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公开(公告)号：US4403052A
公开(公告)日：1983-09-06
申请号：US412473
申请日：1982-08-30
摘要： A flame retarded, injection moldable, saturated, linear polyester composition contains red phosphorus as flame retardant and a metal iodide as phosphine suppressing agent. The metal is one of the groups 1a and 2b of the periodic table of elements with potassium iodide being the most preferred.The phosphine evolution of a poly(ethylene terephthalate) molding composition containing 4% red phosphorus as flame retardant is reduced to 0.3 ppm at the die and to 1.0 ppm in storage by the addition of 0.6% of potassium iodide.
摘要翻译： 阻燃注射成型的饱和直链聚酯组合物含有作为阻燃剂的红磷和作为磷化氢抑制剂的金属碘化物。 金属是元素周期表的组1a和2b之一，其中碘化钾是最优选的。 含有4％红磷作为阻燃剂的聚（对苯二甲酸乙二醇酯）模塑组合物的磷化氢演变通过加入0.6％碘化钾在模具处降低至0.3ppm，并在储存时减少至1.0ppm。
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2.发明授权Process for increasing the melt viscosity of polyamide with aryl phosphate compound 失效用芳基磷酸酯化合物提高聚酰胺的熔体粘度的方法
公开(公告)号：US4390667A
公开(公告)日：1983-06-28
申请号：US280564
申请日：1981-07-06
申请人： Shaul M. Aharoni , Theodore Largman
发明人： Shaul M. Aharoni , Theodore Largman
IPC分类号： C08G69/48
CPC分类号： C08G69/48
摘要： A process for decreasing the melt index and increasing the viscosity of polyamide compositions by adding thereto an effective amount of an aryl phosphate compound, and thereafter heating the composition until the desired changes in melt index or viscosity are attained.
摘要翻译： 通过向其中加入有效量的芳基磷酸酯化合物，然后加热组合物直到达到所需的熔体指数或粘度变化，从而降低聚酰胺组合物的熔体指数和增加粘度的方法。
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3.发明授权Process for increasing the relative viscosity of polycaprolactam with phosphite compound 失效增加聚己内酰胺与亚磷酸酯化合物的相对粘度的方法
公开(公告)号：US4433116A
公开(公告)日：1984-02-21
申请号：US453210
申请日：1982-12-27
申请人： Theodore Largman , Shaul M. Aharoni
发明人： Theodore Largman , Shaul M. Aharoni
IPC分类号： C08G69/48
CPC分类号： C08G69/48
摘要： A process for rapidly and substantially decreasing the melt index and increasing the viscosity of polymers of caprolactams during melt processing by forming a molten mixture of the polymer and a phosphite compound and heating the mixture until the desired change in melt index and viscosity are obtained.
摘要翻译： 通过形成聚合物和亚磷酸酯化合物的熔融混合物并加热混合物直到获得所需的熔体指数和粘度变化，从而快速且显着降低熔体指数并增加己内酰胺聚合物在熔融加工过程中的粘度。
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公开(公告)号：US4417032A
公开(公告)日：1983-11-22
申请号：US370885
申请日：1982-04-22
CPC分类号： C08G69/48 , C08G69/265 , C08G69/36 , C08L77/00
摘要： A process for preparing quasi-random copolymers is described which involves heating a mixture of polyamides in the presence of one or more phosphite promotor(s). The process is conducted at temperatures between about 265.degree. C. and 315.degree. C. with the process time generally ranging from about 2 to about 20 minutes. The process is especially useful for preparing copolymers from a mixture of poly(caproamide) and poly(hexamethylene adipamide). The copolymer products prepared in accordance with the process are particularly suitable for the production of plastic films which have improved properties as compared to either of the homopolymers.
摘要翻译： 描述了制备准无规共聚物的方法，其涉及在一种或多种亚磷酸酯促进剂的存在下加热聚酰胺的混合物。 该方法在约265℃至315℃的温度下进行，处理时间通常为约2至约20分钟。 该方法对于由聚（己酰胺）和聚（己二酰己二胺）的混合物制备共聚物特别有用。 根据该方法制备的共聚物产物特别适用于与均聚物相比具有改进性能的塑料膜的生产。
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公开(公告)号：US4417031A
公开(公告)日：1983-11-22
申请号：US337800
申请日：1982-01-07
申请人： Shaul M. Aharoni , Theodore Largman
发明人： Shaul M. Aharoni , Theodore Largman
摘要： A process for preparing block, and/or graft copolymeric compositions by forming an intimate mixture of two or more polymers, at least one of which includes one or more amino junctions and at least one of the remaining polymers includes one or more carboxylic acid junctions and an effective amount of a phosphite compound, and thereafter heating the intimate mixture at a temperature and for a time sufficient to form the desired block, and/or graft copolymers.
摘要翻译： 一种通过形成两种或更多种聚合物的紧密混合物制备嵌段和/或接枝共聚物组合物的方法，其中至少一种包括一个或多个氨基结，至少一种剩余的聚合物包括一个或多个羧酸结和 有效量的亚磷酸酯化合物，然后在足以形成所需嵌段的温度和时间下加热紧密混合物，和/或接枝共聚物。
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公开(公告)号：US5493000A
公开(公告)日：1996-02-20
申请号：US109954
申请日：1993-08-23
申请人： Shaul M. Aharoni
发明人： Shaul M. Aharoni
IPC分类号： C08G18/83 , C08G63/20 , C08G69/00 , C08G69/32 , C08G69/48 , C08G73/02 , C08G81/00 , C08G83/00 , C08G85/00 , C08L101/00
CPC分类号： C08G83/003 , C08G18/831 , C08G63/20 , C08G69/00 , C08G69/32 , C08G69/48 , C08G73/02 , C08G81/00 , C08G85/004 , C08L101/005 , Y10T428/31504 , Y10T428/31725
摘要： This invention relates to a branched fractal three dimensional porous polymer species which comprises rigid aromatic recurring units having electrophilic or nucleophilic reactive moieties on the exterior thereof. Another aspect of this invention relates to a star polymer comprising a polymeric core formed of the fractal polymers (FPS) of this invention having linear polymeric moieties grafted to the exterior thereof by way of residues formed by reaction between the reactive moieties on the exterior of the fractal polymer (FP) and complimentary reactive moieties on a linear polymer. Yet another aspect of this invention relates to polymeric composites comprising a polymer matrix having dispersed therein the star polymers of this invention.
摘要翻译： 本发明涉及支化分形三维多孔聚合物物质，其包含在其外部具有亲电子或亲核反应性部分的刚性芳族重复单元。 本发明的另一方面涉及一种星形聚合物，其包含由本发明的分形聚合物（FPS）形成的聚合物芯，其具有通过在其外部的反应部分之间的反应而形成的残余物，其接枝到其外部的线性聚合物部分 分形聚合物（FP）和在线性聚合物上的互补的反应性部分。 本发明的另一方面涉及包含其中分散有本发明的星形聚合物的聚合物基质的聚合物复合材料。
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公开(公告)号：US5183839A
公开(公告)日：1993-02-02
申请号：US760306
申请日：1991-09-16
申请人： Shaul M. Aharoni
发明人： Shaul M. Aharoni
IPC分类号： C08F220/22
CPC分类号： C08F220/22
摘要： Copolymer compositions derived from (a) perfluroalkylalkyl acrylate or methacrylate, (b) acrylic, methacrylic or itaconic acid, and (c) a hydroxyl-containing acrylate or methacrylate, in combination, can be cross-linked through internal esterification or anhydride formation. These product combine properties typical of fluorine-containing polymers with processability, including processability from solution.
摘要翻译： 衍生自（a）丙烯酸酯或甲基丙烯酸烷基烷基酯，（b）丙烯酸，甲基丙烯酸或衣康酸的丙烯酸烷基烷基酯和（c）组合的含羟基的丙烯酸酯或甲基丙烯酸酯的共聚物组合物可以通过内酯化或酸酐形成而交联。 这些产品将含氟聚合物的典型性能与加工性相结合，包括溶液的可加工性。
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公开(公告)号：US5178955A
公开(公告)日：1993-01-12
申请号：US783032
申请日：1991-10-25
IPC分类号： C08F220/22 , G02B1/11
CPC分类号： C08F220/22 , G02B1/111 , Y10T428/3154
摘要： Solid bodies having a reflective surface are provided with an anti-reflection coating of a terpolymer composition derived from (a) perfluoroalkylalkyl acrylate or methacrylate, (b) acrylic, methacrylic or itaconic acid, and (c) hydroxyl- containing acrylate or methacrylate.
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公开(公告)号：US4336356A
公开(公告)日：1982-06-22
申请号：US180753
申请日：1980-08-25
CPC分类号： C08C19/04 , C08F8/06 , C08F8/44 , C08G69/26 , C08F2810/20
摘要： Partially unsaturated polymers are dissolved in a two component solvent comprising a first component having a reactivity toward ozone less than carbon-carbon double bonds but more reactive than carbon-carbon single bonds and a second component being inert toward ozone. Introduction of ozone into the solution produces ozonides which are readily cleft into difunctional aliphatic species that can be converted to e.g. carboxy-terminated or multifunctional carboxy substituted aliphatic compounds. These may be used as monomeric species in various polymerization schemes as such, in preparation of polyamides, for example, or may be reduced to aldehydes or alcohols to be used in the preparation of such polymers as polyesters, polyurethanes, poly (Schiff bases), etc. The carboxylated products may also be employed as ionomers, which are useful as surfactants. Monocarboxyl terminated polyethylene having a number average molecular weight of from about 4,000 to 100,000 are provided. Poly(carboxymethyl) substituted polyethylenes, wherein from about 0.05 to 1.3 percent of the hydrogen atom or polyethylene are substituted with carboxymethyl groups, are obtained.
摘要翻译： 部分不饱和聚合物溶解在包含对臭氧反应性低于碳 - 碳双键但比碳 - 碳单键反应性更高的第一组分的第二组分和对臭氧呈惰性的第二组分的双组分溶剂中。 将臭氧引入溶液中产生臭氧化物，其易于裂解成可以转化为例如二官能的脂族物质。 羧基封端或多官能的羧基取代的脂族化合物。 这些可以在各种聚合方案中用作单体物质，例如在制备聚酰胺时，或者可以还原成醛或醇，以用于制备聚合物如聚酯，聚氨酯，聚（席夫碱）， 羧化产物也可以用作离聚物，它们可用作表面活性剂。 提供数均分子量为约4,000至100,000的单羧基封端的聚乙烯。 得到其中约0.05-1.3％的氢原子或聚乙烯被羧甲基取代的聚（羧甲基）取代的聚乙烯。
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10.发明授权Process for preparing extended chain polyesters and block or graft copolyesters 失效制备延伸链聚酯和嵌段或接枝共聚酯的方法
公开(公告)号：US5389721A
公开(公告)日：1995-02-14
申请号：US250313
申请日：1994-05-27
申请人： Shaul M. Aharoni
发明人： Shaul M. Aharoni
IPC分类号： C08G63/692 , C08G63/91 , C08G81/00 , C08L67/00 , C08G3/76
CPC分类号： C08G63/916 , C08G63/6926 , C08G81/00
摘要： A process for forming extended chain polyesters and block or graft polyesters or copolyesters which comprises the steps of (a) forming an intimate mixture of one or more polyesters, and an effective amount of one or more chain extension reagents, which are phosphorous (III)-containing compounds, and (b) heating said mixture for a time and at a temperature sufficient to form said extended chain, or graft or block copolyester or polyester; wherein the polyester used in step (a) contains no or substantially no substances which comprise elements from groups VA and VIA of the periodic table in elemental form; and wherein preferably, said polyesters conatain one or more elements belonging to groups IIA, IIIA, IVA, VB, IIB, IIIB, IVB, VIII and the lanthanides.
摘要翻译： 一种形成延伸链聚酯和嵌段或接枝聚酯或共聚酯的方法，其包括以下步骤：（a）形成一种或多种聚酯的紧密混合物，以及有效量的一种或多种扩链试剂，其为磷（III） （b）将所述混合物加热足以形成所述延伸链的时间和温度，或接枝或嵌段共聚酯或聚酯; 其中在步骤（a）中使用的聚酯不含或基本上不含有以元素形式包含周期表的基团VA和VIA的元素的物质; 并且其中优选地，所述聚酯适合属于IIA，IIIA，IVA，VB，IIB，IIIB，IVB，VIII族和镧系元素的一种或多种元素。
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