摘要:
A stabilized resin composition comprising a resin, a piperidine derivative represented by the formula (III) ##STR1## wherein R.sub.1 is a hydrogen atom or an alkyl group having 1 to 3 carbom atoms; R.sub.2 is a hydrogen atom or an alkyl group having from 1 to 2 carbon atoms; and R.sub.3 and R.sub.4 are each independently an alkyl group having 1 to 12 carbon atoms, a phenol-type antioxidant and a sulfur-containing antioxidant. The composition simultaneously meets heat resistance, oxidation resistance and light resistance requirements.
摘要翻译:一种稳定的树脂组合物,其包含树脂,由式(III)表示的哌啶衍生物(III),其中R 1是氢原子或具有1至3个碳原子的烷基; R2是氢原子或具有1至2个碳原子的烷基; R 3和R 4各自独立地为具有1〜12个碳原子的烷基,酚型抗氧化剂和含硫抗氧化剂。 该组合物同时满足耐热性,抗氧化性和耐光性要求。
摘要:
The present invention relates to a piperidine derivative represented by the general formula (I), ##STR1## wherein R.sub.1 is a uni- or divalent carboxylic acid residue, R.sub.2 is a hydrogen atom or a C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.18 acyl group, l is an integer of 1 to 3 and n is 1 or 2,its production and a stabilizer for organic substances containing it as an effective ingredient.
摘要:
The present invention relates to a piperidine derivative represented by the general formula (I), ##STR1## wherein R.sub.1 and R.sub.2 independently represent a hydrogen atom or a C.sub.1 -C.sub.3 alkyl or C.sub.2 -C.sub.20 acyl group, R.sub.3 represents a hydrogen atom or a C.sub.1 -C.sub.20 alkyl, C.sub.6 -C.sub.20 aryl, C.sub.7 -C.sub.20 aralkyl or C.sub.2 -C.sub.20 acyl group, and l represents 1 to 3, and a stabilizer for organic substances containing said piperidine derivative as an effective ingredient.
摘要:
A stabilizer for synthetic resins containing as an effective ingredient a hindered piperidine compound represented by the general formula: ##STR1## wherein R.sub.1 represents a C.sub.1 -C.sub.18 alkyl group, R.sub.2 represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, n represents an integer of 1 to 12, and C.sub.n H.sub.2n represents a straight-chain or branched alkylene group.
摘要翻译:含有作为有效成分的由通式表示的受阻哌啶化合物的合成树脂稳定剂:其中R1表示C1-C18烷基,R2表示氢原子或C1-C4烷基,n表示整数 为1〜12,C n H 2n为直链或支链亚烷基。
摘要:
Piperidine derivatives represented by the general formula (1) ##STR1## (wherein R.sub.1 is a hydrogen atom, an alkyl group of 1 to 3 carbon atoms or an acyl group of 2 to 18 carbon atoms; and k, m and n each are independently an integer of 1 to 3), a process for producing said derivatives, and stabilizers for organic substances containing said derivatives as an active component.
摘要:
There are provided piperidine derivatives having the formula ##STR1## wherein R represents a hydrogen atom or a C.sub.1 -C.sub.3 group, and R.sup.2 and R.sup.3 represent a hydrogen atom or taken together, form ##STR2## There is also provided a method for producing the above compounds which comprises reacting a tricetonamine derivative represented by the formula ##STR3## wherein R has the same meaning as described above, or its salt with sorbitol.The subject piperdine derivatives are useful as stabilizers for preventing the deterioration of polymers by light.
摘要:
A process for producing a bisphenol compound useful as deterioration preventor capable of stabilizing organic substances against the decompositions caused by heat, light and oxygen, represented by the following general formula: ##STR1## wherein R.sub.1 represents alkyl group having 1 to 3 carbon atoms, alkenyl group having 2 to 4 carbon atoms, phenyl group or 2-phenylethenyl group; R.sub.2 represents alkyl group having 1 to 5 carbon atoms, or cyclohexyl group; R.sub.3 represents alkyl group having 1 to 9 carbon atoms, cyclohexyl group or phenyl group; and R.sub.4 represents alkyl group having 1 to 11 carbon atoms or phenyl group, which comprises reacting a carboxylic acid represented by the following general formula: ##STR2## wherein R.sub.1 is as defined above, with a bisphenol compound represented by the following general formula: ##STR3## wherein R.sub.2, R.sub.3 and R.sub.4 are as defined above, by the use of a halogenating agent in the presence of a dehydrohalogenating agent, as well as butadiene polymer compositions containing said bisphenol compounds.
摘要翻译:一种生产双酚化合物的方法,该双酚化合物可用作能够稳定有机物质以抵抗由热,光和氧引起的分解引起的降解防止剂,由以下通式表示:其中R 1表示具有1至3个碳原子的烷基,烯基 具有2至4个碳原子的基团,苯基或2-苯基乙烯基; R2表示具有1至5个碳原子的烷基或环己基; R3表示具有1至9个碳原子的烷基,环己基或苯基; R 4表示具有1〜11个碳原子的烷基或苯基,其包括使由以下通式表示的羧酸与下述通式表示的双酚化合物反应:其中R 1如上定义。 其中R2,R3和R4如上定义,在脱卤化氢剂存在下使用卤化剂,以及含有所述双酚化合物的丁二烯聚合物组合物。
摘要:
A novel stabilizing mixture composed of 1 1,3,5-tris 2-[3-(3-t-butyl-4-hydroxy-5-methyl-phenyl)-propionyloxyl] ethyl isocyanuric acid (I) and at least one sulfur-containing compound (II) selected from compounds represented by the general formulas (II-1) and (II-2): ##STR1## wherein R.sub.1 is an alkyl group having 4 to 20 carbon atoms, and ##STR2## wherein R.sub.2 is an alkyl group having 3 to 18 carbon atoms, and R.sub.3 and R.sub.4 each independently is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, is useful as a stabilizer for synthetic resins.
摘要:
A styrene polymer is stabilized by incorporating into said styrene polymer(A) a hindered piperidine compound represented by the formula ##STR1## wherein R.sub.1 is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms,R.sub.2 is a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, andR.sub.3 and R.sub.4 are each independently an alkyl group having 1 to 4 carbon atoms; and(B) a benzotriazole compound selected from the group consisting of 2-(2-hydroxy-5-methylphenyl)benzotriazole and 2-(2-hydroxy-3-tert-butyl-5-methylphenyl)-5-chlorobenzotriazole.
摘要:
Phosphorus-containing compounds of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are each a hydrogen atom or a lower alkyl group, and R.sup.3 is a lower alkyl or phenyl group. These compounds may be used as stabilizers against the action of heat, light and oxygen for organic substances and especially polyolefin resins. These phosphorus-containing compounds may be used in conjunction with other stabilizers such phenol-type and sulfur-containing antioxidants, especially in polyolefin resin compositions to produce a polyolefin resin composition having excellent resistance to light, heat and oxygen. The present invention also relates to a method of producing the compounds of the aforementioned formula by reacting ##STR2## with a disubstituted phosphonate of the formula ##STR3## wherein R.sup.1, R.sup.2 and R.sup.3 are as defined above.