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公开(公告)号：US20080154060A1
公开(公告)日：2008-06-26
申请号：US11659370
申请日：2005-08-05
IPC分类号： C07C59/42
摘要： Processes for producing a hydroxyalkyl(meth)acrylate which comprise reacting (meth)acrylic acid with an alkylene oxide in the presence of a catalyst. A first process is characterized in that the amount of the acid ingredient is kept, on calculation, at 0.010 or more in terms of molar ratio to the catalyst present in the liquid reaction mixture and that the liquid reaction mixture from which the hydroxyalkyl(meth)acrylate has been distilled off is used in the subsequent reaction. A second process is characterized in that a dialkylene glycol mono(meth)acylate is supplied to the reaction system to cause the dialkyleneglycol mono(meth)acylate to coexist in the liquid reaction mixture.
摘要翻译： 制备（甲基）丙烯酸羟烷基酯的方法，其包括在催化剂存在下使（甲基）丙烯酸与烯化氧反应。 第一种方法的特征在于，根据计算，按照与液体反应混合物中存在的催化剂的摩尔比计算酸成分的量为0.010以上，并且其中（甲基）丙烯酸羟烷基酯的液体反应混合物， 蒸馏出的丙烯酸酯用于随后的反应。 第二种方法的特征在于向反应体系中加入单（甲基）丙烯酸二亚烷基二醇酯，以使液体反应混合物中的二烷基二醇单（甲基）酰化物共存。
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公开(公告)号：US06984751B2
公开(公告)日：2006-01-10
申请号：US10633139
申请日：2003-08-01
IPC分类号： C07C67/26
摘要： There is disclosed a novel production process for a hydroxyalkyl (meth)acrylate in which: the diffusion of harmful substances due to disposal of catalysts can be reduced; and also the amount of the catalyst as used can be greatly saved in the entire production process. This production process comprises the step of carrying out a reaction between (meth)acrylic acid and an alkylene oxide in the presence of a catalyst in order to produce the hydroxyalkyl (meth)acrylate; with the production process being characterized by further comprising the step of recovering the catalyst as has been used for the reaction.
摘要翻译： 公开了一种新型的（甲基）丙烯酸羟烷基酯的制备方法，其中可以减少由于处理催化剂而引起的有害物质的扩散; 并且在整个生产过程中可以极大地节省所使用的催化剂的量。 该制造方法包括在催化剂的存在下进行（甲基）丙烯酸与烯化氧的反应以制备（甲基）丙烯酸羟烷基酯的步骤; 其制备方法的特征在于还包括如已经用于反应的回收催化剂的步骤。
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公开(公告)号：US08203018B2
公开(公告)日：2012-06-19
申请号：US11659370
申请日：2005-08-05
摘要： Processes for producing a hydroxyalkyl(meth)acrylate which comprise reacting (meth)acrylic acid with an alkylene oxide in the presence of a catalyst. A first process is characterized in that the amount of the acid ingredient is kept, on calculation, at 0.010 or more in terms of molar ratio to the catalyst present in the liquid reaction mixture and that the liquid reaction mixture from which the hydroxyalkyl(meth)acrylate has been distilled off is used in the subsequent reaction. A second process is characterized in that a dialkylene glycol mono(meth)acylate is supplied to the reaction system to cause the dialkyleneglycol mono(meth)acylate to coexist in the liquid reaction mixture.
摘要翻译： 制备（甲基）丙烯酸羟烷基酯的方法，其包括在催化剂存在下使（甲基）丙烯酸与烯化氧反应。 第一种方法的特征在于，根据计算，按照与液体反应混合物中存在的催化剂的摩尔比计算酸成分的量为0.010以上，并且其中（甲基）丙烯酸羟烷基酯的液体反应混合物， 蒸馏出的丙烯酸酯用于随后的反应。 第二种方法的特征在于向反应体系中加入单（甲基）丙烯酸二亚烷基二醇酯，以使液体反应混合物中的二烷基二醇单（甲基）酰化物共存。
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公开(公告)号：US07214817B2
公开(公告)日：2007-05-08
申请号：US10436662
申请日：2003-05-13
摘要： The present invention provides: a high-quality hydroxyalkyl (meth)acrylate of which the alkylene glycol di(meth)acrylate content and the acid component content are both low; and its novel production process. The hydroxyalkyl (meth)acrylate, which has a content, in terms of an alkylene glycol di(meth)acrylate as an impurity, of not more than 0.1 weight % and an acid component content of not more than 0.1 weight %, is obtained by a process comprising the step of carrying out a batch reaction between (meth)acrylic acid and an alkylene oxide in the presence of a catalyst in order to produce the hydroxyalkyl (meth)acrylate; with the process making an adjustment as to charging of both raw materials in such a manner that, for, of a time as needed for supplying both raw materials, a supplying time of not less than 40% of a total supplying time when the raw materials as supplied have a temperature of not lower than 40° C., the molar ratio of the integrated amount of the alkylene oxide to the integrated amount of the (meth)acrylic acid that have been added to a reactor by then can be more than 1.0.
摘要翻译： 本发明提供：其中亚烷基二醇二（甲基）丙烯酸酯含量和酸成分含量均低的（甲基）丙烯酸羟烷基酯; 及其新颖的生产工艺。 通过以0.1重量％以下的亚烷基二醇二（甲基）丙烯酸酯作为杂质含量，酸成分含量为0.1重量％以下的（甲基）丙烯酸羟烷基酯，可以通过 一种方法，包括在催化剂存在下进行（甲基）丙烯酸和烯化氧之间的间歇反应以制备（甲基）丙烯酸羟烷基酯的步骤; 该方法对两种原材料的充电进行调整，使得在供应两种原料的时间内，当原料的供应时间不少于总供应时间的40％时， 如所供应的温度不低于40℃，那么环氧烷的一体化量与当时加入到反应器中的（甲基）丙烯酸的一体化量的摩尔比可以大于1.0 。
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公开(公告)号：US07045651B2
公开(公告)日：2006-05-16
申请号：US10435992
申请日：2003-05-12
申请人： Tokumasa Ishida , Masahiro Uemura
发明人： Tokumasa Ishida , Masahiro Uemura
IPC分类号： C07C67/26
摘要： The present invention provides a novel production process for a hydroxyalkyl (meth)acrylate, in which it is possible that: in a batch reaction system, the amount of the hydroxyalkyl (meth)acrylate (which is the objective product) as produced is kept nearly on the same level as conventional and further, at the same time, there is suppressed the side production of the alkylene oxide's diaddition product (dialkylene glycol mono(meth)acrylate) that lowers the purity of the product to thus give a bad influence upon its quality. The present invention production process comprises the step of carrying out a batch reaction between (meth)acrylic acid and an alkylene oxide in the presence of a catalyst in order to produce the hydroxyalkyl (meth)acrylate; with the production process being characterized by arranging that the reaction should be initiated in a state of a catalyst concentration of more than 1, wherein the catalyst concentration is defined as the amount of the catalyst as used relative to the integrated amount of the (meth)acrylic acid as supplied and is assumed to be 1 in terms of the amount of the entire catalyst to be used relative to the amount of the entire (meth)acrylic acid to be supplied.
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公开(公告)号：US06465681B2
公开(公告)日：2002-10-15
申请号：US10021061
申请日：2001-12-19
申请人： Masahiro Uemura , Tokumasa Ishida , Yukihiro Yoneda , Tetsuya Kajihara , Yasuhiro Shingai , Tadayoshi Kawashima
发明人： Masahiro Uemura , Tokumasa Ishida , Yukihiro Yoneda , Tetsuya Kajihara , Yasuhiro Shingai , Tadayoshi Kawashima
IPC分类号： C07C6726
摘要： The present invention provides: a production process for a hydroxyalkyl(meth)acrylate, which can raise productivity together with avoiding danger of explosion, and further can suppress side-formation of impurities such as a diester or a monoester wherein the impurities have a bad influence on product quality. When the time from the start of adding an alkylene oxide (AO) till the end of supplying the entirety of the AO is defined as T (hour), the amount of more than 50% of the entirety of the AO is supplied before T/2 (hour) has passed since the start of adding the AO. In addition, when the total amount of an AO as supplied and the time from the start of adding the AO till the end of supplying the entirety of the AO are defined as W (mol) and T (hour) respectively, the supply of the AO is started at a supplying speed V0 (mol/hour) that is faster than the average supplying speed V (=W/T) (mol/hour), and thereafter the supplying speed of the AO is decreased at least once, and then the supply of the entirety of the AO is completed for T (hour) from the start of adding the AO.
摘要翻译： 本发明提供：（甲基）丙烯酸羟烷基酯的制造方法，其能够提高生产率，同时避免爆炸的危险，并且还可以抑制杂质如杂质影响不良的杂质的副产物 对产品质量。 当从添加烯化氧（AO）开始直到提供AO全部结束时的时间定义为T（小时）时，超过全部AO的50％的量在T / 从加入AO开始，已经过了2（小时）。 此外，当供应的AO的总量和从AO的添加开始到提供AO的全部的时间分别被定义为W（mol）和T（小时）时， AO以比平均供给速度V（= W / T）（mol /小时）快）的供给速度V0（mol /小时）开始，此后AO的供给速度至少减少一次，然后 从添加AO开始，T（小时）完成AO的整体供应。
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7.发明授权Process for preserving resin catalyst for addition reaction of alkylene oxide and utilization of this process 失效用于保护用于环氧烷加成反应的树脂催化剂的方法和该方法的利用公开(公告)号：US06858761B2
公开(公告)日：2005-02-22
申请号：US10100766
申请日：2002-03-18
IPC分类号： B01J33/00 , B01J31/08 , C07B61/00 , C07C51/353 , C07C59/42 , C08G65/26 , C08G65/30 , C07C29/10 , B01J20/24 , C07C67/26
CPC分类号： C08G65/2615 , C08G65/2642 , C08G65/30 , Y02P20/584
摘要： The present invention provides a process and its utilization in a process comprising the step of carrying out an addition reaction of an alkylene oxide to an addition-receiving substance in the presence of a resin catalyst, thereby producing the addition reaction product, when the resin catalyst as used for the reaction is persevered so as to recycle it after it is recovered, the unreacted alkylene oxide remaining in the resin catalyst can be prevented from polymerizing and solidifying during the preservation, and the resin catalyst accordingly can be preserved stably for a long time. The resin catalyst as recovered after it is used for the reaction may be preserved under any of the following conditions: 1) at a low temperature of not higher than 40° C.; 2) in the presence of a carboxylic acid; 3) in the presence of a liquid having an alkylene oxide concentration of not more than 2 weight %; and 4) in the coexistence of a carboxylic acid and a liquid having an alkylene oxide concentration of not more than 2 weight %. The present catalyst is recycled for the above addition reaction.
摘要翻译： 本发明提供了一种方法及其在一种方法中的应用，该方法包括在树脂催化剂存在下进行环氧烷与加成物质的加成反应的步骤，由此生成加成反应产物，当树脂催化剂 如反应所用的那样被持续以便在回收之后再循环，可以防止保留在树脂催化剂中的未反应的烯化氧在保存期间聚合和固化，因此可以长时间稳定地保存树脂催化剂 。 用于反应后回收的树脂催化剂可以在以下任一条件下保存：1）在不高于40℃的低温下; 2）在羧酸存在下; 3）在具有不大于2重量％的环氧烷浓度的液体的存在下; 和4）在羧酸和烯化氧浓度不大于2重量％的液体的共存下。 将本催化剂再循环用于上述加成反应。
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公开(公告)号：US20050126966A1
公开(公告)日：2005-06-16
申请号：US10514621
申请日：2003-05-14
申请人： Katsuyoshi Tanida , Shinichi Nonaka , Mitsushige Shimada , Tsutomu Matsuda , Kiyoshi Hirai , Masahiro Uemura , Kazutaka Takata , Yutaka Ito , Susumu Hasegawa
发明人： Katsuyoshi Tanida , Shinichi Nonaka , Mitsushige Shimada , Tsutomu Matsuda , Kiyoshi Hirai , Masahiro Uemura , Kazutaka Takata , Yutaka Ito , Susumu Hasegawa
CPC分类号： B01D65/00 , B01D63/084 , B01D65/003 , B01D69/06 , B01D2313/04 , B01D2313/143 , B01D2319/022 , C02F1/444
摘要： It is an object of the present invention to provide a membrane separation apparatus and a membrane separation process that are unlikely to cause membrane fouling and plugging, capable of achieving membrane separation even with relatively low flow rate of water, have an excellent membrane packing density, and are unlikely to cause deposition of foreign components in the apparatus. In order to achieve the above object, according to the present invention, vessel-type inner casings are disposed in a pressure vessel along the longitudinal axis thereof, in which the pressure vessel has a water inlet at a first end and a concentrate outlet at a second end. A flow-regulating plate is disposed on the side of the water inlet of the pressure vessel. Stacks of membrane separation units are respectively disposed in the inner casings, and spacers are disposed between the adjacent membrane separation elements. The spacers also serve as sealing members. Each stack of the membrane separation units and the spacers together define a through-hole extending from a first side to a second side, of the stack of the membrane separation elements. The inner casings have permeate discharge passages along the longitudinal axis thereof. The permeate discharge passages are communicated with the through-hole of each stack of the membrane separation elements. Water that has been fed into the pressure vessel via the flow-regulating plate permeates through the membrane separation elements and is discharged to the outside via the through-holes and the permeate discharge passages.
摘要翻译： 本发明的目的是提供即使在相对较低的水流速下也能够实现膜分离的膜分离装置和膜分离方法不易引起膜污染和堵塞，具有优异的膜堆积密度， 并且不太可能引起异物在设备中的沉积。 为了实现上述目的，根据本发明，容器式内壳沿其纵向轴线设置在压力容器中，其中压力容器在第一端具有进水口和在第一端处具有浓缩物出口 第二端 流量调节板设置在压力容器的入口侧。 膜分离单元的分隔件分别设置在内壳中，间隔件设置在相邻的膜分离元件之间。 间隔件还用作密封构件。 膜分离单元和间隔物的每一叠层一起限定了从膜分离元件的堆叠的第一侧延伸到第二侧的通孔。 内壳具有沿其纵向轴线的渗透物排出通道。 渗透物排出通道与膜分离元件的每个叠层的通孔连通。 已经通过流量调节板进入压力容器的水渗入膜分离元件，并经由通孔和渗透物排出通道排出到外部。
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公开(公告)号：US4566463A
公开(公告)日：1986-01-28
申请号：US601222
申请日：1984-04-17
IPC分类号： A61B5/022 , A61B5/0225 , A61B5/0468 , A61B5/02
CPC分类号： A61B5/022 , A61B5/02255 , A61B5/0468
摘要： An automatic blood pressure measuring apparatus including an occluding device having a cuff to apply a pressure to a body member of a subject, and a blood-pressure determining device to determine a blood pressure according to a variation in a pulse wave in relation to a change in the cuff pressure. The apparatus comprises a detector for monitoring a blood circulatory system of the subject, and generating signals representing an abnormality associated with the circulatory system. The apparatus further comprises a control device for actuating the occluding device to apply the cuff pressure to the body member, and causing the blood-pressure determining device to execute a predetermined series of blood-pressure measuring steps to measure the blood pressure, thereby permitting an automatic measurement of the blood pressure of the subject when the blood circulatory system is found abnormal by the detector.
摘要翻译： 一种自动血压测量装置，包括具有用于对受试者的身体构件施加压力的袖带的闭塞装置，以及根据与变化相关的脉搏波的变化来确定血压的血压测定装置 袖口压力。 该装置包括用于监测对象的血液循环系统的检测器，以及产生表示与循环系统相关联的异常的信号。 该装置还包括用于致动闭塞装置以将袖带压施加到身体构件的控制装置，并且使得血压测定装置执行预定的一系列血压测量步骤来测量血压，从而允许 当血液循环系统被检测器发现异常时，自动测量受试者的血压。
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公开(公告)号：US20080018501A1
公开(公告)日：2008-01-24
申请号：US11778943
申请日：2007-07-17
申请人： Masahiro Uemura
发明人： Masahiro Uemura
IPC分类号： H03M11/00
CPC分类号： H03M11/00 , G06F3/0202 , H03M11/003 , H03M11/006 , H03M11/02 , H03M11/04
摘要： A computer keyboard which enables a computer to automatically recognize nomenclature information (ID) of keys is provided. Preferably, the keyboard contains a first memory which stores a table in which nomenclature information (ID) of keys and resistance values are associated with each other, a resistor having a resistance value substantially equal to any one of the resistance values, and a controller connected to the first memory and the resistor. The controller detects the resistance value of the resistor and reads the ID of the key corresponding to the resistance value from the table.
摘要翻译： 提供了使计算机能够自动识别键的命名信息（ID）的计算机键盘。 优选地，键盘包含第一存储器，该第一存储器存储一个表，其中按键和电阻值的命名信息（ID）彼此相关联，电阻值大致等于电阻值中的任何一个，并且控制器连接 到第一个存储器和电阻器。 控制器检测电阻的电阻值，并从表中读取与电阻值对应的键的ID。
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