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    Method for the continuous production of aldehydes
    6.
    发明授权
    Method for the continuous production of aldehydes 失效
    连续生产醛的方法

    公开(公告)号：US07615645B2

    公开(公告)日：2009-11-10

    申请号：US10575843

    申请日：2004-10-14

    申请人： Martin Volland ,  Thomas Mackewitz ,  Wolfgang Ahlers ,  Ansgar Schäfer ,  Wolfgang Richter ,  Rocco Paciello

    发明人： Martin Volland ,  Thomas Mackewitz ,  Wolfgang Ahlers ,  Ansgar Schäfer ,  Wolfgang Richter ,  Rocco Paciello

    IPC分类号： C07C45/50 ,  C07D207/00

    CPC分类号： B01J31/186 ,  B01J2231/321 ,  B01J2531/822 ,  C07C45/50 ,  C07C47/02

    摘要： The invention relates to a method for the continuous production of aldehydes by the isomerising hydroformylation in a homogenous phase of olefin compositions by means of a synthesis gas, in the presence of a homogeneous rhodium catalyst that is complexed with an organophosphorus ligand containing oxygen atoms and/or nitrogen atoms and a free ligand. The production is carried out at high temperature and high pressure in a multi-stage reaction system consisting of at least two reaction zones. According to the method, the olefin composition is first reacted in a first reaction zone or a group of several first reaction zones at a total pressure of between 10 and 40 bar, using a synthesis gas with a CO/H2 molar ratio of between 4:1 and 1:2 until a 40 to 95% conversion of the α-olefins is obtained.

    摘要翻译： 本发明涉及通过在与含氧原子的有机磷配体络合的均匀铑催化剂的存在下，通过合成气在烯烃组合物的均相中通过异构化加氢甲酰化连续生产醛的方法和/ 或氮原子和游离配体。 在由至少两个反应区组成的多级反应体系中，在高温高压下进行生产。 根据该方法，首先使用CO / H 2摩尔比为4：4的合成气，在10-400巴的总压力下，在第一反应区或几个第一反应区的一组中反应烯烃组合物。 1和1：2，直到获得40-95％的α-烯烃转化率。

    Method for the continuous production of aldehydes
    7.
    发明申请
    Method for the continuous production of aldehydes 失效
    连续生产醛的方法

    公开(公告)号：US20070004939A1

    公开(公告)日：2007-01-04

    申请号：US10575843

    申请日：2004-10-14

    申请人： Martin Volland ,  Thomas Mackewitz ,  Wolfgang Ahlers ,  Ansgar Schafer ,  Wolfgang Richter ,  Rocco Paciello

    发明人： Martin Volland ,  Thomas Mackewitz ,  Wolfgang Ahlers ,  Ansgar Schafer ,  Wolfgang Richter ,  Rocco Paciello

    IPC分类号： C07C45/50

    CPC分类号： B01J31/186 ,  B01J2231/321 ,  B01J2531/822 ,  C07C45/50 ,  C07C47/02

    摘要： The invention relates to a method for the continuous production of aldehydes comprising between 5 and 21 carbon atoms, by the isomerising hydroformylation in a homogenous phase of olefin compositions comprising between 4 and 20 carbon atoms and containing α-olefins and olefins with internal double bonds, by means of a synthesis gas, in the presence of a homogeneous rhodium catalyst that is complexed with an organophosphorus ligand containing oxygen atoms and/or nitrogen atoms and a free ligand. Said production is carried out at high temperature and high pressure in a multi-stage reaction system consisting of at least two reaction zones. According to said method, the olefin composition is first reacted in a first reaction zone or a group of several first reaction zones at a total pressure of between 10 and 40 bar, using a synthesis gas with a CO/H2 molar ratio of between 4:1 and 1:2 until a 40 to 95% conversion of the α-olefins is obtained. The hydroformylation product from the first reaction zone or group of several first reaction zones is then reacted in a subsequent reaction zone or group of several reaction zones at a total pressure of between 5 and 30 bar, using a synthesis gas with a CO/H2 molar ratio of between 1:4 and 1:1000. The total pressure in the subsequent reaction zone or zones is respectively 1 to (G1−Gf) bar lower than that of the preceding reaction zone, whereby G1 represents the total pressure in the respective preceding reaction zone and Gf represents the total pressure in the respective reaction zone that succeeds said first reaction zone or zones, with the proviso that the difference between G1 and Gf is greater than 1 bar and the partial CO pressure in the subsequent reaction zone or zones is respectively lower than that of the preceding reaction zone.

    摘要翻译： 本发明涉及通过在包含4至20个碳原子并含有具有内部双键的α-烯烃和烯烃的烯烃组合物的均质相中的异构化加氢甲酰化来连续生产含有5至21个碳原子的醛的方法， 在与含有氧原子和/或氮原子的有机磷配体和游离配体络合的均匀的铑催化剂的存在下，通过合成气。 所述生产在由至少两个反应区组成的多级反应体系中在高温高压下进行。 根据所述方法，首先使用具有CO / H 2 O 2的合成气在第一反应区或一组几个第一反应区中以10至40巴的总压力反应烯烃组合物， 的摩尔比在4:1和1:2之间，直到获得40-95％的α-烯烃转化率。 然后使用具有CO / H 2的合成气使来自第一反应区或几个第一反应区的组的加氢甲酰化产物在随后的反应区或几个反应区的组中以5至30巴的总压力反应， 1摩尔比为1:4-1:1000。 后续反应区域或区域中的总压力分别比前述反应区域低1〜（G1-Gf）巴，由此G1表示前述反应区域中的总压力，Gf表示相应的 所述第一反应区或区域成功的反应区，条件是G 1和G f之间的差大于1巴，并且后续反应区或区中的部分CO压力分别低于前述反应区。

    Phosphabenzene compounds and their use in hydroformylation
    8.
    发明授权
    Phosphabenzene compounds and their use in hydroformylation 失效
    膦酸化合物及其在加氢甲酰化中的应用

    公开(公告)号：US06509505B1

    公开(公告)日：2003-01-21

    申请号：US09936346

    申请日：2001-09-11

    申请人： Rocco Paciello ,  Thomas Mackewitz ,  Michael Röper ,  Bernhard Breit

    发明人： Rocco Paciello ,  Thomas Mackewitz ,  Michael Röper ,  Bernhard Breit

    IPC分类号： C07F950

    CPC分类号： B01J31/2419 ,  B01J31/2466 ,  B01J2531/80 ,  B01J2531/822 ,  C07C45/50 ,  C07D309/34 ,  C07F9/6568 ,  C07F15/008 ,  C07C47/02

    摘要： Phosphabenzene compounds of the formula (I) where the radicals R1 to R13 are, independently of one another, hydrogen, COOM, SO3M, NR3X, NR2, OR, COOR or SR (where M=hydrogen, NH4 or alkali metal, X=anion, R=hydrogen or C1-C6-alkyl), or C1-C12-alkyl, C6-C12-aryl, C7-C12-aralkyl, C7-C12-alkaryl or C3-C6-heteroaromatics, where the alkyl, aryl, alkaryl and aralkyl radicals may bear the abovementioned radicals as substituents and two or more of the radicals may be joined to form aliphatic or fused-on rings, where at least one of the radicals R4 and R8 and at least one of the radicals R9 and R13 is not hydrogen, can be used for preparing hydroformylation catalysts.

    摘要翻译： 其中基团R 1至R 13彼此独立地为氢，COOM，SO 3 M，NR 3 X，NR 2，OR，COOR或SR（其中M =氢，NH 4或碱金属，X =阴离子）的式（I） 或C 1 -C 12 - 烷基，C 6 -C 12 - 芳基，C 7 -C 12 - 芳烷基，C 7 -C 12烷芳基或C 3 -C 6 - 杂芳族化合物，其中烷基，芳基，烷芳基 并且芳烷基可以带有上述基团作为取代基，并且两个或更多个基团可以连接形成脂族或稠合环，其中基团R 4和R 8中的至少一个以及基团R 9和R 13中的至少一个是 不是氢，可用于制备加氢甲酰化催化剂。