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公开(公告)号:US20070178394A1
公开(公告)日:2007-08-02
申请号:US11621896
申请日:2007-01-10
申请人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
发明人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
IPC分类号: G03C5/00
CPC分类号: G03F7/70616 , G03F7/0382 , G03F7/0397 , G03F7/70341 , Y10S430/106 , Y10S430/111
摘要: A resist composition which is stable relative to solvents used in immersion lithography processes and displays excellent sensitivity and resist pattern profile, and a method of forming a resist pattern that uses such a resist composition are provided. The resist composition is in accordance with predetermined parameters, or is a positive resist composition comprising a resin component (A) which contains an acid dissociable, dissolution inhibiting group and displays increased alkali solubility under the action of acid, an acid generator component (B), and an organic solvent (C), wherein the component (A) contains a structural unit (a1) derived from a (meth)acrylate ester containing an acid dissociable, dissolution inhibiting group, but contains no structural units (a0), including structural units (a0-1) containing an anhydride of a dicarboxylic acid and structural units (a0-2) containing a phenolic hydroxyl group.
摘要翻译: 提供了相对于在浸没式光刻工艺中使用的溶剂是稳定的并且显示出优异的灵敏度和抗蚀剂图案轮廓的抗蚀剂组合物,以及形成使用这种抗蚀剂组合物的抗蚀剂图案的方法。 抗蚀剂组合物是根据预定参数,或是包含含有酸解离的溶解抑制基团并在酸的作用下显示增加的碱溶性的树脂组分(A)的阳性抗蚀剂组合物,酸产生剂组分(B) 和有机溶剂(C),其中,成分(A)含有来自含有酸解离性,溶解抑制基团但不含结构单元(a0)的(甲基)丙烯酸酯的结构单元(a1) 含有二羧酸的酸酐的单元(a0-1)和含有酚羟基的结构单元(a0-2)。
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公开(公告)号:US08198004B2
公开(公告)日:2012-06-12
申请号:US12252319
申请日:2008-10-15
申请人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
发明人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
CPC分类号: G03F7/70616 , G03F7/0382 , G03F7/0397 , G03F7/70341 , Y10S430/106 , Y10S430/111
摘要: A resist composition which is stable relative to solvents used in immersion lithography processes and displays excellent sensitivity and resist pattern profile, and a method of forming a resist pattern that uses such a resist composition are provided. The resist composition is in accordance with predetermined parameters, or is a positive resist composition comprising a resin component (A) which contains an acid dissociable, dissolution inhibiting group and displays increased alkali solubility under the action of acid, an acid generator component (B), and an organic solvent (C), wherein the component (A) contains a structural unit (a1) derived from a (meth)acrylate ester containing an acid dissociable, dissolution inhibiting group, but contains no structural units (a0), including structural units (a0-1) containing an anhydride of a dicarboxylic acid and structural units (a0-2) containing a phenolic hydroxyl group.
摘要翻译: 提供了相对于在浸没式光刻工艺中使用的溶剂是稳定的并且显示出优异的灵敏度和抗蚀剂图案轮廓的抗蚀剂组合物,以及形成使用这种抗蚀剂组合物的抗蚀剂图案的方法。 抗蚀剂组合物是根据预定参数,或是包含含有酸解离的溶解抑制基团并在酸的作用下显示增加的碱溶性的树脂组分(A)的阳性抗蚀剂组合物,酸产生剂组分(B) 和有机溶剂(C),其中,成分(A)含有来自含有酸解离性,溶解抑制基团但不含结构单元(a0)的(甲基)丙烯酸酯的结构单元(a1) 含有二羧酸的酸酐的单元(a0-1)和含有酚羟基的结构单元(a0-2)。
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公开(公告)号:US07541138B2
公开(公告)日:2009-06-02
申请号:US11621895
申请日:2007-01-10
申请人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
发明人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
IPC分类号: G03F7/30
CPC分类号: G03F7/70616 , G03F7/0382 , G03F7/0397 , G03F7/70341 , Y10S430/106 , Y10S430/111
摘要: A resist composition which is stable relative to solvents used in immersion lithography processes and displays excellent sensitivity and resist pattern profile, and a method of forming a resist pattern that uses such a resist composition are provided. The resist composition is in accordance with predetermined parameters, or is a positive resist composition comprising a resin component (A) which contains an acid dissociable, dissolution inhibiting group and displays increased alkali solubility under the action of acid, an acid generator component (B), and an organic solvent (C), wherein the component (A) contains a structural unit (a1) derived from a (meth)acrylate ester containing an acid dissociable, dissolution inhibiting group, but contains no structural units (a0), including structural units (a0-1) containing an anhydride of a dicarboxylic acid and structural units (a0-2) containing a phenolic hydroxyl group.
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公开(公告)号:US20090130605A1
公开(公告)日:2009-05-21
申请号:US12252319
申请日:2008-10-15
申请人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
发明人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
IPC分类号: G03F7/20
CPC分类号: G03F7/70616 , G03F7/0382 , G03F7/0397 , G03F7/70341 , Y10S430/106 , Y10S430/111
摘要: A resist composition which is stable relative to solvents used in immersion lithography processes and displays excellent sensitivity and resist pattern profile, and a method of forming a resist pattern that uses such a resist composition are provided. The resist composition is in accordance with predetermined parameters, or is a positive resist composition comprising a resin component (A) which contains an acid dissociable, dissolution inhibiting group and displays increased alkali solubility under the action of acid, an acid generator component (B), and an organic solvent (C), wherein the component (A) contains a structural unit (a1) derived from a (meth)acrylate ester containing an acid dissociable, dissolution inhibiting group, but contains no structural units (a0), including structural units (a0-1) containing an anhydride of a dicarboxylic acid and structural units (a0-2) containing a phenolic hydroxyl group.
摘要翻译: 提供了相对于在浸没式光刻工艺中使用的溶剂是稳定的并且显示出优异的灵敏度和抗蚀剂图案轮廓的抗蚀剂组合物,以及形成使用这种抗蚀剂组合物的抗蚀剂图案的方法。 抗蚀剂组合物是根据预定参数,或是包含含有酸解离的溶解抑制基团并在酸的作用下显示增加的碱溶性的树脂组分(A)的阳性抗蚀剂组合物,酸产生剂组分(B) 和有机溶剂(C),其中,成分(A)含有来自含有酸解离性,溶解抑制基团但不含结构单元(a0)的(甲基)丙烯酸酯的结构单元(a1) 含有二羧酸的酸酐的单元(a0-1)和含有酚羟基的结构单元(a0-2)。
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公开(公告)号:US07527909B2
公开(公告)日:2009-05-05
申请号:US11621896
申请日:2007-01-10
申请人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
发明人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
CPC分类号: G03F7/70616 , G03F7/0382 , G03F7/0397 , G03F7/70341 , Y10S430/106 , Y10S430/111
摘要: A resist composition which is stable relative to solvents used in immersion lithography processes and displays excellent sensitivity and resist pattern profile, and a method of forming a resist pattern that uses such a resist composition are provided. The resist composition is in accordance with predetermined parameters, or is a positive resist composition comprising a resin component (A) which contains an acid dissociable, dissolution inhibiting group and displays increased alkali solubility under the action of acid, an acid generator component (B), and an organic solvent (C), wherein the component (A) contains a structural unit (a1) derived from a (meth)acrylate ester containing an acid dissociable, dissolution inhibiting group, but contains no structural units (a0), including structural units (a0-1) containing an anhydride of a dicarboxylic acid and structural units (a0-2) containing a phenolic hydroxyl group.
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公开(公告)号:US07501220B2
公开(公告)日:2009-03-10
申请号:US10845620
申请日:2004-05-13
申请人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
发明人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
CPC分类号: G03F7/70616 , G03F7/0382 , G03F7/0397 , G03F7/70341 , Y10S430/106 , Y10S430/111
摘要: A resist composition which is stable relative to solvents used in immersion lithography processes and displays excellent sensitivity and resist pattern profile, and a method of forming a resist pattern that uses such a resist composition are provided. The resist composition is in accordance with predetermined parameters, or is a positive resist composition comprising a resin component (A) which contains an acid dissociable, dissolution inhibiting group and displays increased alkali solubility under the action of acid, an acid generator component (B), and an organic solvent (C), wherein the component (A) contains a structural unit (a1) derived from a (meth)acrylate ester containing an acid dissociable, dissolution inhibiting group, but contains no structural units (a0), including structural units (a0-1) containing an anhydride of a dicarboxylic acid and structural units (a0-2) containing a phenolic hydroxyl group.
摘要翻译: 提供了相对于在浸没式光刻工艺中使用的溶剂是稳定的并且显示出优异的灵敏度和抗蚀剂图案轮廓的抗蚀剂组合物,以及形成使用这种抗蚀剂组合物的抗蚀剂图案的方法。 抗蚀剂组合物是根据预定参数,或是包含含有酸解离的溶解抑制基团并在酸的作用下显示增加的碱溶性的树脂组分(A)的阳性抗蚀剂组合物,酸产生剂组分(B) 和有机溶剂(C),其中,成分(A)含有来自含有酸解离性,溶解抑制基团但不含结构单元(a0)的(甲基)丙烯酸酯的结构单元(a1) 含有二羧酸的酸酐的单元(a0-1)和含有酚羟基的结构单元(a0-2)。
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公开(公告)号:US20070190436A1
公开(公告)日:2007-08-16
申请号:US11621895
申请日:2007-01-10
申请人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
发明人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
IPC分类号: G03C5/00
CPC分类号: G03F7/70616 , G03F7/0382 , G03F7/0397 , G03F7/70341 , Y10S430/106 , Y10S430/111
摘要: A resist composition which is stable relative to solvents used in immersion lithography processes and displays excellent sensitivity and resist pattern profile, and a method of forming a resist pattern that uses such a resist composition are provided. The resist composition is in accordance with predetermined parameters, or is a positive resist composition comprising a resin component (A) which contains an acid dissociable, dissolution inhibiting group and displays increased alkali solubility under the action of acid, an acid generator component (B), and an organic solvent (C), wherein the component (A) contains a structural unit (a1) derived from a (meth)acrylate ester containing an acid dissociable, dissolution inhibiting group, but contains no structural units (a0), including structural units (a0-1) containing an anhydride of a dicarboxylic acid and structural units (a0-2) containing a phenolic hydroxyl group.
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公开(公告)号:US20050014090A1
公开(公告)日:2005-01-20
申请号:US10845620
申请日:2004-05-13
申请人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
发明人: Taku Hirayama , Hideo Hada , Satoshi Fujimura , Takeshi Iwai , Mitsuru Sato , Ryoichi Takasu , Toshikazu Tachikawa , Jun Iwashita , Keita Ishiduka , Tomotaka Yamada , Toshikazu Takayama , Masaaki Yoshida
CPC分类号: G03F7/70616 , G03F7/0382 , G03F7/0397 , G03F7/70341 , Y10S430/106 , Y10S430/111
摘要: A resist composition which is stable relative to solvents used in immersion lithography processes and displays excellent sensitivity and resist pattern profile, and a method of forming a resist pattern that uses such a resist composition are provided. The resist composition is in accordance with predetermined parameters, or is a positive resist composition comprising a resin component (A) which contains an acid dissociable, dissolution inhibiting group and displays increased alkali solubility under the action of acid, an acid generator component (B), and an organic solvent (C), wherein the component (A) contains a structural unit (a1) derived from a (meth)acrylate ester containing an acid dissociable, dissolution inhibiting group, but contains no structural units (a0), including structural units (a0-1) containing an anhydride of a dicarboxylic acid and structural units (a0-2) containing a phenolic hydroxyl group.
摘要翻译: 提供了相对于在浸没式光刻工艺中使用的溶剂是稳定的并且显示出优异的灵敏度和抗蚀剂图案轮廓的抗蚀剂组合物,以及形成使用这种抗蚀剂组合物的抗蚀剂图案的方法。 抗蚀剂组合物是根据预定参数,或是包含含有酸解离的溶解抑制基团并在酸的作用下显示增加的碱溶性的树脂组分(A)的阳性抗蚀剂组合物,酸产生剂组分(B) 和有机溶剂(C),其中,成分(A)含有来自含有酸解离性,溶解抑制基团但不含结构单元(a0)的(甲基)丙烯酸酯的结构单元(a1) 含有二羧酸的酸酐的单元(a0-1)和含有酚羟基的结构单元(a0-2)。
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公开(公告)号:US20060154171A1
公开(公告)日:2006-07-13
申请号:US10546573
申请日:2004-02-25
申请人: Taku Hirayama , Satoshi Fujimura , Kataro Endo , Keita Ishiduka
发明人: Taku Hirayama , Satoshi Fujimura , Kataro Endo , Keita Ishiduka
IPC分类号: G03C1/76
CPC分类号: G03F7/0397 , G03F7/0045 , G03F7/0395 , G03F7/2041
摘要: There is provided a positive photoresist composition for use in a method of forming a resist pattern that includes an immersion lithography step, which exhibits little line edge roughness and an excellent resist pattern profile. This photoresist composition includes a resin component (A), an acid generator component (B), an organic solvent (C), and a nitrogen-containing organic compound (D) represented by a general formula (1) shown below: [wherein, X, Y, and Z each represent, independently, an alkyl group that may contain an aryl group bonded to a terminal (although two terminals from the groups X, Y, and Z may also be bonded together to form a cyclic structure), at least one of X, Y, and Z contains a polar group, and the molecular weight of the compound (D) is at least 200].
摘要翻译: 提供了一种用于形成抗蚀剂图案的方法中的正型光致抗蚀剂组合物,其包括浸渍光刻步骤,其显示出较小的线边缘粗糙度和优异的抗蚀剂图案轮廓。 该光致抗蚀剂组合物包含由下述通式(1)表示的树脂组分(A),酸产生剂组分(B),有机溶剂(C)和含氮有机化合物(D):[其中, X,Y和Z各自独立地表示可以含有与末端键合的芳基的烷基(尽管X,Y和Z组中的两个末端也可以结合在一起形成环状结构), X,Y和Z中的至少一个含有极性基团,化合物(D)的分子量至少为200]。
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10.
公开(公告)号:US06982140B2
公开(公告)日:2006-01-03
申请号:US10466172
申请日:2002-11-29
申请人: Hideo Hada , Satoshi Fujimura , Jun Iwashita
发明人: Hideo Hada , Satoshi Fujimura , Jun Iwashita
CPC分类号: G03F7/0397 , Y10S430/106 , Y10S430/111
摘要: There is provided a positive type resist composition formed by dissolving (A) a resin component with a unit derived from a (meth)acrylate ester in the principal chain, for which the solubility in alkali increases under the action of acid, and (B) an acid generator component which generates acid on exposure, in an organic solvent component (C), wherein the resin component (A) is a copolymer comprising (a1) a unit derived from a (meth)acrylate ester comprising an acid dissociable, dissolution inhibiting group containing a polycyclic group, (a2) a unit derived from a (meth)acrylate ester comprising a lactone containing monocyclic group or polycyclic group, (a3) a unit derived from a (meth)acrylate ester comprising a hydroxyl group containing polycyclic group, and (a4) a unit derived from a (meth)acrylate ester comprising a polycyclic group which is different from the unit (a1), the unit (a2) and the unit (a3). This composition provides a chemically amplified positive type resist composition which displays excellent resolution, enables the depth of focus range of an isolated resist pattern to be improved, and enables the proximity effect to be suppressed.
摘要翻译: 提供一种正型抗蚀剂组合物,其通过将(A)树脂组分与主链中衍生自(甲基)丙烯酸酯的单元溶解,其中在碱的作用下碱的溶解度增加,(B) 一种在有机溶剂组分(C)中暴露时产生酸的酸产生剂组分,其中树脂组分(A)是共聚物,其包含(a1)衍生自(甲基)丙烯酸酯的单元,其包含酸解离,溶解抑制 含有多环基团的基团,(a2)由含有内酯单体或多环基团的(甲基)丙烯酸酯衍生的单元,(a3)由含有羟基的多环基团的(甲基)丙烯酸酯衍生的单元, 和(a4)衍生自包含与单元(a1),单元(a2)和单元(a3)不同的多环基团的(甲基)丙烯酸酯的单元。 该组合物提供显示出优异的分辨率的化学放大正型抗蚀剂组合物,能够提高隔离抗蚀剂图案的聚焦范围的深度,并且能够抑制邻近效应。
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