Fractal polymers and graft copolymers formed from same
    1.
    发明授权
    Fractal polymers and graft copolymers formed from same 失效
    分形聚合物和由其形成的接枝共聚物

    公开(公告)号:US5493000A

    公开(公告)日:1996-02-20

    申请号:US109954

    申请日:1993-08-23

    申请人: Shaul M. Aharoni

    发明人: Shaul M. Aharoni

    摘要: This invention relates to a branched fractal three dimensional porous polymer species which comprises rigid aromatic recurring units having electrophilic or nucleophilic reactive moieties on the exterior thereof. Another aspect of this invention relates to a star polymer comprising a polymeric core formed of the fractal polymers (FPS) of this invention having linear polymeric moieties grafted to the exterior thereof by way of residues formed by reaction between the reactive moieties on the exterior of the fractal polymer (FP) and complimentary reactive moieties on a linear polymer. Yet another aspect of this invention relates to polymeric composites comprising a polymer matrix having dispersed therein the star polymers of this invention.

    摘要翻译: 本发明涉及支化分形三维多孔聚合物物质,其包含在其外部具有亲电子或亲核反应性部分的刚性芳族重复单元。 本发明的另一方面涉及一种星形聚合物,其包含由本发明的分形聚合物(FPS)形成的聚合物芯,其具有通过在其外部的反应部分之间的反应而形成的残余物,其接枝到其外部的线性聚合物部分 分形聚合物(FP)和在线性聚合物上的互补的反应性部分。 本发明的另一方面涉及包含其中分散有本发明的星形聚合物的聚合物基质的聚合物复合材料。

    Fluoropolymers and fluoropolymer coatings
    2.
    发明授权
    Fluoropolymers and fluoropolymer coatings 失效
    含氟聚合物和氟聚合物涂料

    公开(公告)号:US5183839A

    公开(公告)日:1993-02-02

    申请号:US760306

    申请日:1991-09-16

    申请人: Shaul M. Aharoni

    发明人: Shaul M. Aharoni

    IPC分类号: C08F220/22

    CPC分类号: C08F220/22

    摘要: Copolymer compositions derived from (a) perfluroalkylalkyl acrylate or methacrylate, (b) acrylic, methacrylic or itaconic acid, and (c) a hydroxyl-containing acrylate or methacrylate, in combination, can be cross-linked through internal esterification or anhydride formation. These product combine properties typical of fluorine-containing polymers with processability, including processability from solution.

    摘要翻译: 衍生自(a)丙烯酸酯或甲基丙烯酸烷基烷基酯,(b)丙烯酸,甲基丙烯酸或衣康酸的丙烯酸烷基烷基酯和(c)组合的含羟基的丙烯酸酯或甲基丙烯酸酯的共聚物组合物可以通过内酯化或酸酐形成而交联。 这些产品将含氟聚合物的典型性能与加工性相结合,包括溶液的可加工性。

    Production of ozonides from unsaturated polymers
    4.
    发明授权
    Production of ozonides from unsaturated polymers 失效
    从不饱和聚合物生产臭氧化物

    公开(公告)号:US4336356A

    公开(公告)日:1982-06-22

    申请号:US180753

    申请日:1980-08-25

    IPC分类号: C08C19/04 C08F8/06

    摘要: Partially unsaturated polymers are dissolved in a two component solvent comprising a first component having a reactivity toward ozone less than carbon-carbon double bonds but more reactive than carbon-carbon single bonds and a second component being inert toward ozone. Introduction of ozone into the solution produces ozonides which are readily cleft into difunctional aliphatic species that can be converted to e.g. carboxy-terminated or multifunctional carboxy substituted aliphatic compounds. These may be used as monomeric species in various polymerization schemes as such, in preparation of polyamides, for example, or may be reduced to aldehydes or alcohols to be used in the preparation of such polymers as polyesters, polyurethanes, poly (Schiff bases), etc. The carboxylated products may also be employed as ionomers, which are useful as surfactants. Monocarboxyl terminated polyethylene having a number average molecular weight of from about 4,000 to 100,000 are provided. Poly(carboxymethyl) substituted polyethylenes, wherein from about 0.05 to 1.3 percent of the hydrogen atom or polyethylene are substituted with carboxymethyl groups, are obtained.

    摘要翻译: 部分不饱和聚合物溶解在包含对臭氧反应性低于碳 - 碳双键但比碳 - 碳单键反应性更高的第一组分的第二组分和对臭氧呈惰性的第二组分的双组分溶剂中。 将臭氧引入溶液中产生臭氧化物,其易于裂解成可以转化为例如二官能的脂族物质。 羧基封端或多官能的羧基取代的脂族化合物。 这些可以在各种聚合方案中用作单体物质,例如在制备聚酰胺时,或者可以还原成醛或醇,以用于制备聚合物如聚酯,聚氨酯,聚(席夫碱), 羧化产物也可以用作离聚物,它们可用作表面活性剂。 提供数均分子量为约4,000至100,000的单羧基封端的聚乙烯。 得到其中约0.05-1.3%的氢原子或聚乙烯被羧甲基取代的聚(羧甲基)取代的聚乙烯。

    Process for preparing extended chain polyesters and block or graft
copolyesters
    5.
    发明授权
    Process for preparing extended chain polyesters and block or graft copolyesters 失效
    制备延伸链聚酯和嵌段或接枝共聚酯的方法

    公开(公告)号:US5389721A

    公开(公告)日:1995-02-14

    申请号:US250313

    申请日:1994-05-27

    申请人: Shaul M. Aharoni

    发明人: Shaul M. Aharoni

    摘要: A process for forming extended chain polyesters and block or graft polyesters or copolyesters which comprises the steps of (a) forming an intimate mixture of one or more polyesters, and an effective amount of one or more chain extension reagents, which are phosphorous (III)-containing compounds, and (b) heating said mixture for a time and at a temperature sufficient to form said extended chain, or graft or block copolyester or polyester; wherein the polyester used in step (a) contains no or substantially no substances which comprise elements from groups VA and VIA of the periodic table in elemental form; and wherein preferably, said polyesters conatain one or more elements belonging to groups IIA, IIIA, IVA, VB, IIB, IIIB, IVB, VIII and the lanthanides.

    摘要翻译: 一种形成延伸链聚酯和嵌段或接枝聚酯或共聚酯的方法,其包括以下步骤:(a)形成一种或多种聚酯的紧密混合物,以及有效量的一种或多种扩链试剂,其为磷(III) (b)将所述混合物加热足以形成所述延伸链的时间和温度,或接枝或嵌段共聚酯或聚酯; 其中在步骤(a)中使用的聚酯不含或基本上不含有以元素形式包含周期表的基团VA和VIA的元素的物质; 并且其中优选地,所述聚酯适合属于IIA,IIIA,IVA,VB,IIB,IIIB,IVB,VIII族和镧系元素的一种或多种元素。

    Polyester composition with mixed metal ion nucleating agents
    6.
    发明授权
    Polyester composition with mixed metal ion nucleating agents 失效
    聚酯组合物与混合金属离子成核剂

    公开(公告)号:US4366273A

    公开(公告)日:1982-12-28

    申请号:US262236

    申请日:1981-05-11

    申请人: Shaul M. Aharoni

    发明人: Shaul M. Aharoni

    IPC分类号: C08L67/02 C08J3/18

    CPC分类号: C08L67/02 Y10S525/919

    摘要: This invention relates to a composition comprising a linear, saturated polyester, such as poly(ethylene terephthalate), containing between about 4% and about 10% by weight of the poly(ethylene terephthalate) of a hydrocarbon carboxylic acid and/or an organic polymer containing pendant acid carboxyl groups, where the acid groups are neutralized by a first cation selected from Group IA of the Periodic Table of Elements and a second cation selected from Groups IIIA, IIIB and IVB. The first cation is present in an amount less than 50% of the total metal ions and neutralizes not more than 20% of the hydrocarbon acid groups or carboxylic acid groups of the organic polymer. The second cation neutralizes up to 100% of the remaining hydrocarbon acid or carboxyl acid groups. Preferably, the first cation is sodium and the second cation is aluminum. The composition can contain up to about 150% filler and a suitable plasticizer.

    摘要翻译: 本发明涉及一种组合物,其包含线性饱和聚酯,例如聚(对苯二甲酸乙二醇酯),其含有约4重量%至约10重量%的聚(对苯二甲酸乙二醇酯)烃羧酸和/或有机聚合物 其中酸基被选自元素周期表的IA族的第一阳离子和选自IIIA,IIIB和IVB族的第二阳离子中和。 第一阳离子的存在量小于总金属离子的50%,并且中和不超过有机聚合物的烃酸基团或羧酸基团的20%。 第二阳离子中和至多100%剩余的烃酸或羧酸基团。 优选地,第一阳离子是钠,第二阳离子是铝。 组合物可以含有高达约150%的填料和合适的增塑剂。

    Novel copolyester-polyepoxide compositions
    8.
    发明授权
    Novel copolyester-polyepoxide compositions 失效
    新型共聚酯 - 聚环氧化物组合物

    公开(公告)号:US4055606A

    公开(公告)日:1977-10-25

    申请号:US698247

    申请日:1976-06-21

    摘要: Novel copolyester-polyepoxide compositions possessing a high green strength and tack before curing and characterized by having a single discernible glass transition temperature are produced. The compositions are composed of a copolyester and a polyepoxide mixture containing high, intermediate and low molecular weight components. They are especially useful as gap-filling adhesives and for various other adhesive applications. Methods of preparation are also described.

    摘要翻译: 在固化前具有高生坯强度和粘性的新型共聚酯 - 聚环氧化物组合物,其特征在于具有单一可识别的玻璃化转变温度。 组合物由含有高,中和低分子量组分的共聚酯和聚环氧化物混合物组成。 它们特别适用于间隙填充粘合剂和各种其他粘合剂应用。 还描述了制备方法。