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公开(公告)号：US4353802A
公开(公告)日：1982-10-12
申请号：US86192
申请日：1979-10-18
申请人： Shigeyoshi Hara , Yuzuru Hayashi , Takeyuki Kawaguchi , Noriaki Sasaki , Yutaka Taketani , Hiroyoshi Minematsu
发明人： Shigeyoshi Hara , Yuzuru Hayashi , Takeyuki Kawaguchi , Noriaki Sasaki , Yutaka Taketani , Hiroyoshi Minematsu
IPC分类号： B01D61/08 , B01D69/12 , B01D71/40 , B01D71/44 , B01D71/48 , B01D71/52 , B01D71/60 , B01D71/66 , B01D71/82 , B01D13/00
CPC分类号： B01D71/60 , B01D69/125 , B01D71/44
摘要： A semipermeable composite membrane comprising a thin semipermeable film of a polymeric material deposited on one side of a microporous substrate, the polymeric material being prepared by crosslinking a soluble polymer containing at least 30 mole % of a recurring unit of the formula ##STR1## wherein all symbols are as defined herein, and having at least 0.5 milliequivalent, per gram of said polymer, of an amino group containing 1 or 2 active hydrogen atoms, with a polyfunctional compound containing at least two functional groups capable of reacting with the amino group having 1 or 2 active hydrogen atoms; and a process for preparing the same. The semipermeable composite membrane of this invention is especially useful for desalination of saline or brackish water by reverse osmosis.
摘要翻译： 一种半透性复合膜，其包含沉积在微孔基材的一侧上的聚合材料的薄的半透膜，所述聚合物材料通过交联含有至少30摩尔％的式（IMAGE）的重复单元的可溶性聚合物制备，其中所有 符号如本文所定义，并且每克所述聚合物具有至少0.5毫当量的含有1或2个活性氢原子的氨基，和具有至少两个能够与具有1个氨基的氨基反应的官能团的多官能化合物 或2个活性氢原子; 及其制备方法。 本发明的半透膜复合膜特别适用于通过反渗透脱盐盐水或微咸水。
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公开(公告)号：US4360434A
公开(公告)日：1982-11-23
申请号：US225324
申请日：1981-01-15
CPC分类号： B01D67/0093 , B01D69/125 , B01D71/60 , G01N27/40 , B01D2323/30 , Y10T428/249978 , Y10T428/249981
摘要： An amphoteric ion-permeable composite membrane composed of a microporous substrate, and supported on the substrate, a thin amphoteric ion-exchange film formed of an active amino group-containing polymer which has been interfacially crosslinked at least at the surface portion of the thin film, said membrane being produced by forming a thin layer comprising an active amino group-containing polymer containing 1.0 to 23 milliequivalents/g, as amino equivalent, of an active amino group selected from primary and secondary amino groups and 0 to 18 milliequivalents/g, as amino equivalent, of a tertiary amino group and/or an ammonium salt group per molecule with the total amino content thereof being in the range of 2.0 to 23 milliequivalents/g on the microporous substrate and then contacting the thin layer on the substrate interfacially with a polyfunctional aromatic compound containing at least two functional groups selected from carbonyl halide groups, sulfonyl halide groups, carboxylic acid anhydride groups, sulfonic acid anhydride groups and derivative groups of carboxylic acids and sulfonic acids having equivalent reactivity to the aforesaid halide and anhydride groups.
摘要翻译： 由微孔基材构成并负载在基板上的两性离子透过性复合膜由至少在薄膜的表面部分进行了界面交联的含活性氨基聚合物形成的薄的两性离子交换膜 所述膜通过形成包含含有选自伯氨基和仲氨基的活性氨基和0至18毫当量/克的作为氨基当量的1.0至23毫当量/克的含有活性氨基的聚合物的薄层， 作为氨基当量的每个分子的叔氨基和/或铵盐基团，其总氨基含量在微孔基材上在2.0至23毫当量/ g的范围内，然后使基底上的薄层与 含有至少两个选自羰基卤基，磺酰卤基，羧酸的官能团的多官能芳族化合物 酸酐基团，磺酸酐基团和与上述卤化物和酸酐基团具有等同反应性的羧酸和磺酸的衍生基团。
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公开(公告)号：US4388189A
公开(公告)日：1983-06-14
申请号：US220081
申请日：1980-12-24
IPC分类号： B01D71/28 , B01D69/12 , B01D71/38 , B01D71/48 , B01D71/52 , B01D71/60 , B01D71/66 , B01D71/82 , B01D31/00
CPC分类号： B01D69/125 , B01D71/60
摘要： In a process for producing a semipermeable composite membrane which comprises forming on a microporous substrate a thin layer of a polymeric material comprising a polyamino polymer containing at least 1 milliequivalent, per gram of the polymer in the dry state, of active amino groups selected from primary amino groups and secondary amino groups, and thereafter interfacially crosslinking a surface portion of said thin layer with a crosslinking agent having at least two functional groups (a) capable of easily reacting with either the primary or secondary amino groups or both in said polymer; the improvement wherein(1) said polymeric material contains dispersed therein a polyfunctional compound having at least two functional groups (b) substantially incapable of reacting with the primary or secondary amino groups in said polymer at a temperature at which the interfacial crosslinking is carried out, but capable of reacting easily with either the primary or secondary amino groups or both in said polymer at a temperature at least 30.degree. C. higher than said crosslinking temperature, and(2) the interfacially crosslinked thin layer is heated to a temperature at which said polyfunctional compound reacts with the primary or secondary amino groups or both in said polymer.
摘要翻译： 在一种制备半透膜复合膜的方法中，该方法包括在微孔基材上形成包含聚氨基聚合物的聚合物材料的薄层，所述聚合物材料含有至少1毫当量的每克干燥状态的聚合物，选自主要 氨基和仲氨基，然后用具有至少两个能够容易地与所述聚合物中的伯或仲氨基反应的二官能团（a）的交联剂与所述薄层的表面部分进行界面交联; 改进之处在于（1）所述聚合材料含有分散有至少两个官能团的多官能化合物（b）在进行界面交联的温度下基本上不能与所述聚合物中的伯或仲氨基发生反应， 但能够在高于所述交联温度的至少30℃的温度下容易地与所述聚合物中的伯或仲氨基或两者反应，和（2）将界面交联的薄层加热至所述 多官能化合物与所述聚合物中的伯或仲氨基或两者反应。
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公开(公告)号：US4302336A
公开(公告)日：1981-11-24
申请号：US72044
申请日：1979-09-04
申请人： Takeyuki Kawaguchi , Yutaka Taketani , Noriaki Sasaki , Hiroyoshi Minematsu , Yuzuru Hayashi , Shigeyoshi Hara
发明人： Takeyuki Kawaguchi , Yutaka Taketani , Noriaki Sasaki , Hiroyoshi Minematsu , Yuzuru Hayashi , Shigeyoshi Hara
IPC分类号： C08J9/28 , B01D69/12 , B01D71/40 , B01D71/44 , B01D71/60 , B01D71/82 , C08G85/00 , B01D3/00 , B01D13/00
CPC分类号： B01D71/60 , B01D69/125 , B01D71/44 , C08G85/004
摘要： A semipermeable composite membrane comprising a thin semipermeable film of a polymeric material deposited on one side of a microporous substrate, said polymeric material being prepared by crosslinking a soluble polymer containing at least 30 mole % of a recurring unit of the formula ##STR1## wherein all symbols are as defined in claim 1, and having at least 0.2 milliequivalent, per gram of said polymer, of an amino group containing 1 or 2 active hydrogen atoms, with a polyfunctional compound containing at least two functional groups capable of reacting with the amino group having 1 or 2 active hydrogen atoms; and a process for preparing the same. The semipermeable composite membrane of this invention is especially useful for desalination of saline or brackish water by reverse osmosis.
摘要翻译： 一种半透膜复合膜，其包含沉积在微孔基材的一侧上的聚合物材料的薄的半透膜，所述聚合物材料通过交联含有至少30摩尔％的式“IMAGE”的重复单元的可溶性聚合物制备，其中所有 符号如权利要求1中所定义，并且每克所述聚合物具有至少0.2毫当量的含有1或2个活性氢原子的氨基，和具有至少两个能够与氨基反应的官能团的多官能化合物 具有1或2个活性氢原子; 及其制备方法。 本发明的半透膜复合膜特别适用于通过反渗透脱盐盐水或微咸水。
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公开(公告)号：US4242208A
公开(公告)日：1980-12-30
申请号：US39559
申请日：1979-05-16
申请人： Takeyuki Kawaguchi , Yutaka Taketani , Hiroyoshi Minematsu , Noriaki Sasaki , Yuzuru Hayashi , Shigeyoshi Hara
发明人： Takeyuki Kawaguchi , Yutaka Taketani , Hiroyoshi Minematsu , Noriaki Sasaki , Yuzuru Hayashi , Shigeyoshi Hara
IPC分类号： B01D71/82 , B01D69/12 , B01D71/62 , B01D71/66 , B01D39/00 , B01D13/00 , B05D5/00 , C08C19/22
CPC分类号： B01D71/66 , B01D69/125 , B01D71/62
摘要： A semipermeable composite membrane comprising a thin semipermeable film of a polymeric material deposited on one side of the microporous substrate, said polymeric material being prepared by interfacial crosslinking of a polymer containing a recurring unit of the formula ##STR1## wherein each of R.sub.1 and R.sub.2 represents a hydrogen atom or a methyl group, and W.sub.1 represents a direct bonding or a sulfonyl group (--SO.sub.2 --), with a polyfunctional compound containing at least two functional groups selected from acid halide, sulfonyl halide, isocyanate, N-haloformyl, haloformate and acid anhydride groups; and a process for producing the same. The semipermeable composite membrane of this invention is especially useful for desalination of saline or brackish water by reverse osmosis.
摘要翻译： 一种半透膜复合膜，其包含沉积在微孔基材的一侧上的聚合材料的薄的半透膜，所述聚合物材料通过含有式（I）的重复单元的聚合物的界面交联制备，其中每个R 1 并且R 2表示氢原子或甲基，并且W 1表示直接键合或磺酰基（-SO 2 - ），其中多官能化合物含有至少两个选自酰卤，磺酰卤，异氰酸酯，N-卤代甲酰基 ，卤代甲酸酯和酸酐基团; 及其制造方法。 本发明的半透膜复合膜特别适用于通过反渗透脱盐盐水或微咸水。
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公开(公告)号：US5061521A
公开(公告)日：1991-10-29
申请号：US451892
申请日：1989-12-18
CPC分类号： C08J7/126 , C08G61/08 , C08J7/12 , C08L65/00 , C08J2365/00
摘要： A method for improving the properties of a metathesis polymerized cycloolefin article by treating with molecular halogen in an organic solvent. Degree of treatment can be regulated according to the swelling power of the solvent for the polymer. Improved properties include improved flame retardance, oxidation resistance and surface properties.
摘要翻译： 一种通过在有机溶剂中用分子卤素处理来改善易位聚合的环烯烃制品的性质的方法。 可以根据溶剂对聚合物的溶胀力来调节处理程度。 改进的性能包括改进的阻燃性，抗氧化性和表面性能。
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7.发明授权Polyamideimides containing 3,4'-diamino-diphenylether as diamine component, with plasticizer 失效含有3,4'-二氨基 - 二苯基醚作为二胺组分的聚酰胺酰亚胺与增塑剂
公开(公告)号：US4902740A
公开(公告)日：1990-02-20
申请号：US268479
申请日：1988-11-08
申请人： Shigeyoshi Hara , Hiroo Inata , Shunichi Matsumura
发明人： Shigeyoshi Hara , Hiroo Inata , Shunichi Matsumura
CPC分类号： C08L79/08 , C08G73/105 , C08G73/1071 , C08G73/14 , C08K5/41 , H05K1/0346 , H05K3/386
摘要： A polyamideimide having an inherent viscosity of above 0.48 which comprises a unit of the following formula (II) ##STR1## and a unit of the following formula (IV) ##STR2## as main units forming the molecular chains of the polyamideimide, and an intimate mixture of the polyamideimide and a plasticizing material for the polyamideimide.
摘要翻译： 具有特性粘度高于0.48的聚酰胺酰亚胺，其包含下式（II）的单元：（II）和下式（IV）的单元作为形成分子链的主要单元 聚酰胺酰亚胺和聚酰胺酰亚胺与聚酰胺酰亚胺的增塑材料的紧密混合物。
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公开(公告)号：US4069206A
公开(公告)日：1978-01-17
申请号：US550738
申请日：1975-02-18
申请人： Shigeyoshi Hara , Masao Senoo , Koh Mori , Yutaka Taketani
发明人： Shigeyoshi Hara , Masao Senoo , Koh Mori , Yutaka Taketani
CPC分类号： C08G69/00 , C08G73/02 , C08G73/024 , C08G73/0253 , C08G73/028
摘要： Novel aromatic imine polymers containing as at least a part of its entire recurring units an aromatic imino group ##STR1## wherein .phi. is an aromatic ring group having a valence of at least two and has at least one electron-attracting group with respect to the group ##STR2## and R.sub.1 is a hydrogen atom or a non-aromatic hydrocarbon residue having a valence of at least 1. These polymers find a wide variety of applications by utilizing their thermal stability and various other desirable properties such as reducibility or photosensitivity. The polymers are prepared by reacting specific aromatic dihalogen compound with specific difunctional amino-containing compounds in an inert organic solvent in the presence of an acid acceptor. Copolymers can be obtained by carrying out the reaction using specific difunctional comonomers.
摘要翻译： 含有至少一部分其全部重复单元的芳族亚胺聚合物是芳香族亚氨基，其中phi是具有至少两个化合价的芳环基团，并且相对于该基团具有至少一个吸电子基团 R1是氢原子或至少为1价的非芳族烃残基。这些聚合物通过利用它们的热稳定性和各种其它所需的性质如还原性或光敏性，可以找到各种应用。 通过在酸性受体的存在下，在惰性有机溶剂中使特定芳族二卤化物与特定的双官能含氨基化合物反应来制备聚合物。 可以通过使用特定的双官能共聚单体进行反应来获得共聚物。
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公开(公告)号：US5045362A
公开(公告)日：1991-09-03
申请号：US451703
申请日：1989-12-18
申请人： Shigeyoshi Hara , Umewaka Nakatani
发明人： Shigeyoshi Hara , Umewaka Nakatani
CPC分类号： C08J7/126 , C08G61/08 , C08J7/12 , C08L65/00 , C08J2365/00
摘要： A metathesis polymerized cycloolefin article may be improved by treating with halogen halide in an organic solvent. Degree of treatment can be regulated according to the swelling power of the solvent for the polymer. Improved properties include improved flame retardance, oxidation resistance and surface properties.
摘要翻译： 复分解聚合的环烯烃制品可以通过用卤代卤化物在有机溶剂中处理来改进。 可以根据溶剂对聚合物的溶胀力来调节处理程度。 改进的性能包括改进的阻燃性，抗氧化性和表面性能。
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公开(公告)号：US5019620A
公开(公告)日：1991-05-28
申请号：US589292
申请日：1990-09-27
申请人： Zenichiro Endo , Shigeyoshi Hara
发明人： Zenichiro Endo , Shigeyoshi Hara
CPC分类号： C08G61/08
摘要： An elastic crosslinked metathesis polymer composition is disclosed comprised of a copolymer of a norbornene-type compound which metathesis polymerizes to a linear polymer and a norbornene-type compound having a second double bond of similar reactivity which forms a crosslinked polymer, and a hydrocarbon-based extending oil. Norbornene and dicyclopentadiene are typical comonomers. Polymerization is carried out by a RIM or resin injection molding process.
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