Process for preparing pyridine bases
    1.
    发明授权
    Process for preparing pyridine bases 失效
    制备吡啶碱的方法

    公开(公告)号:US4263439A

    公开(公告)日:1981-04-21

    申请号:US48572

    申请日:1979-06-14

    IPC分类号: C07D213/10 C07D213/16

    CPC分类号: C07D213/16 C07D213/10

    摘要: A process for preparing simultaneously pyridine bases including 2-methylpyridine and 4-methylpyridine, occasionally, together with pyridine from acetaldehyde and ammonia by gas phase catalytic reaction, characterized in that the gas phase catalytic reaction is conducted in the presence of a catalyst prepared by (A) incorporating at least one compound containing at least one metal selected from the group consisting of tungsten, manganese, nickel, iron, cobalt, molybdenum, uranium, lead, silver, copper and tin into silica-alumina simultaneously with preparation of the silica-alumina, or (B) subjecting silica-alumina to ion exchange with ions of at least one metal selected from the group consisting of manganese, nickel, iron, cobalt, uranium, lead, silver, copper and tin to adsorb the ions on said silica-alumina. According to the process of the present invention, there can be obtained the desired pyridine bases in high yield, whereas formation of by-products including high boiling point pyridine derivatives is remarkably suppressed. The catalyst employed in the present process has a high resistance to the reaction atmosphere.

    摘要翻译: 同时通过气相催化反应同时制备包括2-甲基吡啶和4-甲基吡啶的吡啶碱与乙醛和氨的吡啶一起制备的方法,其特征在于气相催化反应是在催化剂存在下进行的, A)同时制备含有选自钨,锰,镍,铁,钴,钼,铀,铅,银,铜和锡中的至少一种金属的至少一种化合物,同时制备二氧化硅 - 氧化铝,或(B)使二氧化硅 - 氧化铝与选自锰,镍,铁,钴,铀,铅,银,铜和锡中的至少一种金属的离子进行离子交换,以将离子吸附在所述二氧化硅 氧化铝 根据本发明的方法,可以高产率获得所需的吡啶碱,而显着抑制了包括高沸点吡啶衍生物在内的副产物的形成。 本方法中使用的催化剂对反应气氛具有高抗性。

    Process for preparing pyridine bases
    2.
    发明授权
    Process for preparing pyridine bases 失效
    制备吡啶碱的方法

    公开(公告)号:US4239892A

    公开(公告)日:1980-12-16

    申请号:US61335

    申请日:1979-07-27

    IPC分类号: C07D213/10 C07D213/16

    CPC分类号: C07D213/16 C07D213/10

    摘要: A process for preparing simultaneously pyridine bases including 2-methylpyridine and 4-methylpyridine, occasionally, together with pyridine from acetaldehyde and ammonia by gas phase catalytic reaction, characterized in that the gas phase catalytic reaction is conducted in the presence of a catalyst prepared by (A) incorporating at least one compound containing at least one metal selected from the group consisting of tungsten, manganese, nickel, iron, cobalt, molybdenum, uranium, lead, silver, copper and tin into silica-alumina simultaneously with preparation of the silica-alumina, or (B) subjecting silica-alumina to ion exchange with ions of at least one metal selected from the group consisting of manganese, nickel, iron, cobalt, uranium, lead, silver, copper and tin to adsorb the ions on said silica-alumina. According to the process of the present invention, there can be obtained the desired pyridine bases in high yield, whereas formation of by-products including high boiling point pyridine derivatives is remarkably suppressed. The catalyst employed in the present process has a high resistance to the reaction atmosphere.

    摘要翻译: 同时通过气相催化反应同时制备包括2-甲基吡啶和4-甲基吡啶的吡啶碱与乙醛和氨的吡啶一起制备的方法,其特征在于气相催化反应是在催化剂存在下进行的, A)同时制备含有选自钨,锰,镍,铁,钴,钼,铀,铅,银,铜和锡中的至少一种金属的至少一种化合物,同时制备二氧化硅 - 氧化铝,或(B)使二氧化硅 - 氧化铝与选自锰,镍,铁,钴,铀,铅,银,铜和锡中的至少一种金属的离子进行离子交换,以将离子吸附在所述二氧化硅 氧化铝 根据本发明的方法,可以高产率获得所需的吡啶碱,而显着抑制了包括高沸点吡啶衍生物在内的副产物的形成。 本方法中使用的催化剂对反应气氛具有高抗性。

    Process for preparing pyridine bases
    3.
    发明授权
    Process for preparing pyridine bases 失效
    制备吡啶碱的方法

    公开(公告)号:US4179576A

    公开(公告)日:1979-12-18

    申请号:US841083

    申请日:1977-10-11

    IPC分类号: C07D213/10 C07D213/16

    CPC分类号: C07D213/16 C07D213/10

    摘要: A process for preparing simultaneously pyridine bases including 2-methylpyridine and 4-methylpyridine, occasionally, together with pyridine from acetaldehyde and ammonia by gas phase catalytic reaction, characterized in that the gas phase catalytic reaction is conducted in the presence of a catalyst prepared by (A) incorporating at least one compound containing at least one metal selected from the group consisting of tungsten, manganese, nickel, iron, cobalt, molybdenum, uranium, lead, silver, copper and tin into silica-alumina simultaneously with preparation of the silica-alumina, or (B) subjecting silica-alumina to ion exchange with ions of at least one metal selected from the group consisting of manganese, nickel, iron, cobalt, uranium, lead, silver, copper and tin to adsorb the ions on said silica-alumina. According to the process of the present invention, there can be obtained the desired pyridine bases in high yield, whereas formation of by-products including high boiling point pyridine derivatives is remarkably suppressed. The catalyst employed in the present process has a high resistance to the reaction atmosphere.

    摘要翻译: 同时通过气相催化反应同时制备包括2-甲基吡啶和4-甲基吡啶的吡啶碱与乙醛和氨的吡啶一起制备的方法,其特征在于气相催化反应是在催化剂存在下进行的, A)同时制备含有选自钨,锰,镍,铁,钴,钼,铀,铅,银,铜和锡中的至少一种金属的至少一种化合物,同时制备二氧化硅 - 氧化铝,或(B)使二氧化硅 - 氧化铝与选自锰,镍,铁,钴,铀,铅,银,铜和锡中的至少一种金属的离子进行离子交换,以将离子吸附在所述二氧化硅 氧化铝 根据本发明的方法,可以高产率获得所需的吡啶碱,而显着抑制了包括高沸点吡啶衍生物在内的副产物的形成。 本方法中使用的催化剂对反应气氛具有高抗性。

    Optical fiber wiring board having an extension portion
    7.
    发明授权
    Optical fiber wiring board having an extension portion 失效
    具有延伸部分的光纤布线板

    公开(公告)号:US06668129B2

    公开(公告)日:2003-12-23

    申请号:US10053556

    申请日:2002-01-24

    IPC分类号: G02B600

    摘要: An optical fiber board has a substrate, optical fiber arranged as wiring on the substrate, and extension portions in each of which some optical fibers are led out from the substrate to be adjacent to each other in a row. The adjacent optical fibers at a base portion of the extension portion are not fixed to one another. The adjacent optical fibers at a forward end portion of the extension portion are fixed to one another integrally. The base portion has a predetermined length from an edge portion of the substrate.

    摘要翻译: 光纤基板具有基板,布置在基板上的布线的光纤以及延伸部分,每个延伸部分中的一些光纤从基板被引出并排成彼此相邻。 延伸部的基部的相邻的光纤彼此不固定。 延伸部的前端部的相邻的光纤整体固定。 基部具有从基板的边缘部分预定的长度。