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公开(公告)号：US6069213A
公开(公告)日：2000-05-30
申请号：US991688
申请日：1997-12-16
IPC分类号： C08F2/34 , C08F4/02 , C08F4/60 , C08F4/6192 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F210/16 , C08F4/06 , C08F4/72
CPC分类号： C08F10/00 , C08F10/02 , C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , Y10S526/943
摘要： It has been found that the use of at least one unsupported metallocene polymerization catalyst with at least one supported metallocene polymerization catalyst in the polymerization of olefins allows for better control of the polymerization, especially gas phase polymerization. Such a system takes advantage of the high activity of the unsupported catalyst and the stability of a supported catalyst. Additionally, the relative timing of the addition of the supported and unsupported catalysts to a reaction system can be used to control a continuous polymerization reaction by stabilizing the reactor bed with the supported catalyst prior to addition of the unsupported catalyst.
摘要翻译： 已经发现，在烯烃聚合中使用至少一种未负载的茂金属聚合催化剂与至少一种负载的茂金属聚合催化剂可以更好地控制聚合，特别是气相聚合。 这种系统利用了无载体催化剂的高活性和负载型催化剂的稳定性。 此外，将负载型催化剂和未负载的催化剂加入到反应体系中的相对时间可以用于通过在加入未负载的催化剂之前用负载型催化剂稳定反应器床来控制连续聚合反应。
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公开(公告)号：US6136747A
公开(公告)日：2000-10-24
申请号：US100811
申请日：1998-06-19
IPC分类号： C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , B01J31/00
CPC分类号： C08F10/00 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61922 , Y10S526/943
摘要： A mixed catalyst composition comprising a) a solid Ziegler-Natta catalyst; b) a liquid single site catalyst; and c) at least one activating cocatalyst is provided. Polymers having a broad or bimodal molecular weight distribution may be made with this catalyst composition.
摘要翻译： 一种混合催化剂组合物，其包含a）固体齐格勒 - 纳塔催化剂; b）液体单中心催化剂; 和c）提供至少一种活化助催化剂。 可以用该催化剂组合物制备具有宽或双峰分子量分布的聚合物。
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3.发明授权公开(公告)号：US06281320B1
公开(公告)日：2001-08-28
申请号：US09244442
申请日：1999-02-04
IPC分类号： C08F1000
CPC分类号： C08F10/00 , C08F210/16 , Y10S526/943 , C08F4/65925 , C08F4/65912 , C08F210/14 , C08F2500/03
摘要： This invention comprises a metallocene catalyst system for the production of high molecular weight polyolefins, particularly polyethylene and higher poly-alpha olefins, and copolymers of ethylene and/or alpha olefins with other unsaturated monomers, including diolefins, acetylenically unsaturated monomers and cyclic olefins. The catalyst system is highly active, at low ratios of Al to transition metal, and hence catalyzes the production of a polyolefin product containing low levels of catalyst metal residues. The catalyst system comprises (i) a metallocene precursor (Component A), aluminoxane (Component B), and phenolic modifier (Component C) or (ii) the reaction product of a metallocene precursor with a phenolic compound (Component A′) and aluminoxane (Component B). There is also provide a polymerization process using the catalyst and the product so produced.
摘要翻译： 本发明包括用于生产高分子量聚烯烃，特别是聚乙烯和更高级聚-α-烯烃的茂金属催化剂体系，以及乙烯和/或α-烯烃与其它不饱和单体（包括二烯烃，炔属不饱和单体和环烯烃）的共聚物。 催化剂体系在Al与过渡金属的低比例下是高活性的，因此催化了含有低水平催化剂金属残余物的聚烯烃产物的生产。 催化剂体系包括（i）茂金属前体（组分A），铝氧烷（组分B）和酚类改性剂（组分C）或（ii）金属茂前体与酚类化合物（组分A'）和铝氧烷的反应产物 （组分B）。 还提供使用催化剂和如此制备的产物的聚合方法。
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4.发明授权Process for the production of half-sandwich transition metal based catalyst precursors 失效制备半夹心过渡金属基催化剂前体的方法
公开(公告)号：US6069109A
公开(公告)日：2000-05-30
申请号：US108824
申请日：1998-07-01
CPC分类号： B01J31/1805 , B01J31/2204 , B01J31/223 , B01J31/2295 , C07F17/00 , C08F10/00 , B01J2531/30 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/50 , B01J2531/60 , B01J2531/70 , B01J2531/80
摘要： A process for the production of a catalyst precursor comprising reacting (a) a metallocene dihalide; (b) a compound of the formula: ##STR1## wherein each Q is the same or different and is independently selected from the group consisting of O, NR, CR.sub.2, and S; E is either C or S; Z is selected from the group consisting of --OR, --NR.sub.2, --CR.sub.3, --SR, --SiR.sub.3, --PR.sub.2, --H, and a substituted or unsubstituted aryl group; and each R is independently a group containing carbon, silicon, nitrogen, oxygen, and/or phosphorus; and (c) a trialkylamine.
摘要翻译： 一种制备催化剂前体的方法，包括使（a）金属茂二卤化物 （b）下式的化合物：其中每个Q相同或不同并且独立地选自O，NR，CR 2和S; E是C或S; Z选自-OR，-NR2，-CR3，-SR，-SiR3，-PR2，-H和取代或未取代的芳基; 并且每个R独立地是含有碳，硅，氮，氧和/或磷的基团; 和（c）三烷基胺。
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公开(公告)号：US20120220747A1
公开(公告)日：2012-08-30
申请号：US13465135
申请日：2012-05-07
IPC分类号： C08F110/02
CPC分类号： B29C47/64 , B29B7/421 , B29C47/0004 , B29C47/0026 , B29C47/1063 , B29C47/1072 , B29C49/0005 , B29C49/04 , B29C49/06 , B29K2023/06 , B29K2023/0633 , B29K2023/065 , B29K2105/0005 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2314/06 , C08L2666/06
摘要： Bimodal polyethylene compositions and methods for making the same are provided. In at least one specific embodiment, the bimodal polyethylene composition can include a high molecular weight component having a weight average molecular weight (Mw) of from about 400,000 to about 950,000. The bimodal polyethylene composition can also include a low molecular weight component having a weight average molecular weight (Mw) of from about 3,000 to about 100,000. The high molecular weight component can be present in an amount ranging from about 25 wt % to about 40 wt % of the bimodal polyethylene composition. The bimodal polyethylene composition can also have a percent die swell of less than about 80%.
摘要翻译： 提供双峰聚乙烯组合物及其制备方法。 在至少一个具体实施方案中，双峰聚乙烯组合物可包括重均分子量（Mw）为约400,000至约950,000的高分子量组分。 双峰聚乙烯组合物还可以包括重均分子量（Mw）为约3,000至约100,000的低分子量组分。 高分子量组分可以以双峰聚乙烯组合物的约25重量％至约40重量％的量存在。 双峰聚乙烯组合物还可以具有小于约80％的模头膨胀百分比。
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公开(公告)号：US20120046428A1
公开(公告)日：2012-02-23
申请号：US13258945
申请日：2010-05-14
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65904 , C08F4/64148 , C08F4/64048
摘要： A polymerization catalyst system and polymerization processes using the catalyst systems are disclosed. The polymerization catalyst systems may include a) a first catalyst compound, and b) a second catalyst compound, wherein the first catalyst compound includes an oxadiazole-containing compound. In some embodiments, the oxadiazole-containing compound has essentially no hydrogen response, thus allowing better and/or tailored control of product properties when producing polymers using the catalyst system.
摘要翻译： 公开了使用催化剂体系的聚合催化剂体系和聚合方法。 聚合催化剂体系可以包括a）第一催化剂化合物，和b）第二催化剂化合物，其中第一催化剂化合物包括含恶二唑的化合物。 在一些实施方案中，含恶二唑的化合物基本上没有氢气响应，因此当使用催化剂体系制备聚合物时，可以更好和/或定制地控制产品性质。
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公开(公告)号：US07323526B2
公开(公告)日：2008-01-29
申请号：US11192935
申请日：2005-07-29
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , Y02P20/582 , Y10S526/941 , Y10S526/943 , C08F4/65916
摘要： A supported catalyst composition having improved flow properties is disclosed comprising an alkylalumoxane, a metallocene-alkyl an inorganic oxide support having an average particle size of from 0.1 to 50 μm and calcined at a temperature greater than 600° C., and optionally an antifoulant agent and. In one embodiment, the metallocene-alkyl is a Group 4, 5 or 6 metallocene-alkyl, and in another embodiment is a hafnocene-alkyl. Also disclosed is a method of polymerization using such a supported catalyst composition.
摘要翻译： 公开了具有改进的流动性质的负载型催化剂组合物，其包含烷基铝氧烷，茂金属 - 烷基和平均粒度为0.1-50μm的无机氧化物载体，并且在大于600℃的温度下煅烧，以及任选的防污剂 和。 在一个实施方案中，茂金属 - 烷基是第4,5或6族茂金属 - 烷基，在另一个实施方案中是茂金属 - 烷基。 还公开了使用这种负载型催化剂组合物的聚合方法。
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公开(公告)号：US06956094B2
公开(公告)日：2005-10-18
申请号：US10772823
申请日：2004-02-05
申请人： Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
发明人： Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
IPC分类号： C08F2/00 , C08F2/34 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F12/06
CPC分类号： C08F10/00 , C08F4/659 , C08F4/65912 , C08F4/65925 , C08F210/16 , Y10S526/905 , Y10S526/943 , C08F4/65904 , C08F4/65916 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F2500/26
摘要： The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.
摘要翻译： 本发明提供聚合催化剂组合物以及用于将催化剂组合物引入聚合反应器的方法。 更具体地说，该方法结合了含催化剂组分的浆料和含催化剂组分的溶液以形成用于引入聚合反应器的完成的催化剂组合物。 本发明还涉及制备催化剂组分浆料，催化剂组分溶液和催化剂组合物的方法，以及使用该催化剂组合物控制聚合物产品性能的方法以及由其制备的聚合物。
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公开(公告)号：US06605675B2
公开(公告)日：2003-08-12
申请号：US09729550
申请日：2000-12-04
申请人： Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
发明人： Simon Mawson , Sun-Chueh Kao , Tae Hoon Kwalk , Timothy Roger Lynn , David H. McConville , Matthew Gary McKee , John Francis Szul , Kersten Anne Terry , Timothy T. Wenzel , Mark Gregory Goode , John Henry Oskam , Robert J. Jorgensen , Robert Harold Vogel
IPC分类号： C08F444
CPC分类号： B01J8/1827 , B01J4/002 , B01J2219/00108 , C08F4/659 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F210/16 , Y10S526/943 , C08F4/65916 , C08F4/65904 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18 , C08F2500/26
摘要： The invention provides for polymerization catalyst compositions, and for methods for introducing the catalyst compositions into a polymerization reactor. More particularly, the method combines a catalyst component containing slurry and a catalyst component containing solution to form the completed catalyst composition for introduction into the polymerization reactor. The invention is also directed to methods of preparing the catalyst component slurry, the catalyst component solution and the catalyst compositions, to methods of controlling the properties of polymer products utilizing the catalyst compositions, and to polymers produced therefrom.
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公开(公告)号：US06605563B1
公开(公告)日：2003-08-12
申请号：US10359933
申请日：2003-02-06
申请人： Sun-Chueh Kao , Jaimes Sher , Frederick J. Karol
发明人： Sun-Chueh Kao , Jaimes Sher , Frederick J. Karol
IPC分类号： C08F464
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/6592 , Y10S526/943 , C08F4/65912 , C08F210/14 , C08F2500/03
摘要： A polymerization catalyst system and a method for preparing the catalyst system is disclosed. The catalyst system includes a bulky ligand metallocene catalyst compound, preferably containing a single cyclopentadienyl or substituted cyclopentadienyl-type ring system, a Group 13 element containing first modifier, and a cycloalkadiene second modifier. The present invention also provides a process for polymerizing olefin(s) utilizing the catalyst systems described herein.
摘要翻译： 公开了聚合催化剂体系和制备催化剂体系的方法。 催化剂体系包括体积庞大的配位金属茂催化剂化合物，优选含有单个环戊二烯基或取代的环戊二烯基型环系，含有第13族元素的第一改性剂和环二烯二烯改性剂。 本发明还提供了利用本文所述的催化剂体系聚合烯烃的方法。
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