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公开(公告)号：US06387152B1
公开(公告)日：2002-05-14
申请号：US09593339
申请日：2000-06-14
IPC分类号： C01B624
摘要： In a process of producing nanocrystalline metal hydrides, an elemental metal hydride of a first kind is subjected to a mechanical milling process with at least one elemental metal or at least one additional metal hydride to produce an alloy hydride.
摘要翻译： 在制造纳米晶体金属氢化物的方法中，将第一种元素金属氢化物用至少一种元素金属或至少一种另外的金属氢化物进行机械研磨工艺以产生合金氢化物。
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2.发明授权公开(公告)号：US06752881B2
公开(公告)日：2004-06-22
申请号：US09962859
申请日：2001-09-25
IPC分类号： C22C2300
CPC分类号： B01J23/24 , C01B3/00 , C01B6/00 , C22C1/10 , C22C23/00 , C22C32/00 , H01M4/24 , H01M4/38 , H01M4/58 , Y02E60/324
摘要： In a metalliferous storage material for hydrogen a metal oxide is provided in or on the surface of the metalliferous materialas a catalyst for the hydrogenation or dehydrogenation of the metalliferous storage material.
摘要翻译： 在用于氢的金属储存材料中，金属材料的表面中或其上的金属氧化物是用于金属蓄电材料的氢化或脱氢的催化剂。
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公开(公告)号：US07833928B2
公开(公告)日：2010-11-16
申请号：US10568690
申请日：2004-08-12
CPC分类号： C01B3/0078 , Y02E60/327 , Y02E60/328 , Y10S420/90
摘要： The invention relates to a metal-containing, hydrogen-storing material which contains a catalyst for the purpose of hydration or dehydration, said catalyst being a metal carbonate. The method for producing such a metal-containing, hydrogen-storing material is characterized by subjecting the metal-containing material and/or the catalyst in the form of a metal carbonate to a mechanical milling process.
摘要翻译： 本发明涉及一种含金属的储氢材料，其含有用于水合或脱水目的的催化剂，所述催化剂是金属碳酸盐。 制造这种含金属的储氢材料的方法的特征在于，使金属碳酸盐材料和/或催化剂以金属碳酸盐的形式进行机械研磨。
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4.发明授权Device and method for analyzing atomic and/or molecular elements by means of wavelength dispersive X-ray spectrometric devices 有权通过波长色散X射线光谱仪分析原子和/或分子元素的装置和方法公开(公告)号：US06628748B2
公开(公告)日：2003-09-30
申请号：US10012232
申请日：2001-12-07
IPC分类号： G41T136
CPC分类号： B82Y10/00 , G01N23/223 , G01N2223/076 , G21K1/062
摘要： In a device and a method for the analysis of atomic and molecular elements by way of wavelength dispersive x-ray spectrometric structures including at least one mirror or focussing device having a multi-layer structure onto which fluorescent radiation generated by primary x-ray or electrons beams from a sample to be examined is directed and the reflected fluorescence radiation is supplied to a measuring device for determining the nature of impurities contained in the sample, the multi-layer structure consists of at least a lanthanum layer and a boron carbide layer.
摘要翻译： 在用于通过波长色散X射线光谱结构分析原子和分子元素的装置和方法中，包括至少一个具有多层结构的反射镜或聚焦装置，在其上由初级x射线或电子产生的荧光辐射 将来自待检测样品的光束导向，并将反射的荧光辐射提供给用于确定样品中所含杂质的性质的测量装置，多层结构由至少镧层和碳化硼层组成。
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公开(公告)号：US08926861B2
公开(公告)日：2015-01-06
申请号：US12742504
申请日：2008-10-30
申请人： Nico Eigen , Martin Dornheim , Rüdiger Bormann
发明人： Nico Eigen , Martin Dornheim , Rüdiger Bormann
CPC分类号： C01B3/0078 , B02C23/18 , Y02E60/327
摘要： The present invention relates to a hydrogen-storing composite material which is convertible essentially reversibly between a storing state and a non-storing state, wherein the reaction enthalpy in this conversion reaction can be set in a targeted manner to a value between 15 and 80 kJ/mol of H2, preferably 25 to 40 kJ/mol of H2. Hydrogen-storing composite materials are characterized in that, in the storing state, they comprise at least one complex metal halide of alkali metal or alkaline earth metal and an element of main group three of the Periodic Table of the Elements and also at least one complex metal hydride of alkali metal or alkaline earth metal and an element of main group three of the Periodic Table of the Elements, or in the storing state at least one metal halohydride of alkali metal or alkaline earth metal and an element of main group three of the Periodic Table of the Elements, and in the non-storing state, at least one alkali metal halide or alkaline earth metal halide and a metal of main group three of the Periodic Table of the Elements.
摘要翻译： 本发明涉及一种在储存状态和非储存状态之间基本可逆转换的储氢复合材料，其中该转化反应中的反应焓可以以目标方式设定在15至80kJ之间 的H2，优选为25〜40kJ / mol的H 2。 储氢复合材料的特征在于，在储存状态下，它们包含至少一种碱金属或碱土金属的复合金属卤化物和元素周期表中第三组的元素，并且还包含至少一个络合物 碱金属或碱土金属的金属氢化物和元素周期表第三组的元素，或在储存状态下，碱金属或碱土金属的至少一种金属卤化氢和主要组3的元素 元素周期表，在非储存状态下，元素周期表中至少有一种碱金属卤化物或碱土金属卤化物和主要三元金属。
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公开(公告)号：US20130187085A1
公开(公告)日：2013-07-25
申请号：US12742504
申请日：2008-10-30
申请人： Nico Eigen , Martin Dornheim , Rüdiger Bormann
发明人： Nico Eigen , Martin Dornheim , Rüdiger Bormann
CPC分类号： C01B3/0078 , B02C23/18 , Y02E60/327
摘要： The present invention relates to a hydrogen-storing composite material which is convertible essentially reversibly between a storing state and a non-storing state, wherein the reaction enthalpy in this conversion reaction can be set in a targeted manner to a value between 15 and 80 kJ/mol of H2, preferably 25 to 40 kJ/mol of H2. Hydrogen-storing composite materials are characterized in that, in the storing state, they comprise at least one complex metal halide of alkali metal or alkaline earth metal and an element of main group three of the Periodic Table of the Elements and also at least one complex metal hydride of alkali metal or alkaline earth metal and an element of main group three of the Periodic Table of the Elements, or in the storing state at least one metal halohydride of alkali metal or alkaline earth metal and an element of main group three of the Periodic Table of the Elements, and in the non-storing state, at least one alkali metal halide or alkaline earth metal halide and a metal of main group three of the Periodic Table of the Elements.
摘要翻译： 本发明涉及一种在储存状态和非储存状态之间基本可逆转换的储氢复合材料，其中该转化反应中的反应焓可以以目标方式设定在15至80kJ之间 的H2，优选为25〜40kJ / mol的H 2。 储氢复合材料的特征在于，在储存状态下，它们包含至少一种碱金属或碱土金属的复合金属卤化物和元素周期表中第三组的元素，并且还包含至少一个络合物 碱金属或碱土金属的金属氢化物和元素周期表第三组的元素，或在储存状态下，碱金属或碱土金属的至少一种金属卤化氢和主要组3的元素 元素周期表，在非储存状态下，元素周期表中至少有一种碱金属卤化物或碱土金属卤化物和主要三元金属。
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7.发明授权Apparatus and method for the analysis of atomic and molecular elements by wavelength dispersive x-ray spectrometric devices 有权用于通过波长色散X射线光谱仪分析原子和分子元素的装置和方法公开(公告)号：US07113567B2
公开(公告)日：2006-09-26
申请号：US10196805
申请日：2002-07-17
IPC分类号： G21K1/06 , G01N23/223 , G01T1/36
CPC分类号： G02B5/0891 , B82Y10/00 , G21K1/062 , G21K2201/061 , G21K2201/064
摘要： In an apparatus and a method for the analysis of atomic or molecular elements contained in a sample by wavelength dispersive X-ray spectrometry, wherein primary x ray or electron radiation is directed onto the sample whereby fluorescence radiation is emitted from the sample, the fluorescence radiation is directed onto a mirror or focussing device consisting of a multi-layer structure including pairs of layers of which one layer of a pair comprises carbon or scandium and the other comprises a metal oxide or a metal nitride and the fluorescence radiation is reflected from the mirror or focussing device onto an analysis detector for the analysis of the atomic or molecular elements contained in the sample.
摘要翻译： 在通过波长色散X射线光谱法分析样品中原子或分子元素的装置和方法中，其中初级x射线或电子辐射被引导到样品上，从而从样品发射荧光辐射，荧光辐射 被引导到由多层结构构成的反射镜或聚焦装置，该多层结构包括一对层，其中一层包括碳或钪，另一层包含金属氧化物或金属氮化物，并且荧光辐射从反射镜反射 或聚焦装置到分析检测器上，以分析样品中包含的原子或分子元素。
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公开(公告)号：US08815207B2
公开(公告)日：2014-08-26
申请号：US12635315
申请日：2009-12-10
CPC分类号： C01B6/00 , C01B6/04 , C01B6/24 , C01B6/243 , Y02E60/324 , Y02E60/327
摘要： The present invention concerns a method of activating or regenerating a hydrogen storage material which contains at least one metal hydride. The at least one metal hydride is brought into contact with an inert solvent and the inert solvent is subsequently removed again. After contacting with and removal of the inert solvent, there is not only an increase in the reaction rate but surprisingly the hydrogenation also proceeds more completely. The present method is particularly advantageous when the hydrogen storage material contains at least components which interact with one another during absorption and desorption.
摘要翻译： 本发明涉及活化或再生含有至少一种金属氢化物的储氢材料的方法。 使至少一种金属氢化物与惰性溶剂接触，随后再次除去惰性溶剂。 在与惰性溶剂接触并除去之后，反应速率不仅有所增加，而且令人惊奇的是氢化也更完全地进行。 当吸收和解吸时，储氢材料至少含有彼此相互作用的组分时，本方法是特别有利的。
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公开(公告)号：US20100160149A1
公开(公告)日：2010-06-24
申请号：US12635315
申请日：2009-12-10
CPC分类号： C01B6/00 , C01B6/04 , C01B6/24 , C01B6/243 , Y02E60/324 , Y02E60/327
摘要： The present invention concerns a method of activating or regenerating a hydrogen storage material which contains at least one metal hydride. The at least one metal hydride is brought into contact with an inert solvent and the inert solvent is subsequently removed again. After contacting with and removal of the inert solvent, there is not only an increase in the reaction rate but surprisingly the hydrogenation also proceeds more completely.The present method is particularly advantageous when the hydrogen storage material contains at least components which interact with one another during absorption and desorption.
摘要翻译： 本发明涉及活化或再生含有至少一种金属氢化物的储氢材料的方法。 使至少一种金属氢化物与惰性溶剂接触，随后再次除去惰性溶剂。 在与惰性溶剂接触并除去之后，反应速率不仅有所增加，而且令人惊奇的是氢化也更完全地进行。 当吸收和解吸时，储氢材料至少含有彼此相互作用的组分时，本方法是特别有利的。
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