COPOLYMERIZABLE SURFACTANTS
    1.
    发明申请
    COPOLYMERIZABLE SURFACTANTS 审中-公开
    可共聚表面活性剂

    公开(公告)号:US20130317190A1

    公开(公告)日:2013-11-28

    申请号:US13979770

    申请日:2011-10-08

    摘要: The invention relates to the use of compounds of the formula (I), R—CH(O—(AO)mX)—CH2—O—(AO)—CH2—CH═CH2, where: R denotes an alkyl radical which has 8 to 18 carbon atoms and can be saturated or unsaturated, straight-chain or branched; X denotes a sulfate or phosphate group or hydrogen; (AO) denotes an alkylene oxide unit, selected from the group consisting of ethylene oxide, propylene oxide or butylene oxide; n denotes a number in the range of 0 to 50; and m denotes zero or a number in the range of 1 to 30; as copolymerizable emulsifiers in the emulsion polymerization of olefinically unsaturated monomers.

    摘要翻译: 本发明涉及式(I),R-CH(O-(AO)m X)-CH 2 -O-(AO)-CH 2 -CH = CH 2的化合物的用途,其中:R表示具有 8至18个碳原子,可以是饱和或不饱和的,直链或支链的; X表示硫酸根或磷酸基或氢; (AO)表示选自环氧乙烷,环氧丙烷或环氧丁烷的环氧烷单元; n表示0〜50的范围的数; m表示0或1〜30的数; 作为烯属不饱和单体的乳液聚合中的可共聚的乳化剂。

    Use Of Nonionic Surfactants As Emulsifiers For Emulsion Polymerization (III)
    2.
    发明申请
    Use Of Nonionic Surfactants As Emulsifiers For Emulsion Polymerization (III) 失效
    用作乳液聚合乳化剂的非离子表面活性剂(III)

    公开(公告)号:US20120029131A1

    公开(公告)日:2012-02-02

    申请号:US13259846

    申请日:2010-03-13

    CPC分类号: C08F2/30

    摘要: The invention relates to the use of aqueous solutions of nonionic surfactants as gel phase free emulator systems for the emulsion polymerization, wherein said nonionic surfactants are chosen from the group (a) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, and (b) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, wherein the OH-group of said addition products is end-capped in the sense that it is substituted by a group OR, wherein R is an alkyl group with 1 to 20 C-atoms, which can be saturated or unsaturated, straight chained or branched.

    摘要翻译: 本发明涉及非离子表面活性剂的水溶液用作乳液聚合的无凝胶相模拟器系统,其中所述非离子表面活性剂选自1-40mol乙烯和/或环氧丙烷加成产物(a)组 每摩尔烯丙醇,和(b)每摩尔烯丙醇1至40摩尔乙烯和/或环氧丙烷的加成产物,其中所述加成产物的OH-基是在上述意义上被封端 被OR取代,其中R是具有1-20个碳原子的烷基,其可以是饱和或不饱和的,直链或支链的。

    Aqueous Surfactant Compositions With A Low Pour Point
    4.
    发明申请
    Aqueous Surfactant Compositions With A Low Pour Point 有权
    具有低倾点的水性表面活性剂组合物

    公开(公告)号:US20090289220A1

    公开(公告)日:2009-11-26

    申请号:US12469117

    申请日:2009-05-20

    IPC分类号: C09K3/00

    摘要: Surfactant compositions which comprise (i) 10 to 90% by weight of one or more compounds selected from the group (a) to (e), and (ii) 10 to 90% by weight of water, based on the composition, are disclosed, where the compounds (a) to (e) are defined as follows: (a) addition products of ethylene oxide and/or propylene oxide with allyl alcohol, (b) addition products of ethylene oxide and/or propylene oxide with allyl alcohol, terminally capped with C1-20 alkyl, (c) compounds of the formula R1—O—X—R2, where X is 1 to 40 ethylene oxide and/or propylene oxide units and where R1 and R2 independently are C1-20 alkyl, excluding allyl, (d) compounds of the formula R3—O—X—H, where X is 1 to 40 ethylene oxide and/or propylene oxide units and where R3 is C1-20 alkyl, excluding allyl, (e) compounds of the formula H—O—X—H, where X is 1 to 40 ethylene oxide and/or propylene oxide units. The surfactant compositions are liquid and pourable at 20° C., with a pour point below 0° C., and are useful as emulsifiers in emulsion polymerization.

    摘要翻译: 公开了表面活性剂组合物,其包含(i)10至90重量%的一种或多种选自组(a)至(e)的化合物和(ii)10至90重量%的水,基于组合物 其中化合物(a)至(e)定义如下:(a)环氧乙烷和/或环氧丙烷与烯丙醇的加成产物,(b)环氧乙烷和/或环氧丙烷与烯丙醇的加成产物, 末端用C 1-20烷基封端,(c)式R1-OX-R2的化合物,其中X是1至40个环氧乙烷和/或环氧丙烷单元,其中R 1和R 2独立地是C 1-20烷基,不包括烯丙基, (d)式R3-OXH的化合物,其中X为1至40个环氧乙烷和/或环氧丙烷单元,其中R3为C1-20烷基,不包括烯丙基,(e)式HOXH化合物,其中X为1 至40个环氧乙烷和/或环氧丙烷单元。 表面活性剂组合物是液体并且在20℃下倾倒,倾点低于0℃,并且可用作乳液聚合中的乳化剂。

    Use of nonionic surfactants as emulsifiers for emulsion polymerization
    5.
    发明申请
    Use of nonionic surfactants as emulsifiers for emulsion polymerization 审中-公开
    使用非离子表面活性剂作乳液聚合乳化剂

    公开(公告)号:US20090292072A1

    公开(公告)日:2009-11-26

    申请号:US12469226

    申请日:2009-05-20

    IPC分类号: C08F2/22

    摘要: Disclosed is the use of nonionic surfactants as emulsifiers for emulsion polymerization, one or more nonionic surfactants being selected from the group consisting of (a) addition products of from 1 to 40 mol of ethylene oxide and/or propylene oxide per mole onto allyl alcohol, and (b) addition products of from 1 to 40 mol of ethylene oxide and/or propylene oxide per mole onto allyl alcohol, where the OH group of these addition products is terminally capped in the sense that it is replaced by a group OR, where R is an alkyl group having 1 to 20 carbon atoms which may be saturated or unsaturated, straight-chain or branched.

    摘要翻译: 公开了使用非离子表面活性剂作为乳液聚合的乳化剂,一种或多种非离子表面活性剂选自(a)每摩尔1至40摩尔环氧乙烷和/或环氧丙烷加成产物至烯丙醇, 和(b)每摩尔1至40摩尔环氧乙烷和/或环氧丙烷加成的烯丙醇,其中这些加成产物的OH基团被末端封端,其被替换为OR,其中 R是具有1至20个碳原子的烷基,其可以是饱和或不饱和的,直链或支链的。

    Use of nonionic surfactants as emulsifiers for emulsion polymerization (III)
    7.
    发明授权
    Use of nonionic surfactants as emulsifiers for emulsion polymerization (III) 失效
    非离子表面活性剂用作乳液聚合乳化剂(III)

    公开(公告)号:US08779075B2

    公开(公告)日:2014-07-15

    申请号:US13259846

    申请日:2010-03-13

    IPC分类号: C08F2/30

    CPC分类号: C08F2/30

    摘要: The invention relates to the use of aqueous solutions of nonionic surfactants as gel phase free emulsion systems for emulsion polymerization. The nonionic surfactants are chosen from the group (a) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, and (b) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, wherein the OH-group of said addition products is end-capped in the sense that it is substituted by a group OR, wherein R is an alkyl group with 1 to 20 C-atoms, which can be saturated or unsaturated, straight chained or branched.

    摘要翻译: 本发明涉及非离子表面活性剂的水溶液用作乳液聚合的无凝胶相乳液体系。 非离子表面活性剂选自单体摩尔量为1至40mol乙烯和/或环氧丙烷/ mol烯丙醇的加成产物组(a),和(b)1-40mol乙烯和/或丙烯的加成产物 氧化物/摩尔烯丙醇,其中所述加成产物的OH基在被基团OR取代的意义上被封端,其中R是具有1至20个C原子的烷基,其可以是饱和的 或不饱和的,直链或支链的。

    Aqueous surfactant compositions with a low pour point
    8.
    发明授权
    Aqueous surfactant compositions with a low pour point 有权
    具有低倾点的水性表面活性剂组合物

    公开(公告)号:US08142681B2

    公开(公告)日:2012-03-27

    申请号:US12469117

    申请日:2009-05-20

    IPC分类号: C09K3/00 C08F2/22

    摘要: Surfactant compositions which comprise (i) 10 to 90% by weight of one or more compounds selected from the group (a) to (e), and (ii) 10 to 90% by weight of water, based on the composition, are disclosed, where the compounds (a) to (e) are defined as follows: (a) addition products of ethylene oxide and/or propylene oxide with allyl alcohol, (b) addition products of ethylene oxide and/or propylene oxide with allyl alcohol, terminally capped with C1-20 alkyl, (c) compounds of the formula R1—O—X—R2, where X is 1 to 40 ethylene oxide and/or propylene oxide units and where R1 and R2 independently are C1-20 alkyl, excluding allyl, (d) compounds of the formula R3—O—X—H, where X is 1 to 40 ethylene oxide and/or propylene oxide units and where R3 is C1-20 alkyl, excluding allyl, (e) compounds of the formula H—O—X—H, where X is 1 to 40 ethylene oxide and/or propylene oxide units. The surfactant compositions are liquid and pourable at 20° C., with a pour point below 0° C., and are useful as emulsifiers in emulsion polymerization.

    摘要翻译: 公开了表面活性剂组合物,其包含(i)10至90重量%的一种或多种选自组(a)至(e)的化合物和(ii)10至90重量%的水,基于组合物 其中化合物(a)至(e)定义如下:(a)环氧乙烷和/或环氧丙烷与烯丙醇的加成产物,(b)环氧乙烷和/或环氧丙烷与烯丙醇的加成产物, 末端用C 1-20烷基封端,(c)式R 1 -O-X-R 2化合物,其中X为1至40个环氧乙烷和/或环氧丙烷单元,并且其中R 1和R 2各自为C 1-20烷基,不包括 烯丙基,(d)式R 3 -O-X-H的化合物,其中X为1至40个环氧乙烷和/或环氧丙烷单元,其中R 3为C 1-20烷基,不包括烯丙基,(e)式 H-O-X-H,其中X为1至40个环氧乙烷和/或环氧丙烷单元。 表面活性剂组合物是液体并且在20℃下倾倒,倾点低于0℃,并且可用作乳液聚合中的乳化剂。

    Copolymerizable surfactants (1)
    9.
    发明授权
    Copolymerizable surfactants (1) 有权
    可共聚表面活性剂(1)

    公开(公告)号:US08183320B2

    公开(公告)日:2012-05-22

    申请号:US12824394

    申请日:2010-06-28

    IPC分类号: C08L31/06

    CPC分类号: C08F2/24 C08F222/20

    摘要: The invention is directed to the use of maleic esters selected from compounds of formulae (I), (II) and (III), as copolymerizable emulsifiers in the emulsion polymerization of olefinically unsaturated monomers, in which A is a C3-C40 alkyl group; X, Y and Z independently are hydrogen or methyl; B and D independently are sulfate, phosphate or hydrogen; n and p independently are numbers in the range from 0 to 40; and m is a number in the range from 2 to 40.

    摘要翻译: 本发明涉及在烯属不饱和单体的乳液聚合中使用选自式(I),(II)和(III)的化合物的马来酸酯作为可共聚的乳化剂,其中A为C 3 -C 40烷基; X,Y和Z独立地是氢或甲基; B和D独立地是硫酸根,磷酸根或氢原子; n和p独立地为0至40的数字; m为2〜40的数。

    COPOLYMERIZABLE SURFACTANTS (1)
    10.
    发明申请
    COPOLYMERIZABLE SURFACTANTS (1) 有权
    可共聚表面活性剂(1)

    公开(公告)号:US20100331486A1

    公开(公告)日:2010-12-30

    申请号:US12824394

    申请日:2010-06-28

    IPC分类号: C08L33/14

    CPC分类号: C08F2/24 C08F222/20

    摘要: The invention is directed to the use of maleic esters selected from compounds of formulae (I), (II) and (III), as copolymerizable emulsifiers in the emulsion polymerization of olefinically unsaturated monomers, in which A is a C3-C40 alkyl group; X, Y and Z independently are hydrogen or methyl; B and D independently are sulfate, phosphate or hydrogen; n and p independently are numbers in the range from 0 to 40; and m is a number in the range from 2 to 40.

    摘要翻译: 本发明涉及在烯属不饱和单体的乳液聚合中使用选自式(I),(II)和(III)的化合物的马来酸酯作为可共聚的乳化剂,其中A为C 3 -C 40烷基; X,Y和Z独立地是氢或甲基; B和D独立地是硫酸根,磷酸根或氢原子; n和p独立地为0至40的数字; m为2〜40的数。