公开(公告)号：US20060102691A1

公开(公告)日：2006-05-18

申请号：US10517291

申请日：2003-06-16

申请人： Taketoshi Toyama ,  Ryoichi Sanada ,  Yoshiharu Hasegawa ,  Yuji Hisatomi ,  Ichiro Taninaka

发明人： Taketoshi Toyama ,  Ryoichi Sanada ,  Yoshiharu Hasegawa ,  Yuji Hisatomi ,  Ichiro Taninaka

IPC分类号： A47J36/02

CPC分类号： F28F21/084 ,  B23K1/0012 ,  B23K35/288 ,  B23K35/3605 ,  B23K35/3612 ,  B23K35/3613 ,  B23K2101/006 ,  B23K2101/14 ,  B23K2103/10 ,  F28F1/126

摘要： An aqueous aluminum brazing composition containing an organic binder and zinc-based flux which prevents precipitation of the zinc-based flux having a large specific gravity while securing excellent brazeability. The thixotropic index of the brazing composition is adjusted to 1.01-1.20 by adding (meth)acrylic acid/(meth)acrylate copolymer emulsion to the brazing composition as a precipitation inhibitor in an amount of 0.03-1.50 wt % of 100 wt % of the brazing composition. Since the (meth)acrylic acid/(meth)acrylate copolymer emulsion is used as the precipitation inhibitor in a specific amount instead of other types of compounds used for powder-containing paint such as ultrafine particle silica, poly(meth)acrylate, or polyvinyl alcohol, precipitation of the zinc-based flux can be prevented without impairing brazeability.

摘要翻译： 一种含有有机粘合剂和锌基助熔剂的铝水硬铝合金组合物，其在确保优异的钎焊性的同时防止具有大比重的锌基焊剂沉淀。 通过向作为沉淀抑制剂的钎焊组合物中加入（甲基）丙烯酸/（甲基）丙烯酸酯共聚物乳液的量为0.03〜1.50重量％的100重量％的（甲基）丙烯酸/（甲基）丙烯酸酯共聚物乳液，将钎焊组合物的触变指数调整为1.01〜 钎焊组成。 由于使用（甲基）丙烯酸/（甲基）丙烯酸酯共聚物乳液作为特定量的沉淀抑制剂而不是其它类型的用于含粉末涂料的化合物，例如超细颗粒二氧化硅，聚（甲基）丙烯酸酯或聚 酒精，可以防止锌基助熔剂的沉淀而不损害钎焊性。

公开(公告)号：US07534309B2

公开(公告)日：2009-05-19

申请号：US10517291

申请日：2003-06-16

申请人： Taketoshi Toyama ,  Ryoichi Sanada ,  Takashi Hatori ,  Yoshiharu Hasegawa ,  Yuji Hisatomi ,  Ichiro Taninaka

发明人： Taketoshi Toyama ,  Ryoichi Sanada ,  Takashi Hatori ,  Yoshiharu Hasegawa ,  Yuji Hisatomi ,  Ichiro Taninaka

IPC分类号： B23K35/34 ,  C08L93/00 ,  B23K1/20 ,  B23K31/02

CPC分类号： F28F21/084 ,  B23K1/0012 ,  B23K35/288 ,  B23K35/3605 ,  B23K35/3612 ,  B23K35/3613 ,  B23K2101/006 ,  B23K2101/14 ,  B23K2103/10 ,  F28F1/126

摘要： An aqueous aluminum brazing composition containing an organic binder and a zinc-based flux which prevents the precipitation of the zinc-based flux having a large specific gravity while securing an excellent brazeability. The thixotropic index of the brazing composition is adjusted to 1.01-1.20 by adding a (meth)acrylic acid/(meth)acrylate copolymer emulsion to the brazing composition as a precipitation inhibitor in an amount of 0.03-1.50 wt % of 100 wt % of the brazing composition. Since the (meth)acrylic acid/(meth)acrylate copolymer emulsion is used as the precipitation inhibitor in a specific amount instead of other types of compounds used for a powder-containing paint, such as ultrafine particle silica, poly(meth)acrylate, or polyvinyl alcohol, the precipitation of the zinc-based flux can be prevented without impairing the brazeability.

摘要翻译： 含有有机粘合剂的水性铝钎焊组合物和锌基助熔剂，其在确保优异的钎焊性的同时防止具有大比重的锌基焊剂的析出。 通过向作为沉淀抑制剂的钎焊组合物中加入（甲基）丙烯酸/（甲基）丙烯酸酯共聚物乳液的量为0.03〜1.50重量％的量为100重量％的（甲基）丙烯酸/（甲基）丙烯酸酯共聚物乳液，将钎焊组合物的触变指数调整为1.01〜 钎焊组成。 由于使用（甲基）丙烯酸/（甲基）丙烯酸酯共聚物乳液作为特定量的沉淀抑制剂而不是用于含粉末涂料的其它类型的化合物，例如超细颗粒二氧化硅，聚（甲基）丙烯酸酯， 或聚乙烯醇，可以防止锌基焊剂的沉淀而不损害钎焊性。

公开(公告)号：US06800345B2

公开(公告)日：2004-10-05

申请号：US09252303

申请日：1999-02-18

申请人： Shoei Teshima ,  Yoshiharu Hasegawa ,  Ichiro Taninaka ,  Tsutomu Usami ,  Yuji Hisatomi

发明人： Shoei Teshima ,  Yoshiharu Hasegawa ,  Ichiro Taninaka ,  Tsutomu Usami ,  Yuji Hisatomi

IPC分类号： B29D2200

CPC分类号： F28F21/084 ,  B23K35/025 ,  B23K35/3605 ,  B23K35/3613 ,  B23K2101/14 ,  Y10T428/13 ,  Y10T428/1355 ,  Y10T428/139 ,  Y10T428/31576

摘要： An aluminum extruded multi-cavity flat tube for use in an automotive heat exchanger having excellent brazing characteristics. At least one of the flat surfaces of said aluminum extruded multi-cavity flat tube is coated with a flux composition comprising a brazing flux and a synthetic resin based, as its main constituent, on a methacrylate homopolymer or a methacrylate copolymer or, alternatively, with a brazing composition comprising a brazing flux, brazing metals, and said synthetic resin. In a preferred embodiment, such a coating is provided by applying to a surface of an aluminum extruded multi-cavity flat tube, said compositions as added to an organic solvent and having a molecular structure wherein the atomic ratio of carbon to oxygen is between 2 and 3, by a roll-transfer printing technique.

摘要翻译： 一种用于具有优异钎焊特性​​的汽车热交换器的铝挤压多腔扁平管。 所述铝挤压多腔扁平管的至少一个平坦表面涂覆有助熔剂组合物，其包含作为其主要成分的钎焊助熔剂和合成树脂在甲基丙烯酸酯均聚物或甲基丙烯酸酯共聚物上，或者与 钎焊组合物，其包含钎焊剂，钎焊金属和所述合成树脂。 在优选的实施方案中，这种涂层通过施加到铝挤压多腔扁平管的表面来提供，所述组合物加入到有机溶剂中并具有分子结构，其中碳与氧的原子比在2和 3，通过辊式印刷技术。

公开(公告)号：US07989087B2

公开(公告)日：2011-08-02

申请号：US11764372

申请日：2007-06-18

申请人： Yuji Suzuki ,  Yuji Hisatomi ,  Yoshiharu Hasegawa ,  Taketoshi Toyama ,  Masahiro Shimoya

发明人： Yuji Suzuki ,  Yuji Hisatomi ,  Yoshiharu Hasegawa ,  Taketoshi Toyama ,  Masahiro Shimoya

IPC分类号： B32B15/20 ,  F28F21/08 ,  C22C21/04

CPC分类号： B23K35/0266 ,  B23K35/286 ,  Y10S165/905 ,  Y10S428/925 ,  Y10T428/12764

摘要： A brazing fin material for heat exchangers includes a core material and a filler metal clad on each side of the core material, wherein the core material is an aluminum alloy including manganese, the filler metal is an aluminum alloy including 6 to 9.5 mass % of silicon, silicon particles in the filler metal have an average circle equivalent diameter of 3 μm or less, and the brazing fin material has a thickness of 0.06 mm or less.

摘要翻译： 用于热交换器的钎焊翅片材料包括在芯材的每一侧包覆的芯材和填充金属，其中芯材是包括锰的铝合金，该填充金属是含有6至9.5质量％的硅的铝合金 填充金属中的硅颗粒的平均圆当量直径为3μm以下，钎焊翅片材料的厚度为0.06mm以下。

公开(公告)号：US20060102328A1

公开(公告)日：2006-05-18

申请号：US11280632

申请日：2005-11-16

申请人： Taketoshi Toyama ,  Yoshiharu Hasegawa ,  Naohiro Ohya ,  Yasunaga Itoh ,  Yuji Hisatomi ,  Hirokazu Tanaka

发明人： Taketoshi Toyama ,  Yoshiharu Hasegawa ,  Naohiro Ohya ,  Yasunaga Itoh ,  Yuji Hisatomi ,  Hirokazu Tanaka

IPC分类号： F28F13/18

CPC分类号： B23K1/0012 ,  B23K2101/14 ,  F28D1/0391 ,  F28D2021/0085 ,  F28F3/025 ,  F28F19/06 ,  F28F21/084 ,  F28F21/089

摘要： A sheet material for the tube 10 includes: a core material 10b; and a sacrifical corrosion material 10c clad on one face of the core material 10b which becomes an outside of the tube 10. A sheet material for the fin is a bare aluminum material on which a brazing filler metal is not clad. A mixture composition 10e, in which powder of a brazing filler metal and flux are mixed with each other, is coated on the outside of the tube 10. The tube 10 and the fin are brazed to each other with this mixture composition 10e. Even after the completion of brazing, the sacrifical corrosion material 10c remains on the outside of the tube 10.

摘要翻译： 用于管10的片材包括：芯材料10b; 以及包围在成为管10外侧的芯材料10b的一个面上的牺牲腐蚀材料10c。 用于翅片的片材是裸金属材料，钎焊金属不包覆在其上。 将钎料和助熔剂的粉末彼此混合的混合物组合物10e涂覆在管10的外侧。 管10和翅片用这种混合物组合物10e彼此钎焊。 即使在钎焊完成之后，牺牲腐蚀材料10c保留在管10的外侧。

公开(公告)号：US07018722B2

公开(公告)日：2006-03-28

申请号：US10601752

申请日：2003-06-23

申请人： Taketoshi Toyama ,  Koji Hirao ,  Takashi Hatori ,  Yuji Hisatomi ,  Yasunaga Itoh ,  Yoshifusa Shoji

发明人： Taketoshi Toyama ,  Koji Hirao ,  Takashi Hatori ,  Yuji Hisatomi ,  Yasunaga Itoh ,  Yoshifusa Shoji

IPC分类号： B32B15/20 ,  F28F21/08 ,  C22C21/04

CPC分类号： F28F21/084 ,  B23K35/286 ,  B32B15/016 ,  C22C21/00 ,  Y10S165/905 ,  Y10S428/925 ,  Y10T428/12764

摘要： The present invention provides an aluminum alloy fin material for heat exchangers which has a thickness of 80 μm (0.08 mm) or less and excels in joinability to a tube material and in intergranular corrosion resistance. The aluminum alloy fin material is an aluminum alloy bare fin material or a brazing fin material which has a thickness of 80 μm or less and is incorporated into a heat exchanger made of an aluminum alloy manufactured by brazing through an Al—Si alloy filler metal. The structure of the core material before brazing is a fiber structure, and the crystal grain diameter of the structure after brazing is 50–250 μm. The Si concentration in the Si dissolution area on the surface of the fin material and at the center of the thickness of the fin material after brazing is preferably 0.8% or more and 0.7% or less, respectively.

摘要翻译： 本发明提供一种用于热交换器的铝合金翅片材料，其具有80μm（0.08mm）或更小的厚度，并且与管材的接合性和耐晶间腐蚀性优异。 铝合金翅片材料是铝合金裸翅片材料或厚度为80μm以下的钎焊翅片材料，并且被并入由通过Al-Si合金填料金属钎焊制造的铝合金制成的热交换器中。 钎焊前的芯材的结构是纤维结构，钎焊后的结构的晶粒直径为50〜250μm。 翅片材料表面上的Si溶解区域中的Si浓度和钎焊后的翅片材料的厚度的中心分别优选为0.8％以上且0.7％以下。

公开(公告)号：US09132518B2

公开(公告)日：2015-09-15

申请号：US13699182

申请日：2011-05-10

申请人： Naoki Yamashita ,  Yuji Hisatomi

发明人： Naoki Yamashita ,  Yuji Hisatomi

IPC分类号： B23P15/26 ,  B23K1/00 ,  B23K1/008 ,  B23K1/20 ,  B23K35/00 ,  B23K35/28 ,  B23K35/365 ,  C22C21/00 ,  F28F1/02 ,  F28F1/12 ,  F28F21/08 ,  C23C26/02 ,  C23C30/00

CPC分类号： B23P15/26 ,  B23K1/0012 ,  B23K1/008 ,  B23K1/203 ,  B23K35/002 ,  B23K35/28 ,  B23K35/282 ,  B23K35/365 ,  B23K2101/14 ,  C22C21/00 ,  C23C26/02 ,  C23C30/00 ,  F28F1/022 ,  F28F1/126 ,  F28F21/084 ,  F28F21/089 ,  F28F2255/16 ,  Y10T29/49378

摘要： A method for producing an aluminum alloy heat exchanger includes applying a coating material prepared by mixing an Si powder, a flux powder, and a binder to a surface of a multiport flat refrigerant tube, assembling an aluminum alloy bare fin with the multiport flat refrigerant tube, and brazing the multiport flat refrigerant tube and the aluminum alloy bare fin to obtain an aluminum alloy heat exchanger, the multiport flat refrigerant tube being formed of an aluminum alloy extruded material that includes 0.5 to 1.7 mass % of Mn, less than 0.10 mass % of Si, and less than 0.10 mass % of Cu, with the balance being Al and unavoidable impurities, the aluminum alloy bare fin being a corrugated fin that is obtained by forming an Al—Mn—Zn alloy material, the coating material being prepared by mixing an Si powder, a Zn-containing compound flux powder, a Zn-free compound flux powder, and a binder, the Si powder being applied in an amount of 1 to 4 g/m2, and the aluminum alloy heat exchanger obtained by brazing having a configuration in which a deep area of the refrigerant tube has the highest potential, and the potential decreases in order from a surface area of the refrigerant tube, a fin joint fillet, and the fin.

摘要翻译： 一种铝合金热交换器的制造方法，其特征在于，将通过将Si粉末，助熔剂粉末和粘合剂混合而成的涂料施加到多端口平面制冷剂管的表面，将铝合金裸翅片与多端口平面制冷剂管 并且将多孔扁平制冷剂管和铝合金裸翅片钎焊以获得铝合金热交换器，所述多端口平面制冷剂管由包含0.5至1.7质量％的Mn，小于0.10质量％的铝合金挤压材料形成， 的Si，小于0.10质量％的Cu，余量为Al和不可避免的杂质，铝合金裸翅片为通过形成Al-Mn-Zn合金材料而获得的波纹状散热片，该涂料由 混合Si粉末，含Zn化合物焊剂粉末，不含Zn的复合焊剂粉末和粘合剂，施加的Si粉末的量为1〜4g / m 2，铝合金热交换 r，其制冷剂管的深部区域具有最高的电位，电位从制冷剂管的表面积，翅片接头圆角和翅片的顺序下降。

公开(公告)号：US20120145365A1

公开(公告)日：2012-06-14

申请号：US13378854

申请日：2010-06-21

申请人： Naoki Yamashita ,  Yasunaga Itoh ,  Yuji Hisatomi

发明人： Naoki Yamashita ,  Yasunaga Itoh ,  Yuji Hisatomi

IPC分类号： F28F13/18 ,  C22F1/04

CPC分类号： B21D53/06 ,  B23K35/282 ,  B23K35/3607 ,  B23K35/362 ,  B23K2101/14 ,  C22C21/00 ,  C22C21/02 ,  C22C21/10 ,  C22C21/14 ,  F28D2021/0084 ,  F28D2021/0085 ,  F28F1/00 ,  F28F19/02 ,  F28F19/06 ,  F28F21/084 ,  F28F2275/04

摘要： An aluminum alloy heat exchanger is produced by applying a coating material that is prepared by adding a binder to a mixture of an Si powder and a Zn-containing compound flux powder to a surface of an aluminum alloy refrigerant tube, assembling a bare fin that is formed of an Al—Mn—Zn alloy with the refrigerant tube, and brazing the refrigerant tube and the bare fin by heating in an atmosphere-controlled furnace, the refrigerant tube being an extruded product of an aluminum alloy that comprises 0.5 to 1.7% (mass %, hereinafter the same) of Mn, less than 0.10% of Cu, and less than 0.10% of Si, with the balance being Al and unavoidable impurities, a mixing ratio of the Si powder to the Zn-containing compound flux powder being 10:90 to 40:60, the binder being added in an amount of 5 to 40% based on the total amount of the coating material, the coating material being applied to an outer surface of the refrigerant tube so that the total amount of the Si powder and the Zn-containing compound flux powder is 5 to 30 g/m2, the surface of the refrigerant tube subjected to brazing having a potential lower than that of an area of the refrigerant tube that is deeper than a diffusion depth of Si and Zn by 20 to 200 mV, and a potential of the fin being lower than that of a deep area of the refrigerant tube.

摘要翻译： 通过将通过将Si粉末和含Zn化合物助焊剂粉末的混合物中的粘合剂添加到铝合金制冷剂管的表面而制备的涂料来制造铝合金热交换器， 由Al-Mn-Zn合金与制冷剂管形成，并且在气氛控制的炉中通过加热钎焊制冷剂管和裸露的翅片，制冷剂管是铝合金的挤出产品，其包含0.5-1.7％（ 质量％，以下相同），小于0.10％的Cu和小于0.10％的Si，余量为Al和不可避免的杂质，Si粉末与含Zn化合物焊剂粉末的混合比为 10:90〜40:60，粘合剂的添加量相对于涂料总量为5〜40％，涂料施加到制冷剂管的外表面， Si粉末和含Zn组合物 焊剂粉末为5〜30g / m 2，制冷剂管的表面的电位低于比Si和Zn的扩散深度高20〜200mV的制冷剂管的面积的电位， 并且翅片的电位低于制冷剂管的深部区域的电位。

公开(公告)号：US20100263768A1

公开(公告)日：2010-10-21

申请号：US12798315

申请日：2010-04-01

申请人： Yuji Hisatomi ,  Naoki Yamashita ,  Yasunaga Itoh

发明人： Yuji Hisatomi ,  Naoki Yamashita ,  Yasunaga Itoh

IPC分类号： C22F1/057 ,  C22C21/12

CPC分类号： B23K35/22 ,  B23K1/0012 ,  B23K35/286 ,  B23K35/288 ,  B23K2101/14 ,  B32B15/016 ,  C22C21/00 ,  C22C21/02 ,  F28F1/022 ,  F28F21/084

摘要： An aluminum alloy clad sheet for heat exchangers includes a core material, a cladding material 1, and a cladding material 2, one side and the other side of the core material being respectively clad with the cladding material 1 and the cladding material 2, the core material containing 0.5 to 1.2% of Si, 0.2 to 1.0% of Cu, and 1.0 to 1.8% of Mn, with the balance being Al and unavoidable impurities, the cladding material 1 containing 3 to 6% of Si, 2 to 8% of Zn, and at least one of 0.3 to 1.8% of Mn and 0.05 to 0.3% of Ti, with the balance being Al and unavoidable impurities, and the cladding material 2 containing 6 to 13% of Si, with the balance being Al and unavoidable impurities, the cladding material 1 being positioned on the outer side of the aluminum alloy clad sheet during use.

摘要翻译： 用于热交换器的铝合金包覆片包括芯材料，包层材料1和包覆材料2，芯材的一侧和另一侧分别包覆包层材料1和包层材料2，芯体 含有0.5〜1.2％的Si，0.2〜1.0％的Cu和1.0〜1.8％的Mn，余量为Al和不可避免的杂质，包含3〜6％的Si的包层材料1，2〜8％的Si Zn，以及0.3〜1.8％的Mn和0.05〜0.3％的Ti中的至少一种，余量为Al和不可避免的杂质，包层材料2含有6〜13％的Si，余量为Al，不可避免 杂质，包覆材料1在使用期间位于铝合金包覆板的外侧。

公开(公告)号：US09440315B2

公开(公告)日：2016-09-13

申请号：US13378854

申请日：2010-06-21

申请人： Naoki Yamashita ,  Yasunaga Itoh ,  Yuji Hisatomi

发明人： Naoki Yamashita ,  Yasunaga Itoh ,  Yuji Hisatomi

IPC分类号： B23K35/362 ,  B23K35/28 ,  B23K35/36 ,  C22C21/00 ,  C22C21/02 ,  C22C21/10 ,  C22C21/14 ,  F28F19/02 ,  F28F21/08 ,  F28D21/00

CPC分类号： B21D53/06 ,  B23K35/282 ,  B23K35/3607 ,  B23K35/362 ,  B23K2101/14 ,  C22C21/00 ,  C22C21/02 ,  C22C21/10 ,  C22C21/14 ,  F28D2021/0084 ,  F28D2021/0085 ,  F28F1/00 ,  F28F19/02 ,  F28F19/06 ,  F28F21/084 ,  F28F2275/04

摘要： An aluminum alloy heat exchanger is produced by applying a coating material that is prepared by adding a binder to a mixture of an Si powder and a Zn-containing compound flux powder to a surface of an aluminum alloy refrigerant tube, assembling a bare fin that is formed of an Al—Mn—Zn alloy with the refrigerant tube, and brazing the refrigerant tube and the bare fin by heating in an atmosphere-controlled furnace, the refrigerant tube being an extruded product of an aluminum alloy that comprises 0.5 to 1.7% (mass %, hereinafter the same) of Mn, less than 0.10% of Cu, and less than 0.10% of Si, with the balance being Al and unavoidable impurities, a mixing ratio of the Si powder to the Zn-containing compound flux powder being 10:90 to 40:60, the binder being added in an amount of 5 to 40% based on the total amount of the coating material, the coating material being applied to an outer surface of the refrigerant tube so that the total amount of the Si powder and the Zn-containing compound flux powder is 5 to 30 g/m2, the surface of the refrigerant tube subjected to brazing having a potential lower than that of an area of the refrigerant tube that is deeper than a diffusion depth of Si and Zn by 20 to 200 mV, and a potential of the fin being lower than that of a deep area of the refrigerant tube.

摘要翻译： 通过将通过将Si粉末和含Zn化合物助焊剂粉末的混合物中的粘合剂添加到铝合金制冷剂管的表面而制备的涂料来制造铝合金热交换器， 由Al-Mn-Zn合金与制冷剂管形成，并且在气氛控制的炉中通过加热钎焊制冷剂管和裸露的翅片，制冷剂管是铝合金的挤出产品，其包含0.5-1.7％（ 质量％，以下相同），小于0.10％的Cu和小于0.10％的Si，余量为Al和不可避免的杂质，Si粉末与含Zn化合物焊剂粉末的混合比为 10:90〜40:60，粘合剂的添加量相对于涂料总量为5〜40％，涂料施加到制冷剂管的外表面， Si粉末和含Zn组合物 焊剂粉末为5〜30g / m 2，制冷剂管的表面的电位低于比Si和Zn的扩散深度高20〜200mV的制冷剂管的面积的电位， 并且翅片的电位低于制冷剂管的深部区域的电位。