公开(公告)号：US09370770B2

公开(公告)日：2016-06-21

申请号：US14261150

申请日：2014-04-24

Applicant: The Texas A&M University System

Inventor： David E. Bergbreiter ,  Hassan S. Bazzi ,  Chayanant Hongfa

IPC: B01J31/16 ,  C07D207/48 ,  C07D211/96 ,  C07C67/30 ,  C07C67/333 ,  C07D233/58 ,  C07D295/24 ,  C07D403/14 ,  C08L65/00

CPC classification number: C07C67/333 ,  B01J31/06 ,  B01J31/1683 ,  B01J31/2278 ,  B01J31/2291 ,  B01J31/2295 ,  B01J2231/543 ,  B01J2531/17 ,  B01J2531/821 ,  C07C67/30 ,  C07C67/58 ,  C07C2601/10 ,  C07C2601/16 ,  C07D207/46 ,  C07D207/48 ,  C07D211/94 ,  C07D211/96 ,  C07D233/58 ,  C07D295/24 ,  C07D403/14 ,  C08G2261/418 ,  C08L65/00 ,  C07C69/75 ,  C07C69/74

Abstract: One embodiment of the invention provides polyisobutylene (PIB) oligormers that are end-functionalized with ruthenium (Ru) catalysts. Such nonpolar catalysts can be dissolved in nonpolar solvents such as heptane, or any other nonpolar solvent that is otherwise not latently biphasic (i.e., if two or more solvent components are present, they remain miscible with each other throughout the entire reaction process, from the addition of substrate through to the removal of product). Substrate that is dissolved in the nonpolar solvent with the catalyst is converted into product. The lower solubility of the product in the nonpolar solvent renders it easily removable, either by extraction with a more polar solvent or by applying physical means in cases where the product precipitates from the nonpolar solvent. In this manner the catalysts are recycled; since the catalysts remain in the nonpolar solvent, a new reaction can be initiated simply by dissolving fresh substrate into the nonpolar solvent.

Abstract translation: 本发明的一个实施方案提供了用钌（Ru）催化剂端官能化的聚异丁烯（PIB）寡聚体。 这种非极性催化剂可以溶解在非极性溶剂如庚烷或任何其他非潜在双相的非极性溶剂中（即，如果存在两种或多种溶剂组分，则它们在整个反应过程中彼此保持混溶， 加入底物通过去除产物）。 用催化剂溶于非极性溶剂的底物转化成产物。 产品在非极性溶剂中的较低溶解度使其易于除去，无论是通过用极性较大的溶剂萃取还是通过在产物从非极性溶剂沉淀的情况下应用物理方法。 以这种方式，催化剂被再循环; 由于催化剂保留在非极性溶剂中，所以可以简单地通过将新鲜的底物溶解在非极性溶剂中来开始新的反应。

公开(公告)号：US20150057449A1

公开(公告)日：2015-02-26

申请号：US14261150

申请日：2014-04-24

Applicant: The Texas A&M University System

Inventor： David E. Bergbreiter ,  Hassan S. Bazzi ,  Chayanant Hongfa

IPC: B01J31/16 ,  C07D207/48 ,  C07D211/96 ,  C07C67/30

CPC classification number: C07C67/333 ,  B01J31/06 ,  B01J31/1683 ,  B01J31/2278 ,  B01J31/2291 ,  B01J31/2295 ,  B01J2231/543 ,  B01J2531/17 ,  B01J2531/821 ,  C07C67/30 ,  C07C67/58 ,  C07C2601/10 ,  C07C2601/16 ,  C07D207/46 ,  C07D207/48 ,  C07D211/94 ,  C07D211/96 ,  C07D233/58 ,  C07D295/24 ,  C07D403/14 ,  C08G2261/418 ,  C08L65/00 ,  C07C69/75 ,  C07C69/74

Abstract: One embodiment of the invention provides polyisobutylene (PIB) oligormers that are end-functionalized with ruthenium (Ru) catalysts. Such nonpolar catalysts can be dissolved in nonpolar solvents such as heptane, or any other nonpolar solvent that is otherwise not latently biphasic (i.e., if two or more solvent components are present, they remain miscible with each other throughout the entire reaction process, from the addition of substrate through to the removal of product). Substrate that is dissolved in the nonpolar solvent with the catalyst is converted into product. The lower solubility of the product in the nonpolar solvent renders it easily removable, either by extraction with a more polar solvent or by applying physical means in cases where the product precipitates from the nonpolar solvent. In this manner the catalysts are recycled; since the catalysts remain in the nonpolar solvent, a new reaction can be initiated simply by dissolving fresh substrate into the nonpolar solvent.

Abstract translation: 本发明的一个实施方案提供了用钌（Ru）催化剂端官能化的聚异丁烯（PIB）寡聚体。 这种非极性催化剂可以溶解在非极性溶剂如庚烷或任何其他非潜在双相的非极性溶剂中（即如果存在两种或多种溶剂组分，则它们在整个反应过程中彼此保持混溶， 加入底物通过去除产物）。 用催化剂溶于非极性溶剂的底物转化成产物。 产品在非极性溶剂中的较低溶解度使其易于除去，无论是通过用极性较大的溶剂萃取还是通过在产物从非极性溶剂沉淀的情况下应用物理方法。 以这种方式，催化剂被再循环; 由于催化剂保留在非极性溶剂中，所以可以简单地通过将新鲜的底物溶解在非极性溶剂中来开始新的反应。