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    Vulcanization accelerator, a means for accelerating vulcanization and an improved rubber product containing said accelerator therein
    5.
    发明授权
    Vulcanization accelerator, a means for accelerating vulcanization and an improved rubber product containing said accelerator therein 失效
    硫化促进剂，加速硫化的手段和含有所述促进剂的改进的橡胶制品

    公开(公告)号：US4687756A

    公开(公告)日：1987-08-18

    申请号：US800703

    申请日：1985-11-22

    申请人： Akinori Okamoto ,  Tetsuo Yamaguchi ,  Haruki Okamura ,  Eizo Okino

    发明人： Akinori Okamoto ,  Tetsuo Yamaguchi ,  Haruki Okamura ,  Eizo Okino

    IPC分类号： C08K5/44 ,  C07D295/21 ,  C08J5/06 ,  C08K5/36 ,  C08K5/39 ,  C08K5/40 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L33/00 ,  C08L33/02 ,  C08L67/00 ,  C08L101/00 ,  B01J31/02

    CPC分类号： C07D295/21 ,  C08K5/39 ,  Y10T428/2969

    摘要： A vulcanization accelerator containing as an active ingredient a compound having at least one dithiocarbamoyl group, which is shown by the following general formula [I], a means for accelerating vulcanization by adding said compound and rubber products having improved quality which is attained by using said compound as a vulcanization accelerator: ##STR1## wherein R.sup.1 stands for an alkyl group having one to 12 carbon atoms, a cycloalkyl group having 3 to 8 carbon atoms, an aryl group having 6 to 12 carbon atoms or an aralkyl group having 7 to 13 carbon atoms, A stands for a group shown by the formula ##STR2## or metallic atom; in which x represents zero or an integer of 1 to 5, R.sup.2 is an alkyl group having one to 12 carbon atoms, a cycloalkyl group having 3 to 8 carbon atoms, an aryl group having 6 to 12 carbon atoms or an aralkyl group having 7 to 13 carbon atoms; and n is one when A stands for a group shown by the formula ##STR3## and is an integer of 1 to 4 corresponding to the valency when A stands for a metallic atom.

    摘要翻译： 一种硫化促进剂，其含有具有至少一个二硫代氨基甲酰基的化合物作为活性成分，其由以下通式[I]表示：加入所述化合物和通过使用所述的 作为硫化促进剂的化合物：其中R1表示碳原子数1〜12的烷基，碳原子数3〜8的环烷基，碳原子数6〜12的芳基或芳烷基， 7〜13个碳原子，A表示下式所示的基团或金属原子; 其中x表示0或1〜5的整数，R2表示碳原子数1〜12的烷基，碳原子数3〜8的环烷基，碳原子数6〜12的芳基或碳原子数为7的芳烷基 至13个碳原子; 并且当A代表式（IMAGE）所示的基团时，n是1，当A代表金属原子时，它是对应于化合价的1〜4的整数。

    Rubber composition
    6.
    发明授权
    Rubber composition 失效
    橡胶组合物

    公开(公告)号：US5106913A

    公开(公告)日：1992-04-21

    申请号：US496048

    申请日：1990-03-16

    申请人： Tetsuo Yamaguchi ,  Shin-ichi Yachigo ,  Tamaki Ishii ,  Masakatsu Yoshimura ,  Chinehito Ebina ,  Eizo Okino

    发明人： Tetsuo Yamaguchi ,  Shin-ichi Yachigo ,  Tamaki Ishii ,  Masakatsu Yoshimura ,  Chinehito Ebina ,  Eizo Okino

    IPC分类号： C08K5/32

    CPC分类号： C08K5/32

    摘要： Dynamic properties of vulcanized rubber are improved, without accelerating scorching property remarkably nor deteriorating flex-cracking resistance, by incorporating in a filler-containing natural or synthetic rubber composition, a dinitrodiamine derivative represented by the general formula ##STR1## wherein A represents a divalent aliphatic group, a divalent cycloaliphatic group, a divalent aromatic group or a group represented by the formula --CH.sub.2 --X--CH.sub.2 --, wherein X represents a cycloalkylene group or a phenylene group, provided that if A represents a cycloaliphatic group or an aromatic group, the two carbon atoms in A which are bonding to the nitrogen atom are not vicinal to each other; R and R' independently represent hydrogen atom or an alkyl group having 1-12 carbon atoms and may conjointly form a ring; and R" represents hydrogen atom, an aliphatic group, a cycloaliphatic group or an aromatic group. A process for producing the dinitrodiamine derivatives is also disclosed.

    摘要翻译： 通过在含有填料的天然或合成橡胶组合物中加入由通式“IMAGE”表示的二硝基二胺衍生物，其中A表示二价脂族基，可以提高硫化橡胶的动态特性，显着提高焦烧性，也不会降低耐开裂性， 基团，二价脂环族基团，二价芳族基团或由式-CH 2 -X-CH 2 - 表示的基团，其中X表示亚环烷基或亚苯基，条件是如果A表示脂环族基团或芳族基团， 与氮原子键合的A中的两个碳原子彼此不相邻; R和R'独立地表示氢原子或具有1-12个碳原子的烷基，并且可以共同形成环; R“表示氢原子，脂肪族基团，脂环族基团或芳香族基团。 还公开了二硝基二胺衍生物的制备方法。