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1.发明授权Spiro(bis)indane polyamide and polyimide copolysiloxanes and method of preparation 失效螺（双）茚满聚酰胺和聚酰亚胺共聚硅氧烷及其制备方法
公开(公告)号：US4950727A
公开(公告)日：1990-08-21
申请号：US182020
申请日：1988-04-15
申请人： Thomas L. Guggenheim , James A. Cella , Sharon J. McCormick , Alice M. Colley , Jonathan D. Rich , Philip J. McDermott
发明人： Thomas L. Guggenheim , James A. Cella , Sharon J. McCormick , Alice M. Colley , Jonathan D. Rich , Philip J. McDermott
CPC分类号： C08G65/4081 , C07C65/26
摘要： Linear polyamide and polyimide copolysiloxane compositions are prepared by contacting a strongly acidic catalyst, basic catalyst or alkali metal fluoride with a macrocyclic spirobiindane polyamide or polyimide disiloxane, either alone or in combination with a cyclic polysiloxane such as octamethylcyclotetrasiloxane.
摘要翻译： 线性聚酰胺和聚酰亚胺共聚硅氧烷组合物通过单独或与环状聚硅氧烷如八甲基环四硅氧烷组合使强酸性催化剂，碱性催化剂或碱金属氟化物与大环螺茚二酰胺聚酰胺或聚酰亚胺二硅氧烷接触来制备。
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公开(公告)号：USRE34431E
公开(公告)日：1993-11-02
申请号：US915381
申请日：1992-05-08
申请人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
发明人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
IPC分类号： C08G63/193 , C08G64/06 , C08G64/18 , C08G65/40 , C08G65/48 , C08G69/26 , C08G73/10 , C08G75/23 , C08G63/00 , C07D231/00 , C07F7/04 , C08G69/42
CPC分类号： C08G63/193 , C08G64/06 , C08G64/183 , C08G65/4081 , C08G65/48 , C08G69/26 , C08G73/10 , C08G75/23
摘要： Macrocyclic oligomers, including polycarbonates, polyesters, polyamides, polyimides, polyetherketones and polyethersulfones, are conveniently prepared from various spiro(bis)indane compounds, especially the 6,6'-difunctional 3,3',3'-tetramethylspiro(bis)indanes. The macrocyclic oligomers may be conveniently converted to linear polymers.
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公开(公告)号：US4980453A
公开(公告)日：1990-12-25
申请号：US146154
申请日：1988-01-20
申请人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
发明人： Daniel J. Brunelle , Thomas L. Guggenheim , James A. Cella , Thomas L. Evans , Luca P. Fontana , Gary R. Faler , James M. Fukuyama , Eugene P. Boden , Jonathan D. Rich , Thomas G. Shannon , Sharon J. McCormick , Philip J. McDermott , Alice M. Colley , Joseph W. Guiles
CPC分类号： C08G75/23 , C08G64/06 , C08G65/4081
摘要： Macrocyclic oligomers, including polycarbonates, polyesters, polyamides, polyimides, polyetherketones and polyethersulfones, are conveniently prepared from various spiro(bis)indane compounds, especially the 6,6'-difunctional 3,3',3'-tetramethylspiro(bis)indanes. The macrocyclic oligomers may be conveniently converted to linear polymers.
摘要翻译： 大环低聚物，包括聚碳酸酯，聚酯，聚酰胺，聚酰亚胺，聚醚酮和聚醚砜，可以方便地由各种螺（双）二氢化茚化合物，特别是6,6'-二官能3,3'，3'-四甲基螺（双）二氢化茚制备。 大环低聚物可以方便地转化为线性聚合物。
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公开(公告)号：US4868279A
公开(公告)日：1989-09-19
申请号：US156126
申请日：1988-02-16
CPC分类号： C08G65/4081 , C08G63/193 , C08G64/06 , C08G64/183 , C08G69/00 , C08G69/14
摘要： Copolyamides are prepared by the reaction of monocyclic spiro(bis)indane polyamide oligomers with lactams in the presence of basic reagents.
摘要翻译： 通过在碱性试剂存在下，单环螺（双）二氢化茚聚酰胺低聚物与内酰胺的反应制备共聚酰胺。
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公开(公告)号：US4927904A
公开(公告)日：1990-05-22
申请号：US364294
申请日：1989-06-12
IPC分类号： C08G63/181 , C07D321/00 , C07D323/00 , C08G63/19 , C08G63/195 , C08G63/79 , C08G63/87
CPC分类号： C08G63/195 , C08G63/87
摘要： Cyclic polyarylate oligomer compositions are prepared by the reaction of an aromatic dicarboxylic acid halide, such as isophthaloyl chloride or terephthaloyl chloride, with a water-soluble salt of a dihydroxyaromatic compound, such as bisphenol A disodium salt. Freshly prepared solutions of the halide in an organic liquid such as methylene chloride, and of the salt in water, are simultaneously introduced into an organic liquid containing a catalytic amount of at least one quaternary ammonium salt having a single alkyl group containing about 8-20 carbon atoms and having not more than 5 additional carbon atoms. The dihydroxyaromatic compound salt is employed in the amount of at least about 3% in excess of stoichiometric.
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6.发明授权
公开(公告)号：US4945147A
公开(公告)日：1990-07-31
申请号：US319027
申请日：1989-03-06
申请人： Peter P. Policastro , Pamela K. Hernandez , Sandra A. Swint , Gary C. Davis , Jonathan D. Rich , Philip J. McDermott , Thomas L. Guggenheim
发明人： Peter P. Policastro , Pamela K. Hernandez , Sandra A. Swint , Gary C. Davis , Jonathan D. Rich , Philip J. McDermott , Thomas L. Guggenheim
IPC分类号： C08G63/695 , C08G63/19 , C08G63/68 , C08G77/42 , C08G77/445 , C08L69/00
CPC分类号： C08G77/445 , C08G63/6956
摘要： There is provided by the present invention aromatic polyester-siloxane block copolymers which can be made by effecting the condensation between tetramethyldisiloxane bisbenzoic acid or acid chloride with a dihydric phenol such as bisphenol A or in combination with a mixture of such tetramethyldisiloxane bisbenzoic acid and aromatic acids, such as terephthalic acid or isophthalic acid. The aromatic polyester-siloxane block copolymers can be used as molding compounds, extruded films, in making composite matrix materials and as flame retardants for aromatic polycarbonates.
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公开(公告)号：US4945148A
公开(公告)日：1990-07-31
申请号：US319025
申请日：1989-03-06
申请人： Jonathan D. Rich , Philip J. McDermott , Gary C. Davis , Peter P. Policastro , Karen A. Regh , Pamela K. Hernandez , Thomas L. Guggenheim
发明人： Jonathan D. Rich , Philip J. McDermott , Gary C. Davis , Peter P. Policastro , Karen A. Regh , Pamela K. Hernandez , Thomas L. Guggenheim
CPC分类号： C08G64/186 , C08G77/448
摘要： Silicone-polycarbonate block copolymers are provided resulting from the reaction of certain siloxy aromatic imide siloxanes or hydroxyaromatic ester siloxanes which are made by effecting reaction between an organosiloxane having terminal aromatic anhydride groups or aromatic haloacyl groups which are each attached to silicon by silicon arylene linkages with an appropriate bishydroxyarylene compounds or hydroxyarylene amino compound. The aforementioned hydroxyaromatic imide siloxanes or hydroxyaromatic ester siloxanes are then phosgenated with a dihydric phenol or an aromatic bischloroformate. The silicone-polycarbonate block copolymers have been found to be flame retardant and useful as dielectric films and membranes, and as flame retardants in aromatic polycarbonates.
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公开(公告)号：US5243009A
公开(公告)日：1993-09-07
申请号：US851704
申请日：1992-03-16
申请人： Jonathan D. Rich , Philip J. McDermott , Gary C. Davis , Peter P. Policastro , Karen A. Regh , Pamela K. Hernandez , Thomas L. Guggenheim
发明人： Jonathan D. Rich , Philip J. McDermott , Gary C. Davis , Peter P. Policastro , Karen A. Regh , Pamela K. Hernandez , Thomas L. Guggenheim
IPC分类号： C08G64/18 , C08G77/448
CPC分类号： C08G77/448 , C08G64/186
摘要： Silicone-polycarbonate block copolymers are provided resulting from the reaction of certain siloxy aromatic imide siloxanes or hydroxyaromatic ester siloxanes which are made by effecting reaction between an organosiloxane having terminal aromatic anhydride groups or aromatic haloacyl groups which are each attached to silicon by silicon arylene linkages with an appropriate bishydroxyarylene compounds or hydroxyarylene amino compound. The aforementioned hydroxyaromatic imide siloxanes or hydroxyaromatic ester siloxanes are then phosgenated with a dihydric phenol or an aromatic bischloroformate. The silicone-polycarbonate block copolymers have been found to be flame retardant and useful as dielectric films and membranes, and as flame retardants in aromatic polycarbonates.
摘要翻译： 提供的硅氧烷 - 聚碳酸酯嵌段共聚物是由某些甲硅烷氧基芳族酰亚胺硅氧烷或羟基芳族酯硅氧烷的反应产生的，这些硅氧烷或羟基芳族酯硅氧烷是通过使具有末端芳族酸酐基团的有机硅氧烷或芳族卤代酰基与硅烷基链接在硅上的反应制得的， 合适的双羟基亚芳基化合物或羟基亚芳基氨基化合物。 然后将上述羟基芳族酰亚胺硅氧烷或羟基芳族酯硅氧烷用二元酚或芳族双氯甲酸酯进行光气化。 已经发现硅氧烷 - 聚碳酸酯嵌段共聚物是阻燃剂并且可用作介电膜和膜，并且作为芳族聚碳酸酯中的阻燃剂。
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公开(公告)号：US4808754A
公开(公告)日：1989-02-28
申请号：US20264
申请日：1987-02-27
IPC分类号： C08G69/00 , C08G63/193 , C08G64/06 , C08G64/18 , C08G65/40 , C08G69/04 , C08G69/14 , C07C147/107
CPC分类号： C08G64/06 , C08G63/193 , C08G64/183 , C08G65/4081 , C08G69/00 , C08G69/14
摘要： Cyclic polyamide oligomers are prepared by the reaction of various spirobiindane diamines, including spirobiindane bisphenol bis-aminophenoxy ethers, with dicarboxylic acid chloride such as isophthaloyl chloride. The oligomer compositions may be converted to copolyamides by reaction with lactams in the presence of basic reagents.
摘要翻译： 环状聚酰胺低聚物通过各种螺二茚二胺（包括螺二茚满双酚双氨基苯氧基醚）与二羧酸氯化物如间苯二酰氯的反应来制备。 低聚物组合物可以通过在碱性试剂存在下与内酰胺反应而转化成共聚酰胺。
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公开(公告)号：US4814496A
公开(公告)日：1989-03-21
申请号：US157009
申请日：1988-02-18
CPC分类号： C07C65/26
摘要： Esters of spiro(bis)indane bis(carboxyphenyl ethers) are prepared by the reaction of spiro(bis)indane bisphenol di-(alkali metal) salts with nitro- or chloro-substituted benzoic acid esters, and may be converted to the free acids and thence to the acid chlorides. The latter are useful for preparation of macrocyclic polyamide oligomers.
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