains a manganese-containing positive electrode active material of a spinel structure and an oxide that coats the surface of this positive electrode active material, wherein the oxide contains a metallic element, wherein the metallic element forms a solid solution with the positive electrode active material, and wherein the atomic concentration of the metallic element is approximately 0 at depths of from 50 to 100 nm from an external surface of the negative electrode.