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公开(公告)号：US08535556B2
公开(公告)日：2013-09-17
申请号：US12161842
申请日：2007-03-26
申请人： Thomas J. Leck , Nandini C. Mouli , Jon Lee Howell , Velliyur Nott Mallikarjuna Rao , Andrew Edward Feiring , Viacheslav A. Petrov , Allen Capron Sievert , Mario Joseph Nappa , Barbara Haviland Minor , Ekaterina N. Swearingen , Schmitz Corneille , Deepak Perti
发明人： Thomas J. Leck , Nandini C. Mouli , Jon Lee Howell , Velliyur Nott Mallikarjuna Rao , Andrew Edward Feiring , Viacheslav A. Petrov , Allen Capron Sievert , Mario Joseph Nappa , Barbara Haviland Minor , Ekaterina N. Swearingen , Schmitz Corneille , Deepak Perti
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , C09K2205/122
摘要： The present invention relates to compositions comprising iodotrifluoromethane and an effective amount of at least one stabilizer selected from the group consisting of hindered phenols, thiophosphates, butylated triphenylphosphorothionates, organo phosphates, phosphites, aryl alkyl ethers, terpenes, terpenoids, epoxides, fluorinated epoxides, oxetanes, ascorbic acid, thiols, lactones, thioethers, amines, nitromethane, alkylsilanes, benzophenone derivatives, aryl sulfides, divinyl terephalic acid, diphenyl terephalic acid, ionic liquids, and mixtures thereof. These stabilized iodotrifluoromethane compositions may be useful as working fluids in multiple applications including cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps.
摘要翻译： 本发明涉及包含三氟甲烷和有效量的至少一种选自受阻酚，硫代磷酸酯，丁基化三苯基硫代磷酸酯，有机磷酸酯，亚磷酸酯，芳基烷基醚，萜烯，萜类化合物，环氧化物，氟化环氧化物，氧杂环丁烷 ，抗坏血酸，硫醇，内酯，硫醚，胺，硝基甲烷，烷基硅烷，二苯甲酮衍生物，芳基硫醚，二乙烯基对苯二酸，二苯基对苯二酸，离子液体及其混合物。 这些稳定的三氟甲烷组合物可用作多种应用中的工作流体，包括冷却装置，例如制冷，空调，冷却器和热泵。
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公开(公告)号：US08663494B2
公开(公告)日：2014-03-04
申请号：US13325966
申请日：2011-12-14
申请人： Jon Lee Howell , Velliyur Nott Mallikarjuna Rao , Thomas J. Leck , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Ekaterina N. Swearingen , Andrew Edward Feiring
发明人： Jon Lee Howell , Velliyur Nott Mallikarjuna Rao , Thomas J. Leck , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Ekaterina N. Swearingen , Andrew Edward Feiring
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , C09K2205/126
摘要： The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be a terpene, terpenoid or fullerene; or a mixture of a terpene, terpenoid or fullerene with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
摘要翻译： 本发明涉及包含至少一种氟烯烃和有效量的可以是萜烯，萜烯或富勒烯的稳定剂的组合物; 或萜烯，萜烯或富勒烯与其他稳定剂的混合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。
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3.发明授权Ascorbic acid, terephthalate and nitromethane stabilizers for fluoroolefins 有权氟代烯烃的抗坏血酸，对苯二甲酸酯和硝基甲烷稳定剂公开(公告)号：US08097181B2
公开(公告)日：2012-01-17
申请号：US12377677
申请日：2007-08-31
申请人： Thomas J. Leck , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Jon Lee Howell
发明人： Thomas J. Leck , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Jon Lee Howell
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , C09K2205/126
摘要： The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one ascorbic acid, terephthalate, or nitromethane, or mixtures thereof. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
摘要翻译： 本公开涉及包含至少一种氟代烯烃和有效量的包含至少一种抗坏血酸，对苯二甲酸酯或硝基甲烷或其混合物的稳定剂的组合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。
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公开(公告)号：US20110259022A1
公开(公告)日：2011-10-27
申请号：US12377454
申请日：2007-08-31
申请人： Andrew Edward Feiring , Viacheslav A. Petrov , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Thomas J. Leck , Jon Lee Howell
发明人： Andrew Edward Feiring , Viacheslav A. Petrov , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Thomas J. Leck , Jon Lee Howell
IPC分类号： F25D15/00 , C07C21/18 , C10M169/00 , C09K5/04
CPC分类号： C09K5/045 , C09K2205/10 , C09K2205/102 , C09K2205/104 , C09K2205/11 , C09K2205/126 , C09K2205/132 , C09K2205/134 , C09K2205/24 , F25B39/02
摘要： The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be an epoxide, fluorinated epoxide or oxetane, or a mixture thereof with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
摘要翻译： 本发明涉及包含至少一种氟烯烃和有效量的稳定剂的组合物，其可以是环氧化物，氟化环氧化物或氧杂环丁烷，或其与其它稳定剂的混合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。
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5.发明申请ASCORBIC ACID, TEREPHTHALATE AND NITROMETHANE STABILIZERS FOR FLUOROOLEFINS 有权氟尿嘧啶的抗坏血酸，十二烷酸和硝基苯稳定剂公开(公告)号：US20100288966A1
公开(公告)日：2010-11-18
申请号：US12377677
申请日：2007-08-31
申请人： Thomas J. Leck , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Jon Lee Howell
发明人： Thomas J. Leck , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Jon Lee Howell
CPC分类号： C09K5/045 , C09K2205/126
摘要： The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one ascorbic acid, terephthalate, or nitromethane, or mixtures thereof. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
摘要翻译： 本公开涉及包含至少一种氟代烯烃和有效量的包含至少一种抗坏血酸，对苯二甲酸酯或硝基甲烷或其混合物的稳定剂的组合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。
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公开(公告)号：US08101094B2
公开(公告)日：2012-01-24
申请号：US12377645
申请日：2007-08-31
申请人： Jon Lee Howell , Velliyur Nott Mallikarjuna Rao , Thomas J. Leck , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Ekaterina Swearingen , Andrew Edward Feiring
发明人： Jon Lee Howell , Velliyur Nott Mallikarjuna Rao , Thomas J. Leck , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Ekaterina Swearingen , Andrew Edward Feiring
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , C09K2205/126
摘要： The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be a terpene, terpenoid or fullerene; or a mixture of a terpene, terpenoid or fullerene with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
摘要翻译： 本发明涉及包含至少一种氟烯烃和有效量的可以是萜烯，萜烯或富勒烯的稳定剂的组合物; 或萜烯，萜烯或富勒烯与其他稳定剂的混合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。
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公开(公告)号：US08535555B2
公开(公告)日：2013-09-17
申请号：US12377454
申请日：2007-08-31
申请人： Andrew Edward Feiring , Viacheslav A. Petrov , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Thomas J. Leck , Jon Lee Howell
发明人： Andrew Edward Feiring , Viacheslav A. Petrov , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Thomas J. Leck , Jon Lee Howell
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , C09K2205/10 , C09K2205/102 , C09K2205/104 , C09K2205/11 , C09K2205/126 , C09K2205/132 , C09K2205/134 , C09K2205/24 , F25B39/02
摘要： The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be an epoxide, fluorinated epoxide or oxetane, or a mixture thereof with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
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公开(公告)号：US20120085110A1
公开(公告)日：2012-04-12
申请号：US13325966
申请日：2011-12-14
申请人： JON LEE HOWELL , Velliyur Nott Mallikarjuna Rao , Thomas J. Leck , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Ekaterina N. Swearingen , Andrew Edward Feiring
发明人： JON LEE HOWELL , Velliyur Nott Mallikarjuna Rao , Thomas J. Leck , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Ekaterina N. Swearingen , Andrew Edward Feiring
CPC分类号： C09K5/045 , C09K2205/126
摘要： The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be a terpene, terpenoid or fullerene; or a mixture of a terpene, terpenoid or fullerene with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
摘要翻译： 本发明涉及包含至少一种氟烯烃和有效量的可以是萜烯，萜烯或富勒烯的稳定剂的组合物; 或萜烯，萜烯或富勒烯与其他稳定剂的混合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。
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公开(公告)号：US20100301259A1
公开(公告)日：2010-12-02
申请号：US12377474
申请日：2007-08-31
申请人： Thomas J. Leck , Nandini C. Mouli , Barbara Haviland Minor , Mario Joseph Nappa , Jon Lee Howell
发明人： Thomas J. Leck , Nandini C. Mouli , Barbara Haviland Minor , Mario Joseph Nappa , Jon Lee Howell
IPC分类号： C09K5/00
CPC分类号： C09K5/045 , C09K2205/126
摘要： The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one phosphorus-containing compound selected from the group consisting of thiophosphates, butylated triphenylphosphorothionates, and organophosphates. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
摘要翻译： 本公开涉及包含至少一种氟代烯烃和有效量的稳定剂的组合物，其包含至少一种选自硫代磷酸酯，丁基化三苯基硫代硫酸酯和有机磷酸酯的含磷化合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。
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10.发明授权Ascorbic acid, terephthalate and nitromethane stabilizers for fluoroolefins 有权氟代烯烃的抗坏血酸，对苯二甲酸酯和硝基甲烷稳定剂公开(公告)号：US08668791B2
公开(公告)日：2014-03-11
申请号：US13313458
申请日：2011-12-07
申请人： Thomas J. Leck , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Jon Lee Howell
发明人： Thomas J. Leck , Barbara Haviland Minor , Mario Joseph Nappa , Nandini C. Mouli , Jon Lee Howell
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , C09K2205/126
摘要： The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one ascorbic acid, terephthalate, or nitromethane, or mixtures thereof. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
摘要翻译： 本公开涉及包含至少一种氟代烯烃和有效量的包含至少一种抗坏血酸，对苯二甲酸酯或硝基甲烷或其混合物的稳定剂的组合物。 稳定的组合物可用于冷却装置，例如制冷，空调，冷却器和热泵，以及作为泡沫发泡剂，溶剂，气溶胶推进剂，灭火剂和灭菌剂的应用。
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