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公开(公告)号：US4957514A
公开(公告)日：1990-09-18
申请号：US307438
申请日：1989-02-07
申请人： Timothy C. Golden , Ravi Kumar , Wilbur C. Kratz
发明人： Timothy C. Golden , Ravi Kumar , Wilbur C. Kratz
IPC分类号： C01B3/56
CPC分类号： C01B3/56 , C01B2203/043 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0495
摘要： Dilute impurities are removed from a hydrogen stream by selective adsorption in a bed of an X-type zeolite comprising barium cation.
摘要翻译： 通过选择性吸附在包含钡阳离子的X型沸石的床中，从氢气流中除去稀的杂质。
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2.发明授权Method for separation of carbon monoxide by highly dispersed cuprous compositions 失效通过高度分散的亚铜组合物分离一氧化碳的方法
公开(公告)号：US5300271A
公开(公告)日：1994-04-05
申请号：US868743
申请日：1992-04-14
CPC分类号： B01J20/06 , B01J20/0237 , B01J20/08 , B01J20/20 , B01J20/305 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J2220/58
摘要： The present invention is directed to active compositions, such as adsorbents and catalysts, which comprise cuprous compounds dispersed on amorphous oxide or carbon macroporous supports. The compositions are prepared by impregnating cupric compounds on pretreated supports with the aid of an aqueous solution of an ammonium salt of a di- or polycarboxylic acid dispersant, such as ammonium citrate, followed by activation of the cupric compound or reduction of the cupric compound to the corresponding cuprous compound. Methods of synthesis and processes utilizing the compositions are also disclosed.
摘要翻译： 本发明涉及包含分散在无定形氧化物或碳大孔载体上的亚锡化合物的活性组合物，例如吸附剂和催化剂。 通过二 - 或多元羧酸分散剂如柠檬酸铵的铵盐水溶液将铜化合物浸渍在预处理的载体上，然后活化铜化合物或将铜化合物还原成 相应的亚铜化合物。 还公开了使用组合物的合成方法和方法。
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公开(公告)号：US5258571A
公开(公告)日：1993-11-02
申请号：US945282
申请日：1992-09-14
申请人： Timothy C. Golden , Wilbur C. Kratz , Frederick C. Wilhelm , Ronald Pierantozzi , Andrzej Rokicki
发明人： Timothy C. Golden , Wilbur C. Kratz , Frederick C. Wilhelm , Ronald Pierantozzi , Andrzej Rokicki
CPC分类号： B01J20/06 , B01J20/0237 , B01J20/08 , B01J20/20 , B01J20/305 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J2220/58 , Y10S95/90
摘要： The present invention is directed to a process for adsorptive separation of carbon monoxide or olefins from gas mixtures using adsorbents, which comprise cuprous compounds dispersed on amorphous oxide or carbon macroporous supports. The compositions are prepared by impregnating cupric compounds on, preferably pretreated, supports with the aid of an aqueous solution of an ammonium salt of a di- or polycarboxylic acid dispersant, such as ammonium citrate, followed by reduction of the cupric compound to the corresponding cuprous compound. The reduction can be performed either by the use of elevated temperature or by the use of a reducing gas preferably carbon monoxide at relatively low temperatures up to 150.degree. C. Methods of synthesis are also disclosed.
摘要翻译： 本发明涉及一种使用吸附剂从气体混合物中吸附分离一氧化碳或烯烃的方法，该方法包括分散在无定形氧化物或碳大孔载体上的亚铜化合物。 通过在二羧酸分散剂或多元羧酸分散剂如柠檬酸铵的铵盐的水溶液的帮助下，在优选预处理的载体上浸渍铜化合物，然后将铜化合物还原为相应的亚铜 复合。 还原反应可以通过使用升高的温度或在150℃以下的较低的温度下使用还原性气体，优选一氧化碳来进行。还公开了合成方法。
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公开(公告)号：US5126310A
公开(公告)日：1992-06-30
申请号：US572067
申请日：1990-08-23
CPC分类号： B01J20/06 , B01J20/0237 , B01J20/08 , B01J20/20 , B01J20/305 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J2220/58
摘要： The present invention is directed to active compositions, such as adsorbents and catalysts, which comprise cuprous compounds dispersed on amorphous oxide or carbon macroporous supports. The compositions are prepared by impregnating cupric compounds on pretreated supports with the aid of an aqueous solution of an ammonium salt of a di- or polycarboxylic acid dispersant, such as ammonium citrate, followed by activation of the cupric compound or reduction of the cupric compound to the corresponding cuprous compound. Methods of synthesis and processes utilizing the compositions are also disclosed.
摘要翻译： 本发明涉及包含分散在无定形氧化物或碳大孔载体上的亚锡化合物的活性组合物，例如吸附剂和催化剂。 通过二 - 或多元羧酸分散剂如柠檬酸铵的铵盐水溶液将铜化合物浸渍在预处理的载体上，然后活化铜化合物或将铜化合物还原成 相应的亚铜化合物。 还公开了使用组合物的合成方法和方法。
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公开(公告)号：US5447557A
公开(公告)日：1995-09-05
申请号：US216739
申请日：1994-03-23
IPC分类号： B01D53/02 , B01D53/047 , B01J20/20 , B01D53/04
CPC分类号： B01D53/02 , B01D53/047 , B01J20/20 , B01D2253/102 , B01D2256/10 , B01D2257/104 , B01D2259/40066 , B01D2259/40071 , B01D2259/402 , Y10S95/903
摘要： An oxygen selective adsorbent and a method for making an oxygen selective adsorbent wherein a porous carbon substrate such as a carbon molecular sieve, activated carbon, carbon black, coal, or petroleum coke, is impregnated with a solution of an acidic species and the impregnated substrate is dried. The oxygen selective adsorbent can be used in a pressure swing adsorption process for the separation of oxygen from nitrogen, for example, in air.
摘要翻译： 氧选择性吸附剂和制备氧选择性吸附剂的方法，其中多孔碳基质如碳分子筛，活性炭，炭黑，煤或石油焦炭用酸性物质和浸渍基质的溶液浸渍 被干燥。 氧选择性吸附剂可用于例如在空气中从氮气中分离氧的变压吸附方法。
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公开(公告)号：US5175137A
公开(公告)日：1992-12-29
申请号：US744181
申请日：1991-08-08
申请人： Timothy C. Golden , Wilbur C. Kratz , Frederick C. Wilhelm , Ronald Pierantozzi , Andrzej Rokicki
发明人： Timothy C. Golden , Wilbur C. Kratz , Frederick C. Wilhelm , Ronald Pierantozzi , Andrzej Rokicki
CPC分类号： B01J20/06 , B01J20/0237 , B01J20/08 , B01J20/20 , B01J20/305 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J2220/58
摘要： The present invention is directed to a process for adsorptive separation of carbon monoxide or olefins from gas mixtures using adsorbents, which comprise cuprous compounds dispersed on amorphous oxide or carbon macroporous supports. The compositions are prepared by impregnating cupric compounds on, preferably pretreated, supports with the aid of an aqueous solution of an ammonium salt of a di- or polycarboxylic acid dispersant, such as ammonium citrate, followed by reduction of the cupric compound to the corresponding cuprous compound. The reduction can be performed either by the use of elevated temperature or by the use of a reducing gas preferably carbon monoxide at relatively low temperatures up to 150.degree. C. Methods of synthesis are also disclosed.
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公开(公告)号：US5104425A
公开(公告)日：1992-04-14
申请号：US724063
申请日：1991-07-01
CPC分类号： B01D67/0088 , B01D53/22 , B01D53/228 , B01D67/0072 , B01D69/02 , B01D69/10 , B01D69/12 , B01D69/141 , B01D71/02 , B01D71/021 , B01D71/028 , C10G70/045 , B01D2325/04 , Y10S55/05
摘要： Composite semipermeable membranes comprising porous adsorptive material supported by a porous substrate are disclosed for use in a process for the separation of multicomponent gas mixtures. In the process, one or more primary components adsorb within the pores of the adsorptive material and diffuse by surface flow through the membrane to yield a permeate stream enriched in one or more of the primary components. Methods for making the composite membranes are described.
摘要翻译： 公开了用于分离多组分气体混合物的方法的包含由多孔基材支撑的多孔吸附材料的复合半透膜。 在该过程中，一个或多个主要组分吸附在吸附材料的孔内并通过表面流扩散通过膜以产生富含一种或多种主要组分的渗透物流。 描述制备复合膜的方法。
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公开(公告)号：US4702749A
公开(公告)日：1987-10-27
申请号：US877827
申请日：1986-06-24
申请人： Shivaji Sircar , Timothy C. Golden
发明人： Shivaji Sircar , Timothy C. Golden
CPC分类号： C01B31/083 , C01B31/12 , Y10S95/901
摘要： A mild oxidizing acid wash of activated carbon in the presence of an oxidation catalyst produces an adsorbent, with a large carboxyl IR spectra peak, having a favorable water adsorption isotherm that can be used for both pressure swing adsorption, PSA, or thermal swing adsorption, TSA, drying of gases. The oxidation catalyst is a metal salt wherein the metal is selected from the group consisting of copper, chromium and nickel.
摘要翻译： 在氧化催化剂存在下，活性炭的温和氧化酸洗涤产生具有大的羧基红外光谱峰的吸附剂，具有可用于变压吸附，PSA或热变形吸附两者的有利的吸水等温线， TSA，气体干燥。 氧化催化剂是金属盐，其中金属选自铜，铬和镍。
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公开(公告)号：US5536302A
公开(公告)日：1996-07-16
申请号：US475111
申请日：1995-06-07
CPC分类号： B01D53/02 , B01D53/46 , B01J20/041 , B01J20/06 , B01J20/20 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J20/3416 , B01J20/3458 , B01J20/3483 , B01D2253/102 , B01D2253/112 , B01D2256/18 , B01D2257/104 , B01D2259/40088 , Y10S95/901
摘要： An adsorbent and a process for its use in removing trace oxygen from an inert gas. The adsorbent comprises a porous reducing support such as activated carbon, carbon black, coal, petroleum coke and titania which is impregnated with about 10% to about 90% by weight of an alkali metal oxide or an alkaline earth metal oxide.
摘要翻译： 吸附剂及其用于从惰性气体中除去痕量氧的方法。 吸附剂包括多孔还原载体，例如活性炭，炭黑，煤，石油焦炭和二氧化钛，其以约10重量％至约90重量％的碱金属氧化物或碱土金属氧化物浸渍。
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10.发明授权Method of separating and detecting impurities using a fractional concentration detector 失效使用分数浓度检测器分离和检测杂质的方法
公开(公告)号：US5360467A
公开(公告)日：1994-11-01
申请号：US101604
申请日：1993-08-03
CPC分类号： G01N33/0014 , G01N30/00 , G01N30/14 , G01N2030/025 , G01N2030/062 , G01N2030/143 , G01N2030/146
摘要： A method for detection of impurities at very low levels in hydrogen, oxygen or specialty gases comprises the metered mixture with high purity helium and subsequent selective separation of hydrogen, oxygen or specialty gas with the detection of impurities remaining in the helium by ionization spectrometry.
摘要翻译： 在氢气，氧气或特殊气体中检测非常低水平的杂质的方法包括具有高纯度氦的计量混合物，随后通过电离光谱法检测氦气中残留的杂质，选择性分离氢气，氧气或特殊气体。
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