公开(公告)号：US09017868B2

公开(公告)日：2015-04-28

申请号：US13151844

申请日：2011-06-02

申请人： Takeshi Matsuda ,  Masakazu Sanada ,  Kenta Hiramatsu ,  Kiyoshi Kanamura

发明人： Takeshi Matsuda ,  Masakazu Sanada ,  Kenta Hiramatsu ,  Kiyoshi Kanamura

IPC分类号： H01M4/02 ,  H01M4/13 ,  H01M10/50 ,  H01S4/00 ,  H01M4/82 ,  H01M4/88 ,  H01M4/04

CPC分类号： H01M4/8864 ,  H01M4/0404 ,  H01M4/0411 ,  H01M4/8828 ,  Y02E60/122 ,  Y02E60/50 ,  Y02P70/54 ,  Y10T29/49002 ,  Y10T29/49108 ,  Y10T29/49115

摘要： A negative-electrode active material layer formed between a negative-electrode current collector and a solid electrolyte layer has a line-and-space structure in which a plurality of stripe-shaped pattern elements extending in a Y direction are arranged while being separated from each other. A gradient at each contact point where the stripe-shaped pattern element, the negative-electrode current collector and the solid electrolyte layer are in contact with each other is made smaller than 90°.

摘要翻译： 形成在负极集电体和固体电解质层之间的负极活性物质层具有线状空间结构，其中沿着Y方向延伸的多个条状图案元素被排列成与每个 其他。 条状图案元件，负极集电体和固体电解质层彼此接触的各接触点的梯度小于90°。

公开(公告)号：US08999587B2

公开(公告)日：2015-04-07

申请号：US13220244

申请日：2011-08-29

申请人： Takeshi Matsuda ,  Masakazu Sanada ,  Kenta Hiramatsu ,  Kiyoshi Kanamura

发明人： Takeshi Matsuda ,  Masakazu Sanada ,  Kenta Hiramatsu ,  Kiyoshi Kanamura

IPC分类号： H01M10/056 ,  H01M10/0585 ,  H01M10/04 ,  H01M10/0525 ,  H01M4/04 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/485 ,  H01M10/0565 ,  H01M10/42 ,  H01M4/525 ,  H01M4/02

CPC分类号： H01M10/0525 ,  H01M4/0404 ,  H01M4/0411 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/485 ,  H01M4/525 ,  H01M10/0565 ,  H01M10/425 ,  H01M2004/025 ,  H01M2004/027 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011 ,  Y10T29/49108 ,  Y10T29/49112 ,  Y10T29/49115

摘要： A negative-electrode active material layer 12 contains Li4Ti5O12 as a negative-electrode active material, and a positive-electrode active material layer 14 contains LiCoO2 as a positive-electrode active material. A solid electrolyte layer 13 contains polyethylene oxide and polystyrene as an electrolyte material. Gradients of surfaces of stripe-shaped pattern elements 121 forming the negative-electrode active material layer 12 are smaller than 90° when viewed from a surface of the negative-electrode current collector 11. By such a construction, it is possible to construct a battery having a high capacity in relation to the used amount of the active materials and good charge and discharge characteristics.

摘要翻译： 负极活性物质层12含有Li 4 Ti 5 O 12作为负极活性物质，正极活性物质层14含有作为正极活性物质的LiCoO 2。 固体电解质层13含有作为电解质材料的聚环氧乙烷和聚苯乙烯。 形成负极活性物质层12的条状图案元件121的表面的梯度从负极集电体11的表面观察时小于90°。通过这样的结构，可以构成电池 相对于活性物质的使用量具有高容量和良好的充放电特性。

公开(公告)号：US20110070479A1

公开(公告)日：2011-03-24

申请号：US12888070

申请日：2010-09-22

申请人： Takeshi Matsuda ,  Masakazu Sanada ,  Kenta Hiramatsu

发明人： Takeshi Matsuda ,  Masakazu Sanada ,  Kenta Hiramatsu

IPC分类号： H01M10/04 ,  H01M6/12

CPC分类号： H01M10/0585 ,  H01M10/0525 ,  H01M10/0565 ,  Y02E60/122 ,  Y02P70/54 ,  Y10T29/49108 ,  Y10T29/49115

摘要： A negative-electrode active material layer having an uneven pattern is formed on a surface of a copper foil as a negative-electrode current collector by applying an application liquid by a nozzle-scan coating method. Subsequently, an application liquid containing a polymer electrolyte material is applied by a spin coating method, thereby forming a solid electrolyte layer in conformity with the uneven pattern. Subsequently, an application liquid is applied by a doctor blade method, thereby forming a positive-electrode active material layer whose lower surface conforms to the unevenness and whose upper surface is substantially flat. A thin and high-performance all-solid-state battery can be produced by laminating an aluminum foil as a positive-electrode current collector before the application liquid is cured.

摘要翻译： 通过喷嘴扫描涂布法施加涂布液，在作为负极集电体的铜箔的表面上形成具有凹凸图案的负极活性物质层。 随后，通过旋涂法涂布含有聚合物电解质材料的涂布液，从而形成与不匀图案一致的固体电解质层。 随后，通过刮刀法施加涂布液，从而形成其下表面符合凹凸且其上表面基本平坦的正极活性物质层。 在施加液体固化之前，可以通过层压铝箔作为正极集电体来制造薄而高性能的全固态电池。

公开(公告)号：US08920522B2

公开(公告)日：2014-12-30

申请号：US12888070

申请日：2010-09-22

申请人： Takeshi Matsuda ,  Masakazu Sanada ,  Kenta Hiramatsu

发明人： Takeshi Matsuda ,  Masakazu Sanada ,  Kenta Hiramatsu

IPC分类号： H01M10/0585 ,  H01M10/0525 ,  H01M10/0565

CPC分类号： H01M10/0585 ,  H01M10/0525 ,  H01M10/0565 ,  Y02E60/122 ,  Y02P70/54 ,  Y10T29/49108 ,  Y10T29/49115

摘要： A negative-electrode active material layer having an uneven pattern is formed on a surface of a copper foil as a negative-electrode current collector by applying an application liquid by a nozzle-scan coating method. Subsequently, an application liquid containing a polymer electrolyte material is applied by a spin coating method, thereby forming a solid electrolyte layer in conformity with the uneven pattern. Subsequently, an application liquid is applied by a doctor blade method, thereby forming a positive-electrode active material layer whose lower surface conforms to the unevenness and whose upper surface is substantially flat. A thin and high-performance all-solid-state battery can be produced by laminating an aluminum foil as a positive-electrode current collector before the application liquid is cured.

摘要翻译： 通过喷嘴扫描涂布法施加涂布液，在作为负极集电体的铜箔的表面上形成具有凹凸图案的负极活性物质层。 随后，通过旋涂法涂布含有聚合物电解质材料的涂布液，从而形成与不匀图案一致的固体电解质层。 随后，通过刮刀法施加涂布液，从而形成其下表面符合凹凸且其上表面基本平坦的正极活性物质层。 在施加液体固化之前，可以通过层压铝箔作为正极集电体来制造薄而高性能的全固态电池。

公开(公告)号：US20120015253A1

公开(公告)日：2012-01-19

申请号：US13181928

申请日：2011-07-13

申请人： Takeshi Matsuda ,  Masakazu SANADA ,  Kenta HIRAMATSU

发明人： Takeshi Matsuda ,  Masakazu SANADA ,  Kenta HIRAMATSU

IPC分类号： H01M4/64 ,  H01M10/04

CPC分类号： H01M10/04 ,  H01M4/0404 ,  H01M10/052 ,  H01M10/0585 ,  H01M2220/20 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011 ,  Y10T29/49115

摘要： Stripe-shaped pattern elements 121 projecting from a surface of a substantially flat negative-electrode current collector 11 are formed by applying an application liquid containing a negative-electrode active material by a nozzle-scan coating method. Subsequently, an application liquid containing a solid electrolyte material is applied, for example, by a spin coating method to form a solid electrolyte layer 13. A thickness Te of the solid electrolyte layer 13 covering exposed surfaces 11a of the negative-electrode current collector exposed between the stripe-shaped pattern elements 121 is set to be smaller than a height Ha of the stripe-shaped pattern elements 121, taking into account that part of the application liquid applied on the stripe-shaped pattern elements 121 flows down toward the exposed surfaces 11a.

摘要翻译： 通过喷嘴扫描涂布法涂布含有负极活性物质的涂布液，形成从基本平坦的负极集电体11的表面突出的条状图形元件121。 接着，例如通过旋涂法涂布含有固体电解质材料的涂布液，形成固体电解质层13.固体电解质层13的厚度Te覆盖负极集电体露出面11a 考虑到施加在条形图案元件121上的涂敷液的一部分向着露出的表面向下流动，条形图案元件121之间的距离小于条形图案元件121的高度Ha 11a。

公开(公告)号：US08486568B2

公开(公告)日：2013-07-16

申请号：US13572255

申请日：2012-08-10

申请人： Masakazu Sanada ,  Takeshi Matsuda

发明人： Masakazu Sanada ,  Takeshi Matsuda

IPC分类号： H01M6/24

CPC分类号： H01M10/058 ,  H01M4/0419 ,  H01M10/052 ,  H01M10/0565 ,  Y10T29/49115

摘要： Preparation process of an all-solid battery, comprising forming a linear active material part by relatively moving a first nozzle which discharges active material linearly with respect to a current collector to form a plurality of linear active material parts on the current collector, forming a first electrolyte layer by relatively moving a second nozzle which discharges first electrolyte material with respect to the current collector to apply first electrolyte material to each of the plurality of linear active material parts to form linear electrolyte parts thereon to thereby prepare linear active material-electrolyte parts, photo-curing by irradiating light to the linear electrolyte parts to cure them, and forming a second electrolyte layer by applying second electrolyte material to the whole of the linear active material-electrolyte parts and spaces on the current collector between the linear active material-electrolyte parts to prepare the second electrolyte layer.

摘要翻译： 一种全固体电池的制备方法，包括通过相对移动第一喷嘴形成线性活性物质部分，所述第一喷嘴相对于集电器线性排放活性物质，以在集电器上形成多个线性活性物质部分，形成第一 电解质层，通过相对移动相对于集电体排出第一电解质材料的第二喷嘴，以将第一电解质材料施加到多个线性活性材料部件中的每一个上，以在其上形成线性电解质部分，从而制备线性活性材料 - 电解质部件， 通过对线性电解质部分照射光使其固化而进行光固化，并且通过将第二电解质材料施加到线状活性物质 - 电解质之间的整个线性活性物质 - 电解质部分和集电器上的空间来形成第二电解质层 部分以制备第二电解质层。

公开(公告)号：US08771383B2

公开(公告)日：2014-07-08

申请号：US13155020

申请日：2011-06-07

申请人： Masakazu Sanada ,  Takeshi Matsuda

发明人： Masakazu Sanada ,  Takeshi Matsuda

IPC分类号： H01M6/18 ,  H01M6/40

CPC分类号： H01M6/188 ,  H01M4/0404 ,  H01M4/0407 ,  H01M4/0419 ,  H01M4/0471 ,  H01M6/40 ,  H01M10/0413 ,  H01M10/0436 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/0585 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011 ,  Y10T29/49108 ,  Y10T29/49115 ,  Y10T156/10

摘要： A negative-electrode active material layer having a line-and-space structure is formed by applying an application liquid containing a negative-electrode active material in stripes on a surface of a negative-electrode current collector using a nozzle-scan coating method and drying the application liquid (Steps S101, S102). Subsequently, by a spin coating method, an application liquid containing a solid electrolyte material is applied (Step S103) and heated at a temperature lower than a glass-transition temperature of the electrolyte material to be dried. Further, an application liquid containing a positive-electrode active material is applied (Step S105) and a positive-electrode current collector is laminated (Step S106) and, then, a laminated body is heated to or above the glass-transition temperature of the electrolyte material to cause the solid electrolyte to flow and adhere to the active material layers.

摘要翻译： 使用喷嘴扫描涂布法在负极集电体的表面上涂布含有负极活性物质的涂布液，形成具有线间距结构的负极活性物质层， 涂布液（步骤S101，S102）。 随后，通过旋转涂布法涂布含有固体电解质材料的涂布液（步骤S103），并在比待干燥的电解质材料的玻璃化转变温度低的温度下进行加热。 此外，涂布含有正极活性物质的涂布液（步骤S105），层叠正极集电体（步骤S106），然后将层叠体加热至玻璃化转变温度以上 电解质材料以使固体电解质流动并粘附到活性材料层上。

公开(公告)号：US20120002359A1

公开(公告)日：2012-01-05

申请号：US13155020

申请日：2011-06-07

申请人： Masakazu SANADA ,  Takeshi Matsuda

发明人： Masakazu SANADA ,  Takeshi Matsuda

IPC分类号： H05K5/00 ,  H01M10/02 ,  B05D5/12 ,  H01M2/20

CPC分类号： H01M6/188 ,  H01M4/0404 ,  H01M4/0407 ,  H01M4/0419 ,  H01M4/0471 ,  H01M6/40 ,  H01M10/0413 ,  H01M10/0436 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/0585 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011 ,  Y10T29/49108 ,  Y10T29/49115 ,  Y10T156/10

摘要： A negative-electrode active material layer having a line-and-space structure is formed by applying an application liquid containing a negative-electrode active material in stripes on a surface of a negative-electrode current collector using a nozzle-scan coating method and drying the application liquid (Steps S101, S102). Subsequently, by a spin coating method, an application liquid containing a solid electrolyte material is applied (Step S103) and heated at a temperature lower than a glass-transition temperature of the electrolyte material to be dried. Further, an application liquid containing a positive-electrode active material is applied (Step S105) and a positive-electrode current collector is laminated (Step S106) and, then, a laminated body is heated to or above the glass-transition temperature of the electrolyte material to cause the solid electrolyte to flow and adhere to the active material layers.

摘要翻译： 使用喷嘴扫描涂布法在负极集电体的表面上涂布含有负极活性物质的涂布液，形成具有线间距结构的负极活性物质层， 涂布液（步骤S101，S102）。 随后，通过旋转涂布法涂布含有固体电解质材料的涂布液（步骤S103），并在比待干燥的电解质材料的玻璃化转变温度低的温度下进行加热。 此外，涂布含有正极活性物质的涂布液（步骤S105），层叠正极集电体（步骤S106），然后将层叠体加热至玻璃化转变温度以上 电解质材料以使固体电解质流动并粘附到活性材料层上。

公开(公告)号：US08895035B2

公开(公告)日：2014-11-25

申请号：US13806317

申请日：2011-06-21

申请人： Shunichirou Fukumoto ,  Daisuke Shikama ,  Keiji Toriyabe ,  Toshihiro Nagata ,  Masaaki Komatsu ,  Takeshi Matsuda ,  Yuki Nakano

发明人： Shunichirou Fukumoto ,  Daisuke Shikama ,  Keiji Toriyabe ,  Toshihiro Nagata ,  Masaaki Komatsu ,  Takeshi Matsuda ,  Yuki Nakano

IPC分类号： A01N43/54 ,  A01N55/00 ,  A01N37/50 ,  A01N43/08 ,  A01N43/10 ,  A01N43/20 ,  A01N43/40 ,  A01N43/50 ,  A01N43/56 ,  A01N43/653 ,  A01N43/713 ,  A01N43/78 ,  A01N43/82 ,  C07C259/02 ,  A01N43/84 ,  C07D249/10 ,  C07D401/12 ,  C07D403/12 ,  C07D413/06 ,  C07D413/12 ,  C07D417/06 ,  C07F7/10 ,  C07D403/06 ,  C07D405/12 ,  C07D417/12 ,  A01N47/18 ,  C07F7/08

CPC分类号： A01N55/00 ,  A01N37/50 ,  A01N43/08 ,  A01N43/10 ,  A01N43/20 ,  A01N43/40 ,  A01N43/50 ,  A01N43/56 ,  A01N43/653 ,  A01N43/713 ,  A01N43/78 ,  A01N43/82 ,  A01N43/84 ,  A01N47/18 ,  C07C259/02 ,  C07D249/10 ,  C07D401/12 ,  C07D403/06 ,  C07D403/12 ,  C07D405/12 ,  C07D413/06 ,  C07D413/12 ,  C07D417/06 ,  C07D417/12 ,  C07F7/0812 ,  C07F7/10

摘要： The present invention provides a novel alkoxyimino derivative or a salt thereof, as well as to a pest control agent containing the derivative or salt thereof as an active ingredient, which shows an excellent pest control effect on a wide range of pests in the agricultural and horticultural field and is also capable of controlling resistant pests. The novel alkoxyimino derivative is characterized by being represented by general formula [I] (in the formula, X, R1, R2 and Q are as defined in the specification) and the post control agent is characterized by containing as an active ingredient the alkoxyimino derivative or a salt thereof.

摘要翻译： 本发明提供一种新的烷氧基亚氨基衍生物或其盐，以及含有其衍生物或其盐作为活性成分的害虫防治剂，其对农业和园艺中广泛的害虫的显示具有优异的害虫防治效果 并且也能够控制抗性害虫。 该新型烷氧基亚氨基衍生物的特征在于由通式[I]表示（式中，X，R 1，R 2和Q如说明书中所定义），后处理剂的特征在于含有烷氧基亚氨基衍生物 或其盐。

公开(公告)号：US20120088122A1

公开(公告)日：2012-04-12

申请号：US13260831

申请日：2010-03-31

申请人： Takeshi Matsuda ,  Akira Matsuzaki ,  Masato Sasaki ,  Katsutoshi Takashima

发明人： Takeshi Matsuda ,  Akira Matsuzaki ,  Masato Sasaki ,  Katsutoshi Takashima

IPC分类号： B32B15/18 ,  B32B15/01

CPC分类号： C23C22/60 ,  C09D5/082 ,  C09D7/61 ,  C09D7/65 ,  C23C2222/20 ,  Y10T428/12757 ,  Y10T428/12799 ,  Y10T428/12806

摘要： A galvanized steel sheet includes a surface-treatment film with 50 to 1200 mg/m2, wherein the surface-treatment film is obtained by applying a surface-treatment agent to a surface of a galvanized steel sheet and drying the surface-treatment agent by heating; and the surface-treatment agent is prepared as a mixture having a pH of 8 to 10 and containing, with specific proportions, a water-soluble zirconium compound, a tetraalkoxysilane, an epoxy-group-containing compound, a chelating agent, a silane coupling agent, vanadic acid, and a metal compound.

摘要翻译： 镀锌钢板包括具有50〜1200mg / m 2的表面处理膜，其中，通过将表面处理剂涂布在镀锌钢板的表面上并通过加热干燥表面处理剂而获得表面处理膜 ; 并且将表面处理剂制备为pH为8至10的混合物，并且特定比例含有水溶性锆化合物，四烷氧基硅烷，含环氧基的化合物，螯合剂，硅烷偶联剂 试剂，钒酸和金属化合物。