公开(公告)号：US07232791B2

公开(公告)日：2007-06-19

申请号：US10505021

申请日：2003-02-28

申请人： Tatsuo Nagai ,  Kaoru Hamada ,  Tadakazu Fukuchi ,  Takashi Sasaki

发明人： Tatsuo Nagai ,  Kaoru Hamada ,  Tadakazu Fukuchi ,  Takashi Sasaki

IPC分类号： B41M5/323

CPC分类号： B41M5/34 ,  B41M5/3372 ,  B41M5/3375

摘要： In the multi colored thermally sensitive recording medium, at least one kind of dye precursor is contained in complex fine particles which contain dye precursor and polymer of multi valence isocyanate compound, further contain 4,4′-diisocyanate-3,3′-dimethyl-1,1′biphenyl and/or polymethylene.polyphenyl.polyisocyanate.

摘要翻译： 在多色热敏记录介质中，在含有染料前体和多价异氰酸酯化合物的聚合物的复合微粒中含有至少一种染料前体，还含有4,4'-二异氰酸酯-3,3'-二甲基 - 1,1'-联苯和/或聚亚甲基聚苯基多异氰酸酯。

公开(公告)号：US20060072429A1

公开(公告)日：2006-04-06

申请号：US10505021

申请日：2003-02-28

申请人： Tatsuo Nagai ,  Kaoru Hamada ,  Tadakazu Fukuchi ,  Takashi Sasaki

发明人： Tatsuo Nagai ,  Kaoru Hamada ,  Tadakazu Fukuchi ,  Takashi Sasaki

IPC分类号： G11B3/70

CPC分类号： B41M5/34 ,  B41M5/3372 ,  B41M5/3375

摘要： In the multi colored thermally sensitive recording medium, at least one kind of dye precursor is contained in complex fine particles which contain dye precursor and polymer of multi valence isocyanate compound, further contain 4,4′-diisocyanate-3,3′-dimethyl-1,1′biphenyl and/or polymethylene.polyphenyl.polyisocyanate.

摘要翻译： 在多色热敏记录介质中，在含有染料前体和多价异氰酸酯化合物的聚合物的复合微粒中含有至少一种染料前体，还含有4,4'-二异氰酸酯-3,3'-二甲基 - 1,1'-联苯和/或聚亚甲基聚苯基多异氰酸酯。

公开(公告)号：US06579828B1

公开(公告)日：2003-06-17

申请号：US09680928

申请日：2000-10-10

申请人： Kaoru Hamada ,  Tadakazu Fukuchi ,  Yoshimi Midorikawa ,  Yoshihide Kimura

发明人： Kaoru Hamada ,  Tadakazu Fukuchi ,  Yoshimi Midorikawa ,  Yoshihide Kimura

IPC分类号： B41M530

CPC分类号： B41M5/3333 ,  B41M5/3331

摘要： A multi chromatic thermally sensitive recording medium comprising, a higher temperature color developing layer containing dye precursor and an organic color developer that reacts with said dye precursor and develops color by heating, and at least one lower temperature color developing layer that develops different color from that of said higher temperature color developing layer and develops color by lower temperature than the color developing temperature of said higher temperature color developing layer laminated in order on a substrate, wherein an organic color developer contained in said higher temperature color developing layer contains said diphenylsulfone bridgeable type compound represented by general formula (1) and/or said 3-{[(phenylamine)carbonyl]amino}benzenesulfoneamide compound represented by general formula (2), wherein, X and Y can be different and indicates a saturate or an unsaturated liner or grafted hydrocarbon group of carbon number 1 to 12 which can possess an ether bond, or wherein R indicates a methylene group or an ethylene group, T indicates a hydrogen atom or an alkyl group of carbon number 1 to 4, and R1 to R6 independently indicate a halogen atom, an alkyl group of carbon number 1 to 6 or an alkenyl group, further m, n, p, q, r, t indicate an integer number of 0 to 4 and when are bigger than 2, R1 to R6 can be different and a is an integer of 0 to 10.

摘要翻译： 一种多色热敏记录介质，包括：含有染料前体的高温彩色显影层和与所述染料前体反应并通过加热显色的有机彩色显影剂;以及至少一种与该色素前体形成不同颜色的低温彩色显影层 的所述高温彩色显影层，并且通过比在所述高温彩色显影层的彩色显影温度更低的温度显影出颜色，所述显色温度依次层压在基板上，其中所述高温彩色显影层中所含的有机彩色显影剂含有所述二苯砜可桥接型 由通式（1）表示的化合物和/或由通式（2）表示的所述3 - {[（苯基胺）羰基]氨基}苯磺酰胺化合物，其中X和Y可以不同，表示饱和或不饱和的内衬或 碳原子数1〜12的可接受烃基的接枝烃基 R键，或其中R表示亚甲基或亚乙基，T表示氢原子或碳数1〜4的烷基，R1〜R6独立地表示卤素原子，碳原子数为1〜6的烷基或 烯基，另外m，n，p，q，r，t表示0〜4的整数，当大于2时，R 1〜R 6可以不同，a为0〜10的整数。

公开(公告)号：US06410479B1

公开(公告)日：2002-06-25

申请号：US09428489

申请日：1999-10-28

申请人： Tadakazu Fukuchi ,  Kaoru Hamada ,  Daisuke Imai ,  Hidenori Ogawa ,  Yuji Tsuzuki ,  Reiko Sato ,  Yoshihide Kimura

发明人： Tadakazu Fukuchi ,  Kaoru Hamada ,  Daisuke Imai ,  Hidenori Ogawa ,  Yuji Tsuzuki ,  Reiko Sato ,  Yoshihide Kimura

IPC分类号： B41M540

CPC分类号： B41M5/44 ,  B41M2205/04

摘要： A thermally sensitive recording medium which has good printability and surface glossness, by forming a glossing layer on a thermally sensitive recording layer on a substrate, and said glossing layer contains an inorganic pigment and a fixing composition which does not cause sticking at higher temperature than 200° C., and the surface glossiness of the glossing layer based on JIS-P-8142 in which angle of incidence and angle of reflect is 75 degree is bigger than 50%.

摘要翻译： 通过在基板上的热敏记录层上形成光泽层和所述光泽层，具有良好的印刷性和表面光泽度的热敏记录介质，含有无机颜料和定影组合物，其在不高于200℃的温度下不会粘附 ℃，以及其中入射角和反射角为75度的JIS-P-8142的光泽层的表面光泽度大于50％。

公开(公告)号：US6093678A

公开(公告)日：2000-07-25

申请号：US135644

申请日：1998-08-18

申请人： Kaoru Hamada ,  Tadakazu Fukuchi ,  Tomoaki Nagai ,  Reiko Sato ,  Yutaka Wakita

发明人： Kaoru Hamada ,  Tadakazu Fukuchi ,  Tomoaki Nagai ,  Reiko Sato ,  Yutaka Wakita

IPC分类号： B41M5/30 ,  B41M5/323 ,  B41M5/327 ,  B41M5/333 ,  B41M5/337 ,  B41M5/40 ,  B41M5/42 ,  B41M5/44

CPC分类号： B41M5/323 ,  B41M5/3335 ,  B41M5/327 ,  B41M5/3275 ,  B41M5/3372 ,  B41M5/3375 ,  B41M5/42 ,  B41M5/426 ,  B41M5/44

摘要： A thermal sensitive recording medium which has a feature to change the color of recorded pattern slowly and spontaneously after development, and the recorded pattern which has several days passed can be easily distinguished from that of just after development. Said thermal sensitive recording medium contains 4-hydroxybenzoic acid ester represented by general formula (I) as a color developer and uses triphenylmethane-based leuco dye and reddish color developing leuco dye whose maximum absorption wave length is 450.about.560 nm as a dye precursor. ##STR1## In this formula, R represents unsubstituted or substituted lower alkyl group of carbon number 1-7 or benzyl group.

摘要翻译： 具有在显影后缓慢地自发地改变记录图案的颜色的特征的热敏记录介质和几天过去的记录图案可以容易地与刚才开发之后区分开。 所述热敏记录介质含有由通式（I）表示的4-羟基苯甲酸酯作为显色剂，并使用最大吸收波长为450-660nm的三苯基甲烷类无色染料和红色显色无色染料作为染料前体。 在该式中，R表示未取代或取代的碳原子数1〜7的低级烷基或苄基。

公开(公告)号：US5811368A

公开(公告)日：1998-09-22

申请号：US759705

申请日：1996-12-06

申请人： Tadakazu Fukuchi ,  Kaoru Hamada ,  Tomoaki Nagai ,  Nobuhiro Kudoh ,  Akio Sekine

发明人： Tadakazu Fukuchi ,  Kaoru Hamada ,  Tomoaki Nagai ,  Nobuhiro Kudoh ,  Akio Sekine

IPC分类号： B41M5/30 ,  B41M5/333 ,  B41M5/337 ,  B41M5/155

CPC分类号： B41M5/3375 ,  B41M5/3333 ,  B41M5/3336

摘要： In a thermal sensitive recording medium comprising a thermal sensitive color developing layer which includes a basic leuco dye and an organic color developer on a substrate, characterized by the said thermal color developing layer includes 0.01-0.9 parts of aminobenzenesulfonamide derivatives indicated by general formula (I) based on 1 part of color developer and also includes at least one kind of methylolated fatty acid amide indicated by general formula (II) in proportion of 0.01-2 parts based on 1 part of color developer. ##STR1## (wherein, "X" indicates an oxygen or sulfur atom, "R" indicates non-substituted or substituted phenyl group, naphthyl group, aralkyl group, lower alkyl group of carbon number 1-6, cycloalkyl group of carbon number 3-6 or lower alkenyl group of carbon number 2-6. "Z" indicates lower alkyl group of carbon number 1-6 or electron attractive group. "n" indicates an integer from 0 to 4 and "P" indicates an integer from 1 to 5, wherein satisfies the numerical formula of n+p.ltoreq.5) R.sub.1 --CONHCH.sub.2 OH (II) (wherein, "R.sub.1 " indicates alkyl group of carbon number 11-21).

摘要翻译： 在包含热敏彩色显影层的热敏记录介质中，其包含基底上的无色染料和有机彩色显影剂，其特征在于所述热显色层包括0.01-0.9份由通式（I）表示的氨基苯磺酰胺衍生物 ），并且还包括基于1份显色剂的0.01-2份比例的由通式（II）表示的至少一种羟甲基化脂肪酸酰胺。 （I）（I）（其中，“X”表示氧或硫原子，“R”表示未取代或取代的苯基，萘基，芳烷基，碳数1-6的低级烷基，环烷基 碳数3-6的碳原子数为3-6以下的碳原子数为2-6的“Z”表示碳原子数1-6的低级烷基或吸电子基团，“n”表示0〜4的整数，“P”表示 1〜5的整数，其中满足n + p = 5）R1-CONHCH2OH（II）的数学式（其中，“R1”表示碳数为11-21的烷基）。

公开(公告)号：US06303540B1

公开(公告)日：2001-10-16

申请号：US09431052

申请日：1999-11-01

申请人： Tadakazu Fukuchi ,  Kaoru Hamada ,  Yuji Tsuzuki ,  Yoshihide Kimura ,  Tomoaki Nagai ,  Yutaka Wakita

发明人： Tadakazu Fukuchi ,  Kaoru Hamada ,  Yuji Tsuzuki ,  Yoshihide Kimura ,  Tomoaki Nagai ,  Yutaka Wakita

IPC分类号： B41M530

CPC分类号： B41M5/3336 ,  B41M5/3375

摘要： A thermally sensitive recording medium which has thermally sensitive recording layer containing colorless or pale colored basic leuco dye and organic color developer as main components on a substrate, wherein said thermally sensitive recording layer contains diphenylsulfone bridgeable type compound represented by general formula (1) and at least one compound represented by general formula (1). In general formula (2), X and Y can be different and indicates a saturated or an unsaturated liner or grafted hydrocarbon group of carbon number 1-12 which can possess ether bond, or indicates wherein R indicates a methylene group or an ethylene group, T indicates a hydrogen atom or an alkyl group of carbon number 1-4, and R1-R6 independently indicate a halogen atom, an alkyl group of carbon number 1-6, or an alkenyl group, further, m, n, p, q, r, t indicate an integer number of 0-4 and when are bigger than 2, R1-R6 can be different, and a is an integer of 0-10. In general formula (2), R7 represents an alkyl group of carbon number 1-6 or an electron attracting group, u is an integer of 0-2.

摘要翻译： 一种热敏记录介质，其具有含有无色或浅色基础无色染料和有机彩色显影剂作为主要成分的热敏记录层，其中所述热敏记录层含有通式（1）表示的二苯砜桥连型化合物， 至少一种由通式（1）表示的化合物。在通式（2）中，X和Y可以不同，表示可以具有醚键的碳数1-12的饱和或不饱和的内衬或接枝烃基，或表示在 R表示亚甲基或亚乙基，T表示氢原子或碳数为1-4的烷基，R1-R6独立地表示卤素原子，碳原子数为1-6的烷基或烯基 此外，m，n，p，q，r，t表示0-4的整数，当大于2时，R1-R6可以不同，a是0-10的整数。在通式（ 2），R7表示 碳数1-6的烷基或吸电子基团，u为0-2的整数。

公开(公告)号：US06432874B1

公开(公告)日：2002-08-13

申请号：US09572088

申请日：2000-05-17

申请人： Tadakazu Fukuchi ,  Kaoru Hamada ,  Kunio Takebayashi ,  Hidenori Ogawa ,  Yoshimi Midorikawa ,  Reiko Sato ,  Yoshihide Kimura

发明人： Tadakazu Fukuchi ,  Kaoru Hamada ,  Kunio Takebayashi ,  Hidenori Ogawa ,  Yoshimi Midorikawa ,  Reiko Sato ,  Yoshihide Kimura

IPC分类号： B41M540

CPC分类号： B41M5/44 ,  B41M5/30

摘要： A thermally sensitive recording paper having a recording surface which when a postage stamp or a revenue stamp is adhered to the recording surface requires at least ten cycles of a removal test procedure to remove at least one third of the adhered surface of the stamp from the recording surface of the thermally sensitive recording paper, wherein the removal test procedure comprises adhering the postage stamp or revenue stamp to the recording surface of the thermally sensitive recording paper, hanging the recording paper over an iron bar of about 8 mm diameter with the postage stamp or revenue stamp on an outer surface of the recording paper, adjusting the recording paper such that equal lengths are on either side of the iron bar, attaching to one end of the thermally sensitive recording paper a weight of about 500 g, holding the other end of the thermally sensitive recording paper by hand and carrying out a pull down ant put back cycle motion of the hand to move the postage stamp or revenue stamp over the iron bar until at least a portion of the postage stamp or revenue stamp is removed from the surface of the recording paper.

摘要翻译： 一种具有记录表面的热敏记录纸，当邮票或收入印记附着在记录表面上时，需要至少十个循环的去除测试程序，以从记录中去除印模的粘附表面的至少三分之一 热敏记录纸的表面，其中去除测试程序包括将邮票或收入印章粘贴到热敏记录纸的记录表面上，将该记录纸用约8mm直径的铁棒用邮资戳或 记录纸的外表面上的收入印章，调整记录纸，使得相同的长度在铁棒的任一侧上，附着在热敏记录纸的一端，重量约为500g，保持另一端 手感热敏记录纸，并执行拉下蚂蚁放回手的循环运动，以移动邮票或邮寄 场地邮票在铁条上，直到从记录纸的表面移除至少一部分邮票或收据。

公开(公告)号：US07799963B2

公开(公告)日：2010-09-21

申请号：US12379845

申请日：2009-03-03

申请人： Masahiro Inui ,  Kaoru Hamada ,  Kenji Otsubo

发明人： Masahiro Inui ,  Kaoru Hamada ,  Kenji Otsubo

IPC分类号： C07C4/04 ,  C10G9/14 ,  F28F1/14

CPC分类号： F28F1/40 ,  B01F2005/0626 ,  B01F2005/0636 ,  B01J19/006 ,  B01J19/2415 ,  C10G9/20 ,  F28D2021/0022

摘要： A cracking tube (50) for use in thermal cracking furnaces for producing ethylene or the like has fins (1) formed on an inner surface thereof and inclined with respect to an axis of the tube for stirring a fluid inside the tube. The fins are arranged discretely on one or a plurality of helical loci, and the tube inner surface has regions (ZB) wherein no fins are present over the entire axial length of the tube from one axial end of the tube to the other axial end thereof.

摘要翻译： 用于生产乙烯等的热裂解炉的裂解管（50）在其内表面上形成有相对于管轴倾斜的翅片（1），用于搅拌管内的流体。 翅片离散设置在一个或多个螺旋轨迹上，并且管内表面具有区域（ZB），其中在管的整个轴向长度上从管的一个轴向端到另一个轴向端都不存在翅片 。

公开(公告)号：US07655287B2

公开(公告)日：2010-02-02

申请号：US10535387

申请日：2004-03-29

申请人： Yoshio Yoshida ,  Shoichi Endo ,  Masanori Kawashima ,  Susumu Hagisawa ,  Takayuki Fujimoto ,  Masaya Tosaka ,  Yuu Suzuki ,  Kaoru Hamada

发明人： Yoshio Yoshida ,  Shoichi Endo ,  Masanori Kawashima ,  Susumu Hagisawa ,  Takayuki Fujimoto ,  Masaya Tosaka ,  Yuu Suzuki ,  Kaoru Hamada

IPC分类号： B41M5/40

CPC分类号： B41M5/52 ,  B41M5/5218

摘要： An inkjet recording medium obtained by forming a coating layer containing a pigment and a binder on the surface of a base material and coating layer is subsequently pressed onto a heated mirror finished surface to dry to form an ink absorbing layer through a cast coating method, wherein pigment contains a colloidal silica that has a primary particle diameter of from 10 nm to 100 nm while the ratio of the secondary particle diameter to primary particle diameter is from 1.5 to 3.0.

摘要翻译： 随后将通过在基材和涂层的表面上形成含有颜料和粘合剂的涂层而获得的喷墨记录介质压到加热的镜面加工表面上以干燥以通过流延涂布法形成吸墨层，其中 颜料含有一次粒径为10nm〜100nm的胶态二氧化硅，二次粒径与一次粒径的比为1.5〜3.0。