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1.发明授权Phosphate-containing catalyst composition for the preparation of polyesters, and related processes 有权用于制备聚酯的含磷酸酯催化剂组合物及相关方法
公开(公告)号：US6043335A
公开(公告)日：2000-03-28
申请号：US411275
申请日：1999-10-04
申请人： Timothy Edward Banach , Maurizio Fiorini , Bimal Ramesh Patel , Francesco Pilati , Corrado Berti , Elisabetta Marianucci , Massimo Messori , Martino Colonna , Maurizio Toselli
发明人： Timothy Edward Banach , Maurizio Fiorini , Bimal Ramesh Patel , Francesco Pilati , Corrado Berti , Elisabetta Marianucci , Massimo Messori , Martino Colonna , Maurizio Toselli
IPC分类号： B01J27/18 , B01J31/02 , B01J31/18 , B01J31/22 , B01J31/38 , C08G63/85 , C08G63/87 , C08G63/78 , B01J31/00 , C08K3/02
CPC分类号： C08G63/85 , B01J27/1806 , B01J31/0212 , B01J2231/40 , B01J2531/46 , B01J2531/48 , B01J31/1845 , B01J31/2208 , C08G63/87
摘要： Polyesters are prepared by the reaction of a dicarboxylic acid, preferably an aromatic acid such as terephthalic acid, or an ester or ester-forming derivative thereof with a dihydroxy compound such as 1,4-butanediol in the presence of a catalyst composition comprising the combination of a titanium-based compound such as tetra-n-butyl titanate, a zirconium-based compound such as zirconium tetrakis(2,4-pentanedionate) and a phosphate-forming compound such as sodium dihydrogen phosphate. This catalyst composition affords polyesters having relatively low melt viscosities in short reaction times and does not produce an excessive level of undesirable reaction by-products.
摘要翻译： 聚酯通过二羧酸，优选芳族酸如对苯二甲酸或其酯或酯形成衍生物与二羟基化合物如1,4-丁二醇在包含组合的催化剂组合物的存在下反应制备 的钛基化合物如四正丁基钛酸酯，锆基化合物如四（2,4-戊二酮）锆和磷酸盐形成化合物如磷酸二氢钠。 该催化剂组合物在短的反应时间内提供具有相对低的熔体粘度的聚酯，并且不会产生过量的不期望的反应副产物。
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2.发明授权
公开(公告)号：US5902873A
公开(公告)日：1999-05-11
申请号：US953455
申请日：1997-10-17
申请人： Timothy Edward Banach , Francesco Pilati , Martino Colonna , Maurizio Fiorini , Corrado Berti , Maurizio Toselli , Massimo Messori , Elisabetta Marianucci
发明人： Timothy Edward Banach , Francesco Pilati , Martino Colonna , Maurizio Fiorini , Corrado Berti , Maurizio Toselli , Massimo Messori , Elisabetta Marianucci
摘要： A catalyst composition for use in the preparation of a polyester or copolyester is disclosed. The catalyst composition comprises the combination of (a) a titanium-based compound or zirconium-based compound, and (b) a lanthanide series compound or hafnium. Various titanium-based compounds and lanthanide-based compounds are described. Moreover, in some embodiments, the catalyst composition may further comprise a phosphate-forming compound. Another aspect of this invention is an improved method for preparing a polyester, based, for example, on the two-stage process of ester interchange and polycondensation. The method is carried out in the presence of the catalyst composition described above.
摘要翻译： 公开了一种用于制备聚酯或共聚酯的催化剂组合物。 催化剂组合物包含（a）钛基化合物或锆基化合物和（b）镧系化合物或铪的组合。 描述了各种钛基化合物和镧系元素类化合物。 此外，在一些实施方案中，催化剂组合物还可以包含形成磷酸盐的化合物。 本发明的另一方面是改进的制备聚酯的方法，其基于例如酯交换和缩聚的两步方法。 该方法在上述催化剂组合物存在下进行。
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3.发明授权Method for preparing poly(cyclohexane-1,4-dicarboxylate)s from cyclohexane-1,4-dicarboxylic acid, and composition 有权由环己烷-1,4-二羧酸制备聚（环己烷-1,4-二羧酸酯）的方法及其组合物公开(公告)号：US06828410B2
公开(公告)日：2004-12-07
申请号：US10192579
申请日：2002-07-10
申请人： Daniel Joseph Brunelle , Corrado Berti , Annamaria Celli , Martino Colonna , Maurizio Fiorini , Elisabetta Marianucci , Massimo Messori , Francesco Pilati , Laura Sisti , Paola Marchese
发明人： Daniel Joseph Brunelle , Corrado Berti , Annamaria Celli , Martino Colonna , Maurizio Fiorini , Elisabetta Marianucci , Massimo Messori , Francesco Pilati , Laura Sisti , Paola Marchese
IPC分类号： C08G6300
CPC分类号： C08G63/199 , C08G63/78 , C08G63/82
摘要： Poly(1,4-cyclohexanedicarboxylate)s, especially poly(1,4-cyclohexanedimethylene-1,4-cyclohexanedicarboxylate), are prepared from at least one relatively non-volatile diol, such as 1,4-cyclohexanedimethanol, and cyclohexane-1,4-dicarboxylic acid by an esterification process in the presence of a catalyst, at a maximum temperature of about 260°. In one embodiment the procedure employs a two-step process, the second of which may be performed in the melt or in the solid state. A volatile diol such as ethylene glycol may also be present.
摘要翻译： 聚（1,4-环己烷二羧酸酯），特别是聚（1,4-环己烷二亚甲基-1,4-环己烷二羧酸酯），由至少一种相对不挥发的二醇如1,4-环己烷二甲醇和环己烷-1 在催化剂存在下，通过酯化方法，在约260℃的最高温度下进行。 在一个实施方案中，该方法采用两步法，其中第二步可以在熔体中或在固态下进行。 也可以存在挥发性二醇如乙二醇。
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4.发明申请Novel synthetic route for the preparation of hydroxy terminated polyarylates 审中-公开用于制备羟基封端的聚芳酯的新型合成路线公开(公告)号：US20050075456A1
公开(公告)日：2005-04-07
申请号：US10676199
申请日：2003-10-01
申请人： Daniel Brunelle , Joseph Suriano , Corrado Berti , Annamaria Celli , Martino Colonna , Maurizio Fiorini , Elisabetta Marianucci , Paola Marchese , Massimo Messori , Laura Sisti
发明人： Daniel Brunelle , Joseph Suriano , Corrado Berti , Annamaria Celli , Martino Colonna , Maurizio Fiorini , Elisabetta Marianucci , Paola Marchese , Massimo Messori , Laura Sisti
摘要： Efficient and cost-effective methods for producing hydroxyl-terminated arylates are disclosed. These arylates are useful in forming block polyarylate-polycarbonate copolymers.
摘要翻译： 公开了用于生产羟基封端的芳基化物的有效和成本有效的方法。 这些芳基化物可用于形成嵌段聚芳酯 - 聚碳酸酯共聚物。
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公开(公告)号：US08975360B2
公开(公告)日：2015-03-10
申请号：US13941709
申请日：2013-07-15
CPC分类号： C08K9/04 , B82Y30/00 , C08J5/005 , C08J2369/00 , C08K3/346 , Y10T428/139 , C08L69/00
摘要： Nanocomposites comprising a sulfonated telechelic polycarbonate and an organically modified clay are disclosed. The polycarbonate nanocomposites have improved physical and mechanical properties.
摘要翻译： 公开了包含磺化遥爪聚碳酸酯和有机改性粘土的纳米复合材料。 聚碳酸酯纳米复合材料具有改善的物理和机械性能。
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公开(公告)号：US08487066B2
公开(公告)日：2013-07-16
申请号：US13351102
申请日：2012-01-16
CPC分类号： C08K9/04 , B82Y30/00 , C08J5/005 , C08J2369/00 , C08K3/346 , Y10T428/139 , C08L69/00
摘要： Nanocomposites comprising a sulfonated telechelic polycarbonate and an organically modified clay are disclosed. The polycarbonate nanocomposites have improved physical and mechanical properties.
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公开(公告)号：US20120238665A1
公开(公告)日：2012-09-20
申请号：US13351102
申请日：2012-01-16
CPC分类号： C08K9/04 , B82Y30/00 , C08J5/005 , C08J2369/00 , C08K3/346 , Y10T428/139 , C08L69/00
摘要： Nanocomposites comprising a sulfonated telechelic polycarbonate and an organically modified clay are disclosed. The polycarbonate nanocomposites have improved physical and mechanical properties.
摘要翻译： 公开了包含磺化遥爪聚碳酸酯和有机改性粘土的纳米复合材料。 聚碳酸酯纳米复合材料具有改善的物理和机械性能。
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8.发明授权公开(公告)号：US07557174B2
公开(公告)日：2009-07-07
申请号：US11528206
申请日：2006-09-27
CPC分类号： C08G63/85 , C08G63/191 , C08G63/64
摘要： The present invention provides carboxy-terminated oligomeric polyester compositions useful in the preparation of “weatherable” polymeric materials, for example weatherable copolyestercarbonates. In one aspect the present invention provides an oligomeric polyester composition comprising structural units derived from at least one diacid, at least one diaryl carbonate and at least one diol. The structural units derived from the diacid are present in a molar excess of from about 10% to about 40% based on a ratio of moles of diacid-derived structural units to moles of diol-derived structural units present in the oligomeric polyester composition. The oligomeric polyester composition is further characterized by the presence of at least some phenoxy end groups.
摘要翻译： 本发明提供了可用于制备“耐候性”聚合物材料的羧基封端的低聚聚酯组合物，例如耐候性共聚酯碳酸酯。 在一个方面，本发明提供了包含衍生自至少一种二酸，至少一种碳酸二芳酯和至少一种二醇的结构单元的低聚聚酯组合物。 基于二酸衍生的结构单元的摩尔数与存在于低聚聚酯组合物中的二醇衍生的结构单元的摩尔数的比例，衍生自二酸的结构单元的摩尔过量为约10％至约40％。 低聚聚酯组合物的特征还在于存在至少一些苯氧基端基。
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公开(公告)号：US20090043071A1
公开(公告)日：2009-02-12
申请号：US11834417
申请日：2007-08-06
CPC分类号： C08G64/14 , C08G64/081 , C08G64/307
摘要： A sulfonated telechelic polycarbonate is described which is produced by melt synthesis. A dihydroxy compound is reacted with a sulfobenzoic acid salt, then with an activated carbonate. The method results in a sulfonated telechelic polycarbonate which has a high percentage of sulfonated end groups, is soluble, and is transparent.
摘要翻译： 描述了通过熔融合成制备的磺化遥爪聚碳酸酯。 二羟基化合物与磺基苯甲酸盐反应，然后与活性碳酸酯反应。 该方法产生具有高百分比的磺化端基的磺化遥爪聚碳酸酯，是可溶的并且是透明的。
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公开(公告)号：US07687595B2
公开(公告)日：2010-03-30
申请号：US11834417
申请日：2007-08-06
CPC分类号： C08G64/14 , C08G64/081 , C08G64/307
摘要： A sulfonated telechelic polycarbonate is described which is produced by melt synthesis. A dihydroxy compound is reacted with a sulfobenzoic acid salt, then with an activated carbonate. The method results in a sulfonated telechelic polycarbonate which has a high percentage of sulfonated end groups, is soluble, and is transparent.
摘要翻译： 描述了通过熔融合成制备的磺化遥爪聚碳酸酯。 二羟基化合物与磺基苯甲酸盐反应，然后与活性碳酸酯反应。 该方法产生磺化的遥爪聚碳酸酯，其具有高百分比的磺化端基，是可溶的并且是透明的。
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