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    DIAMOND BASED ELECTROCHEMICAL SENSORS
    1.
    发明申请
    DIAMOND BASED ELECTROCHEMICAL SENSORS 审中-公开
    基于钻石的电化学传感器

    公开(公告)号：US20130327640A1

    公开(公告)日：2013-12-12

    申请号：US14001451

    申请日：2012-03-15

    申请人： Timothy Peter Mollart ,  Geoffrey Alan Scarsbrook ,  Mark Edward Newton ,  Julie Victoria MacPherson ,  Patrick Robert Unwin

    发明人： Timothy Peter Mollart ,  Geoffrey Alan Scarsbrook ,  Mark Edward Newton ,  Julie Victoria MacPherson ,  Patrick Robert Unwin

    IPC分类号： G01N27/30

    CPC分类号： G01N27/308 ,  G01N33/0044

    摘要： A diamond based electrochemical band sensor comprising: a diamond body; and a plurality of boron doped diamond band electrodes disposed within the diamond body, wherein at least a portion of each of the plurality of boron doped diamond band electrodes is doped with boron to a level suitable to achieve metallic conduction, the boron doped diamond electrodes being spaced apart by non-conductive intrinsic layers of diamond, wherein the diamond body comprises a front sensing surface with the plurality of boron doped diamond band electrodes being exposed at said sensing surface and extending in an elongate manner across said surface, and wherein each boron doped diamond electrode has a length/width ratio of at least 10 at the front sensing surface.

    摘要翻译： 一种基于金刚石的电化学带传感器，包括：金刚石体; 以及布置在所述金刚石体内的多个掺杂硼的金刚石电极，其中所述多个硼掺杂金刚石电极中的每一个的至少一部分掺杂有硼至适于实现金属导电的水平，所述掺杂硼的金刚石电极为 由金刚石的非导电本征层隔开，其中金刚石主体包括前感测表面，其中多个硼掺杂金刚石电极在所述感测表面处露出并且以细长方式延伸穿过所述表面，并且其中每个硼掺杂 金刚石电极在前感测表面处的长/宽比至少为10。

    Electrochemical sensor with diamond electrodes
    2.
    发明授权
    Electrochemical sensor with diamond electrodes 有权
    带金刚石电极的电化学传感器

    公开(公告)号：US09036149B2

    公开(公告)日：2015-05-19

    申请号：US14115067

    申请日：2012-05-02

    申请人： Mark Edward Newton ,  Julie Victoria MacPherson ,  Laura Anne Hutton ,  Timothy Peter Mollart ,  Geoffrey Alan Scarsbrook

    发明人： Mark Edward Newton ,  Julie Victoria MacPherson ,  Laura Anne Hutton ,  Timothy Peter Mollart ,  Geoffrey Alan Scarsbrook

    IPC分类号： G01N21/75 ,  G01N27/416 ,  G01N27/48 ,  G01N27/30

    CPC分类号： G01N27/4163 ,  G01N21/75 ,  G01N27/308 ,  G01N27/48

    摘要： An electrochemical sensor comprising: a reference electrode (4) formed of an electrically conductive synthetic doped diamond material and configured to be located in electrical contact with a solution (8) to be analysed; a sensing electrode (2) formed of an electrically conductive synthetic doped diamond material and configured to be located in contact with the solution (8) to be analysed; an electrical controller (10) configured to conduct stripping voltammetric measurements by applying a voltage to the sensing electrode (2), to change the applied voltage relative to the reference electrode (4), and to measure an electric current flowing through the sensing electrode (2) thereby generating voltammetry data; and a calibration system configured to provide an in-situ calibration for providing a reference point in the voltammetric data since the potential of the diamond reference electrode is non fixed and floating. Consequently, assigning of peaks (M1, M2, M3) in the voltammetry data to chemical species (M1, M2, M3) is possible, thereby allowing the type and concentration of chemical species in the solution (8) to be determined. The in-situ calibration consists of: 1-using a spectrometer for X-rays, Gamma rays or fluorescence measurements integrated in the sensor, 2-using a known redox couple added to the solution that will provide a reference peak in the voltammetric data, or 3-producing in-situ ionic species at the vicinity of the reference electrode.

    摘要翻译： 一种电化学传感器，包括：由导电合成掺杂金刚石材料形成并被配置为与要分析的溶液（8）电接触的参考电极（4）; 感测电极（2），由导电合成掺杂的金刚石材料形成，并被配置为与要分析的溶液（8）接触; 电气控制器（10），被配置为通过向感测电极（2）施加电压来进行溶出伏安测量，以改变施加的电压相对于参考电极（4），并测量流过感测电极的电流（ 2）由此产生伏安数据; 以及校准系统，其被配置为提供用于在伏安数据中提供参考点的原位校准，因为金刚石参考电极的电位不固定和浮动。 因此，将伏安数据中的峰（M1，M2，M3）分配到化学物质（M1，M2，M3）是可能的，从而允许确定溶液（8）中化学物质的类型和浓度。 原位校准包括：1 - 使用光谱仪进行X射线，伽马射线或集成在传感器中的荧光测量，2 - 使用添加到溶液中的已知氧化还原对，其将提供伏安数据中的参考峰， 或在参考电极附近的3-产生的原位离子物质。

    ELECTROCHEMICAL DEPOSITION AND SPECTROSCOPIC ANALYSIS METHODS AND APPARATUS USING DIAMOND ELECTRODES
    3.
    发明申请
    ELECTROCHEMICAL DEPOSITION AND SPECTROSCOPIC ANALYSIS METHODS AND APPARATUS USING DIAMOND ELECTRODES 有权
    电化学沉积和光谱分析方法和使用金刚石电极的设备

    公开(公告)号：US20140069815A1

    公开(公告)日：2014-03-13

    申请号：US14115055

    申请日：2012-05-11

    申请人： Mark Edward Newton ,  Julie Victoria MacPherson ,  Patrick Robert Unwin ,  Timothy Peter Mollart

    发明人： Mark Edward Newton ,  Julie Victoria MacPherson ,  Patrick Robert Unwin ,  Timothy Peter Mollart

    IPC分类号： G01N21/75 ,  G01N27/30

    CPC分类号： G01N21/75 ,  C25D21/12 ,  G01N23/223 ,  G01N27/308 ,  G01N27/48 ,  G01N2223/076

    摘要： A method of analysing chemical species in a solution, the method comprising: providing an electrochemical deposition apparatus comprising a first electrode (2) formed of an electrically conductive diamond material and a second electrode (4); locating the first electrode in contact with a solution (8) to be analysed and the second electrode in electrical contact with the solution to be analysed; applying a potential difference between the first and second electrodes (2, 4) such that current flows between the first and second electrodes through the solution to be analysed and chemical species are electro-deposited from the solution onto the first electrode; applying a spectroscopic analysis technique to the electro-deposited chemical species (M1, M2, M3) on the first electrode to generate spectroscopic data about the electro-deposited chemical species on the first electrode; and using the spectroscopic data to determine the type of chemical species electro-deposited on the first electrode. The spectroscopic analysis technique, which can be based on X-rays, fluorescent X-rays or gamma rays, is used in combination with stripping voltammetric measurement performed on the first electrode. The spectroscopic data can also be used in-situ calibration data for calibrating the reference potential used voltammetric measurements.

    摘要翻译： 一种分析溶液中化学物质的方法，所述方法包括：提供包括由导电金刚石材料形成的第一电极（2）和第二电极（4）的电化学沉积设备; 将所述第一电极定位成与待分析的溶液（8）接触并且所述第二电极与待分析的溶液电接触; 在第一和第二电极（2,4）之间施加电位差，使得电流通过待分析的溶液在第一和第二电极之间流动，化学物质从溶液中电沉积到第一电极上; 对所述第一电极上的电沉积化学物质（M1，M2，M3）施加光谱分析技术以产生关于所述第一电极上的电沉积化学物质的光谱数据; 并且使用光谱数据来确定电沉积在第一电极上的化学物质的类型。 可以基于X射线，荧光X射线或γ射线的光谱分析技术与在第一电极上进行的溶出伏安测量结合使用。 光谱数据也可以用于原位校准数据，用于校准参考电位的伏安测量。

    Electrochemical deposition and spectroscopic analysis methods and apparatus using diamond electrodes
    4.
    发明授权
    Electrochemical deposition and spectroscopic analysis methods and apparatus using diamond electrodes 有权
    使用金刚石电极的电化学沉积和光谱分析方法和设备

    公开(公告)号：US09036148B2

    公开(公告)日：2015-05-19

    申请号：US14115055

    申请日：2012-05-11

    申请人： Mark Edward Newton ,  Julie Victoria MacPherson ,  Patrick Robert Unwin ,  Timothy Peter Mollart

    发明人： Mark Edward Newton ,  Julie Victoria MacPherson ,  Patrick Robert Unwin ,  Timothy Peter Mollart

    IPC分类号： G01N21/75 ,  G01N23/223 ,  G01N27/48 ,  G01N27/30 ,  C25D21/12

    CPC分类号： G01N21/75 ,  C25D21/12 ,  G01N23/223 ,  G01N27/308 ,  G01N27/48 ,  G01N2223/076

    摘要： A method of analyzing chemical species in a solution, the method comprising: providing an electrochemical deposition apparatus comprising a first electrode (2) formed of an electrically conductive diamond material and a second electrode (4); locating the first electrode in contact with a solution (8) to be analyzed and the second electrode in electrical contact with the solution to be analyzed; applying a potential difference between the first and second electrodes (2, 4) such that current flows between the first and second electrodes through the solution to be analyzed and chemical species are electro-deposited from the solution onto the first electrode; applying a spectroscopic analysis technique to the electro-deposited chemical species (M1, M2, M3) on the first electrode to generate spectroscopic data about the electro-deposited chemical species on the first electrode; and using the spectroscopic data to determine the type of chemical species electro-deposited on the first electrode. The spectroscopic analysis technique, which can be based on X-rays, fluorescent X-rays or gamma rays, is used in combination with stripping voltammetric measurement performed on the first electrode. The spectroscopic data can also be used in-situ calibration data for calibrating the reference potential used voltammetric measurements.

    摘要翻译： 一种分析溶液中化学物质的方法，所述方法包括：提供包括由导电金刚石材料形成的第一电极（2）和第二电极（4）的电化学沉积设备; 将所述第一电极定位成与待分析的溶液（8）接触并且所述第二电极与待分析的溶液电接触; 在第一和第二电极（2,4）之间施加电位差，使得电流通过待分析的溶液在第一和第二电极之间流动，化学物质从溶液中电沉积到第一电极上; 对所述第一电极上的电沉积化学物质（M1，M2，M3）进行光谱分析技术以产生关于所述第一电极上的电沉积化学物质的光谱数据; 并且使用光谱数据来确定电沉积在第一电极上的化学物质的类型。 可以基于X射线，荧光X射线或γ射线的光谱分析技术与在第一电极上进行的溶出伏安测量结合使用。 光谱数据也可以用于原位校准数据，用于校准参考电位的伏安测量。