摘要:
There are disclosed a polycyclic norbornene or its derivative hydrogenated copolymer which containsa repeating unit represented by the following formula [I] or the alkyl-substituted derivative thereof (A),a repeating unit represented by the following formula [II] or the alkyl-substituted derivative thereof (B) and, as desired,5-85% by mole of at least one repeating unit (C) selected from a repeating unit represented by the following formula [III], the alkyl-substituted derivative thereof, a repeating unit represented by the following formula [IV], the alkyl-substituted derivative and the alkylidene-substituted derivative thereof, and a process for producing the polycyclic norbornene or its derivative ring-opening hydrogenated copolymer ##STR1## wherein ------ represents either a single bond or a double bond.
摘要:
(1) A solvent-soluble ring-opened polymer constituted of 100-50% by weight of a norbornene derivative of monomer (A) represented by the formula ##STR1## wherein, R.sub.1 and R.sub.2 are the same or different and each denote hydrogen or alkyl and m denotes an interger of 0 to 2, and 0-50% by weight of another norbornene derivative of monomer (B) capable of undergoing ring-opening copolymerization with the preceding monomer (A), the polymer having a number average molecular weight of 10,000 to 50,000, a weight average molecular weight-to-number average molecular weight ratio (Mw/Mn) of up to 3, and a glass transition temperature of at least 80.degree. C., and(2) a process for producing such ring-opened polymers as stated above.
摘要:
There are disclosed a polycyclic norbornene or its derivative ring-opening hydrogenated copolymer which contains 90-10% by mole of a repeating unit represented by the following formula [I] or the alkly-substituted derivative, at least a repeating unit represented by the following formula [II] or the alkly-substituted derivative thereof and, as required, a repeating unit represented by the following formula [III], the alkyl-substituted derivative thereof or the alkylidene-substituted derivative thereof, has an intrinsic viscosity [.eta.] of 0.01-20 dl/g as determined in toluene at 25 .degree. C., and in which at least 50% of the (C C) linkages constituting the main chain are single bonds, and the production of said hydrogenation product ##STR1## wherein represents either a single bond or a double bond.
摘要:
A molding material suitable as an optical material and an optical recording medium formed of the molding material are disclosed. The molding material comprises a hydrogenated product of a polymer formed by ring-opening polymerization of a norbornene-type monomer, the hydrogenated product having a number average molecular weight (Mn) of 20,000 to 50,000, a weight average molecular weight (Mw) of 40,000 to 80,000 and a molecular distribution (Mw/Mn) of not more than 2.5 and having a volatile content of not more than 0.3% by weight.
摘要:
A process for producing a polymer by ring-opening polymerization of a norbornene-type monomer, which comprises starting the ring-opening polymerization in the presence of a Ziegler-type catalyst consisting essentially of an organometallic compound of a metal belonging to the groups I to III of the periodic table and titanium tetrahalide, carrying out the ring-opening polymerization until the norbornene-type monomer shows a conversion ratio of not less than 60%, and then adding a tungsten and/or molybdenum-based metathesis catalyst to the polymerization reaction system to continue the ring-opening polymerization.
摘要:
There is disclosed an optical disk having an optical reflectivity of 70% or above which comprises a substrate made of a thermoplastic saturated norbornene type polymer having a glass transition temperature of 100.degree. C. or above and a light reflecting layer formed by laminating, on said substrate, a multi-layer film constituted of at least one compound selected from the group consisting of metallic oxides and metallic fluorides.
摘要:
A resin obtained by subjecting a norbornene type monomer having an aromatic ring structure (e.g. 5-phenyl-2-norbornene) to ring-opening polymerization and hydrogenating 95% or more of the unsaturated bonds in the backbone structure of the resulting polymer by the use of a catalyst composed of a combination of a transition metal compound and an alkyl metal compound, while leaving 80% or more of the aromatic ring structures, which resin has not only a high refractive index but also characteristics of a hydrogenated norbornene ring-opening polymerization product, i.e., excellent heat resistance, transparency, low birefringent properties, weather resistance, light resistance, low water absorption properties, moisture resistance, small dielectric constant, small dielectric loss, chemical resistance, etc., said resin being usable in optical materials, medical tools and materials, tools and materials for treating electronic parts, etc.
摘要:
A molding frame made by molding a thermoplastic norbornene resin which hardly deforms even after repeated use is used for production of electronic part sealed bodies by sealing the electronic devices of integrated circuits such as light emitting diodes, diodes, transistors, LSI devices, IC devices and CCD devices and capacitors, resistors, coils, microswitches and dipswitches with thermosetting resins such as epoxy resins as sealants.
摘要:
A press-through package obtained by placing objects to be packed, in the accommodating pockets formed by vacuum forming or the like of a sheet made of a thermoplastic norbornene type resin, particularly preferably a hydrogenated product of ring-opening polymerization product of a dicyclopentadiene type monomer, and then closing the openings of pockets of the sheet with another sheet such as metal foil to pack the objects to be packed, which package makes the packed objects clearly visible in the pocket portions, prevents the deterioration of the packed objects by moisture bacause of its excellent water vapor barrier properties, and is good in production efficiency.
摘要:
A thermoplastic norbornene based molded article which can be used as a substrate for liquid crystal display having an excellent performance; said substrate having a specified surface roughness of 0.05 .mu.m or less, and a liquid crystal display produced therefrom.