公开(公告)号：US5631341A

公开(公告)日：1997-05-20

申请号：US570473

申请日：1995-12-11

申请人： Takeshi Morishima ,  Shin Konishi ,  Shinjiro Hama

发明人： Takeshi Morishima ,  Shin Konishi ,  Shinjiro Hama

IPC分类号： C08G18/65 ,  C08G18/08 ,  C08G18/28 ,  C08G18/36 ,  C08G18/70 ,  C08G18/79 ,  C08G18/80 ,  C09D5/00 ,  C09D175/00 ,  C09D175/04 ,  C09D175/08 ,  C09J175/08 ,  C08G18/10

CPC分类号： C08G18/283 ,  C08G18/0823 ,  C08G18/36 ,  C08G18/706 ,  C08G18/79 ,  C08G18/798 ,  C08G18/8009 ,  C08G18/8012 ,  C08G18/8064 ,  C08G2170/80 ,  Y10S528/905

摘要： A self-emulsifiable polyisocyanate mixture having a hexamethylene diisocyanate monomer content of not more than 1.0% by weight and an average NCO functionality of 2.0 to 3.7 obtained by subjecting hexamethylene diisocyanate to urethanation with a branched dihydric alcohol having overall 4 to 35 carbon atoms, of which 2 to 33 carbon atoms are a total number of the carbon atoms possessed by one or more branches, a hydrophilic surfactant having one or more active hydrogen atoms capable of reacting with NCO group and 3 to 90 alkylene oxide units, an aliphatic compound having one or more active hydrogen atoms capable of reacting with NCO group and 8 or more carbon atoms and an unbranched glycol having 1 to 10 carbon atoms; uretdione-forming reaction; and isocyanurate-forming reaction. Said self-emulsifiable polyisocyanate mixture is excellent in compatibility, dispersion stability and NCO group-stability and can be combined with water or a water-soluble resin and/or an aqueous emulsion, and if necessary, an additive to provide an aqueous coating or adhesive composition excellent in heat resistance, workability, coating film appearance, weather resistance and adhesion to substrate.

摘要翻译： 具有六亚甲基二异氰酸酯单体含量不大于1.0重量％且平均NCO官能度为2.0-3.7的自乳化多异氰酸酯混合物，其通过使六亚甲基二异氰酸酯与具有总共4至35个碳原子的支化二元醇进行氨基甲酸酯化反应得到 其中2至33个碳原子是一个或多个分支具有的碳原子总数，具有一个或多个能够与NCO基团反应的活性氢原子和3至90个环氧烷单元的亲水性表面活性剂，具有一个 或更多能够与NCO基团和8个或更多个碳原子反应的活性氢原子和具有1-10个碳原子的未分支的二醇; 脲二酮形成反应; 和异氰脲酸酯形成反应。 所述自乳化多异氰酸酯混合物的相容性，分散稳定性和NCO基团稳定性优异，并且可以与水或水溶性树脂和/或水乳液组合，并且如果需要，可提供添加剂以提供水性涂料或粘合剂 耐热性，加工性，涂膜外观，耐候性和与基材的粘合性优异的组合物。

公开(公告)号：US5548057A

公开(公告)日：1996-08-20

申请号：US294835

申请日：1994-08-29

申请人： Shinji Hirayama ,  Shin Konishi ,  Takao Hidai ,  Shinjiro Hama ,  Sadako Hashimoto ,  Yukihiro Morikawa

发明人： Shinji Hirayama ,  Shin Konishi ,  Takao Hidai ,  Shinjiro Hama ,  Sadako Hashimoto ,  Yukihiro Morikawa

IPC分类号： C08G18/10 ,  C08G18/40 ,  C08G18/65 ,  C08G18/78 ,  C08G18/79 ,  C08G18/83 ,  C08J7/00 ,  C08L75/04

CPC分类号： C08G18/798

摘要： A one-component-type composition for a polyurethane elastomer, comprising as a main component a polyurethane precursor containing a polyisocyanate component, and a compound having active hydrogen groups. The polyisocyanate component contains a polyisocyanate having at least a urethodione group (particularly urethodione and isocyanurate groups), and the compound (polyol or the like) having active hydrogen groups contains at least two active hydrogen groups in its molecule and has a molecular weight of 18 to 20000. The polyurethane precursor is obtained by reacting the polyisocyanate component and the compound having active hydrogen groups under the condition that the equivalent ratio of the active hydrogen group in the compound having active hydrogen groups to the isocyanate group in the polyisocyanate component exceeds 1.0. The equivalent ratio of the urethodione group to the active hydrogen group in the polyurethane precursor is from 0.25 to 1.0. The one-component-type composition for a polyurethane elastomer has storage stability comparable to that of thermoplastic elastomers, can be handled with ease, and does not pollute working environment. The composition is useful for preparaing elastomers which have physical properties equal to those of two-component-type elastomers.

摘要翻译： 用于聚氨酯弹性体的单组分型组合物，其包含作为主要组分的含有多异氰酸酯组分的聚氨酯前体和具有活性氢基团的化合物。 多异氰酸酯成分含有至少具有脲基（特别是脲基和异氰脲酸酯基）的多异氰酸酯，具有活性氢基的化合物（多元醇等）在其分子中含有至少两个活性氢基，分子量为18 聚氨酯前体是通过使多异氰酸酯组分和具有活性氢基团的化合物在多异氰酸酯组分中的具有活性氢基团的化合物中的活性氢基团与异氰酸酯基团的当量比超过1.0的条件下反应而获得的。 脲基组与聚氨酯前体中活性氢基团的当量比为0.25〜1.0。 用于聚氨酯弹性体的单组分型组合物具有与热塑性弹性体相当的储存稳定性，可以容易地处理，并且不会污染工作环境。 该组合物可用于制备具有与双组分型弹性体相同的物理性质的弹性体。