公开(公告)号：US06340496B1

公开(公告)日：2002-01-22

申请号：US09573549

申请日：2000-05-19

申请人： Tom Cloots ,  Roger Van den Bogaert ,  Jean-Pierre Tahon ,  Frank Louwet

发明人： Tom Cloots ,  Roger Van den Bogaert ,  Jean-Pierre Tahon ,  Frank Louwet

IPC分类号： B05D512

CPC分类号： C08G61/126 ,  H01B1/127

摘要： A method for producing electrode pattern in a conductive polymer on a substrate comprising the steps of applying a layer containing between 10 and 5000 mg/m2 of a conductive polymer, so as to prepare a conductive layer and printing an electrode pattern on said layer using a printing solution containing of an oxidant selected from the group consisting of ClO−, BrO−, MnO4−, Cr2O7−−, S2O8−− and H2O2.

摘要翻译： 一种用于在基板上的导电聚合物中制造电极图案的方法，包括以下步骤：施加含有10-5000mg / m 2导电聚合物的层，以便制备导电层，并使用印刷溶液在所述层上印刷电极图案 含有选自ClO-，BrO-，MnO4-，Cr2O7--，S2O8--和H2O2的氧化剂。

公开(公告)号：US20060027791A1

公开(公告)日：2006-02-09

申请号：US11180051

申请日：2005-07-12

申请人： Jean-Pierre Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

发明人： Jean-Pierre Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

IPC分类号： C08G65/38 ,  H01B1/12

CPC分类号： H01B1/128 ,  C08J3/09 ,  C08J2365/00 ,  C08L65/00 ,  C09D5/24 ,  C09D11/033 ,  C09D11/36 ,  C09D11/52 ,  C09D165/00 ,  Y10T428/2809

摘要： A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.

摘要翻译： 一种制备含有0.08至3.0重量％的3,4-二烷氧基噻吩的聚合物或共聚物的组合物的方法，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧 - 亚烷基 - 氧桥， 聚阴离子和至少一种非水溶剂，其由（3,4-二烷氧基噻吩）的聚合物或共聚物和聚阴离子在水中的分散体组成，其在基本上不存在氧的情况下制备，包括以下步骤： i）将至少一种非水溶剂与（3,4-二烷氧基噻吩）和聚阴离子的聚合物或共聚物的水分散体混合; 和ii）从步骤i）中制备的混合物蒸发水，直到其中的水含量降低至少65重量％; 印刷油墨，印刷浆料或涂料组合物，其能够产生根据上述方法制备的在给定透明度下具有增强的导电性的层; 所述涂料组合物由此在给定的透明度下产生具有增强的导电性的层; 以及具有印刷油墨或糊料的印刷方法，从而在给定的透明度下产生具有增强的导电性的层。

公开(公告)号：US07223357B2

公开(公告)日：2007-05-29

申请号：US11180051

申请日：2005-07-12

申请人： Jean-Pierre Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

发明人： Jean-Pierre Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

IPC分类号： H01B1/12

CPC分类号： H01B1/128 ,  C08J3/09 ,  C08J2365/00 ,  C08L65/00 ,  C09D5/24 ,  C09D11/033 ,  C09D11/36 ,  C09D11/52 ,  C09D165/00 ,  Y10T428/2809

摘要： A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.

摘要翻译： 一种制备含有0.08至3.0重量％的3,4-二烷氧基噻吩的聚合物或共聚物的组合物的方法，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧 - 亚烷基 - 氧桥， 聚阴离子和至少一种非水溶剂，其由（3,4-二烷氧基噻吩）的聚合物或共聚物和聚阴离子在水中的分散体组成，其在基本上不存在氧的情况下制备，包括以下步骤： i）将至少一种非水溶剂与（3,4-二烷氧基噻吩）和聚阴离子的聚合物或共聚物的水分散体混合; 和ii）从步骤i）中制备的混合物蒸发水，直到其中的水含量降低至少65重量％; 印刷油墨，印刷浆料或涂料组合物，其能够产生根据上述方法制备的在给定透明度下具有增强的导电性的层; 所述涂料组合物由此在给定的透明度下产生具有增强的导电性的层; 以及具有印刷油墨或糊料的印刷方法，从而在给定的透明度下产生具有增强的导电性的层。

公开(公告)号：US06890584B2

公开(公告)日：2005-05-10

申请号：US10175948

申请日：2002-06-20

申请人： Luc Leenders ,  Eddie Daems ,  Frank Louwet ,  Rafaël Samijn ,  Jean-Pierre Tahon ,  Roger Van den Bogaert

发明人： Luc Leenders ,  Eddie Daems ,  Frank Louwet ,  Rafaël Samijn ,  Jean-Pierre Tahon ,  Roger Van den Bogaert

IPC分类号： C08G61/12 ,  C09D11/00 ,  C09D11/10 ,  C09D165/00 ,  C09K11/06 ,  H01B1/12 ,  H01L51/30 ,  H01L51/52 ,  B41M1/04

CPC分类号： H01B1/128 ,  C08G61/126 ,  C09D11/10 ,  C09D11/106 ,  C09D11/30 ,  C09D11/52 ,  C09D165/00 ,  C09K11/06 ,  H01L51/0022 ,  H01L51/0037 ,  H01L51/5206 ,  H01L51/5221

摘要： A non-dye containing flexographic ink containing a polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and a latex binder in a solvent or aqueous medium, characterized in that the polymer or copolymer of a 3,4-dialkoxythiophene is present in a concentration of at least 0.1% by weight in the ink and that the ink is capable of producing a colorimetrically additive transparent print; a method of preparing the flexographic ink; and a flexographic printing process therewith.

摘要翻译： 包含3,4-二烷氧基噻吩的聚合物或共聚物的非染料含柔性油墨，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧 - 亚烷基 - 氧桥，聚阴离子和胶乳粘合剂 在溶剂或水性介质中，其特征在于3,4-二烷氧基噻吩的聚合物或共聚物在油墨中以至少0.1重量％的浓度存在，并且油墨能够产生比色添加剂透明印刷品; 柔性油墨的制备方法; 和柔性版印刷工艺。

公开(公告)号：US06197418B1

公开(公告)日：2001-03-06

申请号：US09458829

申请日：1999-12-13

申请人： Tom Cloots ,  Frank Louwet ,  Hieronymus Andriessen ,  Bart Verlinden ,  Jean-Pierre Tahon ,  Leo Vermeulen ,  Luc Leenders ,  Rudi Goedeweeck

发明人： Tom Cloots ,  Frank Louwet ,  Hieronymus Andriessen ,  Bart Verlinden ,  Jean-Pierre Tahon ,  Leo Vermeulen ,  Luc Leenders ,  Rudi Goedeweeck

IPC分类号： B32B1710

CPC分类号： H05B33/28 ,  H01L51/5203 ,  Y10T428/26 ,  Y10T428/265 ,  Y10T428/266 ,  Y10T428/31507 ,  Y10T428/31616 ,  Y10T428/31627 ,  Y10T428/3163 ,  Y10T428/31645 ,  Y10T428/31649

摘要： A material is disclosed which comprises a substrate and an organic electroconductive layer provided on said substrate, characterised in that the substrate is a laminate comprising a glass layer and a support. The glass layer is preferably a flexible glass layer having a thickness from 10 to 500 &mgr;m. The material can be used as an electrode in electric or semiconductor devices thereby providing an improved lifetime, e.g. displays, photovoltaic cells or light-emitting diodes.

摘要翻译： 公开了一种材料，其包括基板和设置在所述基板上的有机导电层，其特征在于，所述基板是包括玻璃层和支撑体的层压体。 玻璃层优选为厚度为10〜500μm的柔性玻璃层。 该材料可以用作电或半导体器件中的电极，从而提供改善的寿命，例如， 显示器，光伏电池或发光二极管。

公开(公告)号：US07122130B2

公开(公告)日：2006-10-17

申请号：US10894441

申请日：2004-07-19

申请人： Jean-Piere Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

发明人： Jean-Piere Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

IPC分类号： H01B1/12

CPC分类号： H01B1/128 ,  C08J3/09 ,  C08J2365/00 ,  C08L65/00 ,  C09D5/24 ,  C09D11/033 ,  C09D11/36 ,  C09D11/52 ,  C09D165/00 ,  Y10T428/2809

摘要： A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.

公开(公告)号：US20050040372A1

公开(公告)日：2005-02-24

申请号：US10894441

申请日：2004-07-19

申请人： Jean-Piere Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

发明人： Jean-Piere Tahon ,  Roger Van den Bogaert ,  Bert Groenendaal ,  Frank Louwet

IPC分类号： B05D5/00 ,  H01B1/00

CPC分类号： H01B1/128 ,  C08J3/09 ,  C08J2365/00 ,  C08L65/00 ,  C09D5/24 ,  C09D11/033 ,  C09D11/36 ,  C09D11/52 ,  C09D165/00 ,  Y10T428/2809

摘要： A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.

摘要翻译： 一种制备含有0.08至3.0重量％的3,4-二烷氧基噻吩的聚合物或共聚物的组合物的方法，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧 - 亚烷基 - 氧桥， 聚阴离子和至少一种非水溶剂，其由（3,4-二烷氧基噻吩）的聚合物或共聚物和聚阴离子在水中的分散体组成，其在基本上不存在氧的情况下制备，包括以下步骤： i）将至少一种非水溶剂与（3,4-二烷氧基噻吩）和聚阴离子的聚合物或共聚物的水分散体混合; 和ii）从步骤i）中制备的混合物蒸发水，直到其中的水含量降低至少65重量％; 印刷油墨，印刷浆料或涂料组合物，其能够产生根据上述方法制备的在给定透明度下具有增强的导电性的层; 所述涂料组合物由此在给定的透明度下产生具有增强的导电性的层; 以及具有印刷油墨或糊料的印刷方法，从而在给定的透明度下产生具有增强的导电性的层。

公开(公告)号：US06333145B1

公开(公告)日：2001-12-25

申请号：US09433971

申请日：1999-11-04

申请人： Tom Cloots ,  Johan Loccufier ,  Frank Louwet ,  Hieronymus Andriessen

发明人： Tom Cloots ,  Johan Loccufier ,  Frank Louwet ,  Hieronymus Andriessen

IPC分类号： G03C185

CPC分类号： H01B1/127 ,  H01G9/028 ,  H01G11/48 ,  H01G11/56 ,  H01L51/5203 ,  Y02E60/13

摘要： A method for producing a polymeric conductive layer on an object comprising the steps of: providing an aqueous composition containing a polythiophene, a polyanion compound and an aprotic compound with a dielectric constant, &egr;, ≧15, applying said composition to said object forming a layer and drying said layer to form a conductive polymeric layer on said object, characterised in that during said production said object and said layer are kept at a temperature below 100° C. and said conductive polymeric layer has a resistivity of at most 2 k&OHgr;/square.

摘要翻译： 一种用于在物体上制备聚合物导电层的方法，包括以下步骤：提供含有聚噻吩，聚阴离子化合物和介质常数εi= 15的非质子化合物的水性组合物，将所述组合物施加到所述物体上形成 层和干燥所述层以在所述物体上形成导电聚合物层，其特征在于，在所述生产期间，所述物体和所述层保持在低于100℃的温度，并且所述导电聚合物层具有至多2kOMEGA /平方的电阻率 。

公开(公告)号：US06887556B2

公开(公告)日：2005-05-03

申请号：US10316274

申请日：2002-12-11

申请人： Johan Lamotte ,  Frank Louwet ,  Tom Cloots ,  Huub Van Aert

发明人： Johan Lamotte ,  Frank Louwet ,  Tom Cloots ,  Huub Van Aert

IPC分类号： H01B1/12 ,  H01L51/00 ,  H01L51/30 ,  H01L51/40 ,  H05K3/02 ,  H05K3/10 ,  D06N7/04

CPC分类号： H05K3/105 ,  H01B1/127 ,  H01L51/0021 ,  H01L51/0036 ,  H05K3/02 ,  Y10T428/24355 ,  Y10T428/24802 ,  Y10T428/269 ,  Y10T428/2933 ,  Y10T428/2971 ,  Y10T428/31855

摘要： A material for making a conductive pattern, the material comprising a support and a heat-differentiable element, the heat-differentiable element comprising an outermost layer containing a polyanion and an intrinsically conductive polymer and optionally a second layer contiguous with the outermost layer, characterized in that the outermost layer and/or the optional second layer contains hydrophobic thermocoagulable latex particles in a weight ratio range with respect to the intrinsically conductive polymer in the range of 20:1 to 1:5, the hydrophobic thermocoagulable latex particles are capable upon heating of increasing the conductivity of the heated parts of the outermost layer relative to the unheated parts of the outermost layer and/or changing the removability of the heated parts of the outermost layer relative to the unheated parts of the outermost layer and the heat-differentiable element does not comprise a di- or polyhydroxy organic compound or an aprotic compound with a dielectric constant, ∈, ≧15; a method of making a conductive pattern on a support therewith; and a use of the material for making a conductive pattern in making an electronic circuit in the production of an electric or semiconductor device such as a printed circuit board, an integrated circuit, a display or touch screen, an electroluminescent device or a photovoltaic cell.

摘要翻译： 一种用于制造导电图案的材料，该材料包括支撑体和可热分解的元件，该热可分离元件包括含有聚阴离子和本征导电聚合物的最外层，以及任选地与最外层邻接的第二层，其特征在于 最外层和/或任选的第二层含有相对于本征导电聚合物的重量比范围为20:1至1:5的疏水性热凝胶乳胶颗粒，疏水性热凝胶乳颗粒能够加热 增加最外层的加热部分相对于最外层的未加热部分的导电性和/或改变最外层的加热部分相对于最外层和可热分散元件的未加热部分的可去除性 不包含二 - 或多羟基有机化合物或具有夹层的非质子化合物 三次常数∈，> = 15; 在其上的支撑件上形成导电图案的方法; 以及在制造诸如印刷电路板，集成电路，显示器或触摸屏，电致发光器件或光伏电池的电气或半导体器件中的电子电路中制造导电图案的材料的用途。

公开(公告)号：US20050042556A1

公开(公告)日：2005-02-24

申请号：US10645160

申请日：2003-08-21

申请人： Frank Louwet ,  Tom Cloots ,  Hieronymus Andriessen

发明人： Frank Louwet ,  Tom Cloots ,  Hieronymus Andriessen

IPC分类号： H01B1/12 ,  H01B1/22 ,  H01L51/00 ,  H01L51/30 ,  H01L51/52 ,  H05K3/10 ,  G03C1/46

CPC分类号： H05K3/106 ,  H01B1/127 ,  H01B1/22 ,  H01L51/0021 ,  H01L51/0037 ,  H01L51/445 ,  H01L51/5203 ,  H05K2201/0329 ,  Y02E10/549

摘要： A process for preparing a substantially transparent conductive layer configuration on a support, the layer configuration comprising in any order at least a first layer containing an intrinsically conductive polymer optionally containing structural units represented by formula (I): wherein n is larger than 1 and each of R1 and R2 independently represents hydrogen or an optionally substituted C1-4 alkyl group or together represent an optionally substituted C1-4 alkylene group or an optionally substituted cycloalkylene group, preferably an ethylene group, an optionally alkyl-substituted methylene group, an optionally C1-12 alkyl- or phenyl-substituted ethylene group, a 1,3-propylene group or a 1,2-cyclohexylene group; and a second layer consisting of a non-continuous layer of conductive silver, the process comprising the step of: preparing the second layer by a photographic process; and light emitting diodes, photovoltaic devices, transistors and electroluminescent devices comprising a layer configuration prepared according to this process.

摘要翻译： 一种用于在载体上制备基本上透明的导电层构型的方法，所述层构型至少包含含有本发明的导电聚合物的第一层，所述固有导电聚合物任选含有由式（I）表示的结构单元：其中n大于1， R 1和R 2独立地表示氢或任选取代的C 1-4烷基或一起表示任选取代的C 1-4亚烷基或任选取代的亚环烷基，优选亚乙基，任选烷基取代的 亚甲基，任选的C 1-12烷基或苯基取代的亚乙基，1,3-亚丙基或1,2-亚环己基; 以及由不连续的导电银层组成的第二层，该方法包括以下步骤：通过摄影法制备第二层; 以及发光二极管，光电器件，晶体管和电致发光器件，其包括根据该工艺制备的层构型。