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    Nickel electrode for alkaline storage battery and alkaline storage battery
    3.
    发明授权
    Nickel electrode for alkaline storage battery and alkaline storage battery 有权
    碱性蓄电池和碱性蓄电池用镍电极

    公开(公告)号：US06835497B2

    公开(公告)日：2004-12-28

    申请号：US10122208

    申请日：2002-04-16

    申请人： Takeshi Ogasawara ,  Mitsunori Tokuda ,  Mutsumi Yano ,  Shin Fujitani

    发明人： Takeshi Ogasawara ,  Mitsunori Tokuda ,  Mutsumi Yano ,  Shin Fujitani

    IPC分类号： H01M432

    CPC分类号： H01M4/366 ,  H01M4/32 ,  H01M4/52 ,  H01M4/80 ,  H01M6/10 ,  H01M10/26 ,  H01M2300/0014 ,  Y02E60/124 ,  Y02P70/54

    摘要： A nickel electrode for alkaline storage battery according to the present invention is formed by applying a paste containing active material particles composed of nickel hydroxide to a conductive substrate and drying said paste, wherein a conductive layer consisting of sodium-containing cobalt oxide is formed on a surface of said active material particles, and titanium powder and/or titanium compound powder is added to the surface of said active material particles, and an alkaline storage battery according to the present invention uses as its positive electrode the above-mentioned nickel electrode for alkaline storage battery.

    摘要翻译： 本发明的碱性蓄电池用镍电极是通过将含有由氢氧化镍构成的活性物质粒子的糊料涂敷在导电性基材上而进行干燥而形成的，其中，在含有氧化钴的基材上形成由含钠钴氧化物构成的导电层 所述活性物质粒子的表面，钛粉末和/或钛化合物粉末被添加到所述活性物质粒子的表面，本发明的碱性蓄电池使用上述镍电极作为其正极 蓄电池

    Non-sintered nickel electrode for alkaline storage battery
    6.
    发明授权
    Non-sintered nickel electrode for alkaline storage battery 失效
    碱性蓄电池用非烧结镍电极

    公开(公告)号：US6077625A

    公开(公告)日：2000-06-20

    申请号：US97679

    申请日：1998-06-16

    申请人： Mutsumi Yano ,  Mitsunori Tokuda ,  Kousuke Satoguchi ,  Shin Fujitani ,  Koji Nishio

    发明人： Mutsumi Yano ,  Mitsunori Tokuda ,  Kousuke Satoguchi ,  Shin Fujitani ,  Koji Nishio

    IPC分类号： H01M4/52 ,  H01M4/32

    CPC分类号： H01M4/52

    摘要： Non-sintered nickel electrodes for alkaline storage batteries which can express high active material utilization efficiency not only at the time of charging at ordinary temperature but also at the time of charging in a high-temperature atmosphere are provided by using an active material powder composed of composite particles each comprising a substrate particle containing nickel hydroxide, an inner coat layer covering the substrate particle and comprising yttrium, scandium or a lanthanoid, or an yttrium, scandium or lanthanoid compound, and an outer coat layer covering the inner coat layer and comprising cobalt or a cobalt compound, or composed of composite particles each comprising a substrate particle containing nickel hydroxide, an inner coat layer covering the substrate particle and comprising cobalt or a cobalt compound, and an outer coat layer covering the inner coat layer and comprising yttrium, scandium or a lanthanoid, or an yttrium, scandium or lanthanoid compound.

    摘要翻译： 通过使用由以下组成的活性物质粉末，可以提供不仅在常温充电时也能在高温气氛中充电的情况下表现出高活性物质利用效率的碱性蓄电池用非烧结镍电极 每个复合颗粒包含含有氢氧化镍的底物颗粒，覆盖基质颗粒并包含钇，钪或镧系元素的内涂层，或钇，钪或镧系元素化合物的外涂层和覆盖内涂层的外涂层， 或钴化合物，或由包含含有氢氧化镍的基底颗粒的复合颗粒或覆盖基材颗粒并包含钴或钴化合物的内涂层以及覆盖内涂层并包含钇，钪的外涂层的复合颗粒组成 或镧系元素，或钇，钪或镧系元素化合物。

    Sealed alkaline storage battery
    8.
    发明授权
    Sealed alkaline storage battery 有权
    密封碱性蓄电池

    公开(公告)号：US06566008B2

    公开(公告)日：2003-05-20

    申请号：US09794326

    申请日：2001-02-28

    申请人： Mutsumi Yano ,  Syuichi Suzuki ,  Mitsunori Tokuda ,  Mitsuzou Nogami ,  Mamoru Kimoto ,  Shin Fujitani ,  Koji Nishio

    发明人： Mutsumi Yano ,  Syuichi Suzuki ,  Mitsunori Tokuda ,  Mitsuzou Nogami ,  Mamoru Kimoto ,  Shin Fujitani ,  Koji Nishio

    IPC分类号： H01M432

    CPC分类号： H01M4/362 ,  H01M4/366 ,  H01M4/50 ,  H01M4/52 ,  H01M10/34 ,  H01M2006/5094

    摘要： A sealed alkaline storage battery using, as a positive electrode active material, nickel oxyhydroxide including Mn as a solid-solution element and having a &ggr; ratio of 65 through 100%; a sealed alkaline storage battery using, as a positive electrode active material, nickel oxyhydroxide including as an additive or coated with a rare earth element and/or a rare earth compound in a ratio measured based on the rare earth element of 0.05 through 5 wt %; and a sealed alkaline storage battery including, as a positive electrode active material, nickel oxyhydroxide having a half-width of a peak in a lattice plane (003) in an X-ray diffraction pattern of 0.8° or more. The pressure within the battery is not largely increased for a long period of charge-discharge cycles, and hence, the electrolyte hardly leaks.

    摘要翻译： 使用包含Mn作为固溶体元素并具有65至100％的γ比的正极活性材料的氢氧化正镍的密封碱性蓄电池; 使用包含作为添加剂的氢氧化镍或以稀土元素和/或稀土类化合物为基础的以0.05〜5重量％的稀土元素测定的比例包含稀土元素和/或稀土类化合物作为正极活性物质的密封型碱性蓄电池， ; 以及密封的碱性蓄电池，其包括在0.8°以上的X射线衍射图案中，作为正极活性物质，具有晶格面（003）中的峰的半值宽度的氢氧化正镍。 电池中的压力在长时间的充放电循环中不会大幅度增加，因此电解质几乎不泄漏。

    Sealed, alkaline-zinc storage battery
    9.
    发明授权
    Sealed, alkaline-zinc storage battery 有权
    密封，碱锌蓄电池

    公开(公告)号：US06265105B1

    公开(公告)日：2001-07-24

    申请号：US09329603

    申请日：1999-06-10

    申请人： Mitsunori Tokuda ,  Mutsumi Yano ,  Mitsuzou Nogami ,  Shin Fujitani ,  Koji Nishio

    发明人： Mitsunori Tokuda ,  Mutsumi Yano ,  Mitsuzou Nogami ,  Shin Fujitani ,  Koji Nishio

    IPC分类号： H01M604

    CPC分类号： H01M10/26 ,  H01M4/244 ,  H01M4/32 ,  H01M10/34 ,  H01M2004/023 ,  Y02E60/124

    摘要： A sealed alkaline-zinc storage battery includes a battery can, a hollow positive electrode disposed within the battery can in electrical contact therewith and containing a positive active material including nickle hydroxide, a negative electrode disposed inwardly of the positive electrode and containing a negative active material including zinc, a separator disposed between the positive and negative electrodes, a negative current collector inserted into the negative electrode, and an alkaline electrolyte filled in the battery can and impregnated into the positive electrode, negative electrode and separator. The positive electrode, negative electrode, separator, negative current collector and electrolyte together account for at least 75% of an internal volume of the battery can. The alkaline electrolyte is in the 30 to 45 mass % concentration range and has a total water content in the range of 0.5 to 0.9 g for each theoretical capacity of the negative electrode expressed as 1 Ah (ampere-hour).

    摘要翻译： 密封的碱性锌蓄电池包括电池罐，设置在与其接触的电池壳内的中空正电极，并且包含含有氢氧化镍的正极活性物质，设置在正极内侧的负极并含有负极活性物质 包括锌，设置在正极和负极之间的隔膜，插入负极的负极集电体和填充在电池壳中的碱性电解质，并浸渍在正极，负极和隔板中。 正极，负极，隔膜，负极集电器和电解质一起占电池罐内部体积的至少75％。 碱性电解质的浓度范围为30〜45质量％，对于负极的理论容量为1 Ah（安培小时），总含水量为0.5〜0.9g。