公开(公告)号：US20090104451A1

公开(公告)日：2009-04-23

申请号：US12337286

申请日：2008-12-17

申请人： Hiroshi Wada ,  Tomeyoshi Ohori

发明人： Hiroshi Wada ,  Tomeyoshi Ohori

IPC分类号： B32B27/40 ,  C08G18/10 ,  B05D3/02 ,  C08G18/32

CPC分类号： C09D175/08 ,  C08G18/12 ,  C08G18/227 ,  C08G18/4808 ,  C08G18/4812 ,  C08G18/755 ,  Y10T428/31551 ,  C08G18/307

摘要： The invention relates to a coating agent composition comprising an isocyanate-group-containing prepolymer obtained by reacting a polyol comprising a polyoxyalkylene polyol having 2-4 hydroxyl groups on average, an oxyethylene group content of 85-100% by mass based on all oxyalkylene groups (100% by mass), and an arithmetic-average molecular weight of 800-2,500 with an alicyclic isocyanate and/or an aliphatic isocyanate in the presence of an organic acid bismuth salt catalyst, the isocyanate(s) being used in such an amount as to result in an isocyanate index of 150-300. The invention can provide a coating agent composition which forms a coating film or film having moisture permeability, excellent in mechanical properties and yellowing resistance, having laundering durability and resistance to sweat deterioration, and containing no organotin compounds.

摘要翻译： 本发明涉及包含含异氰酸酯基的预聚物的涂料组合物，其通过使包含平均具有2-4个羟基的聚氧化烯多元醇的多元醇，基于所有氧化烯基的氧乙烯基含量为85-100质量％ （100质量％），在脂肪族异氰酸酯和/或脂肪族异氰酸酯的存在下，在有机酸铋盐催化剂的存在下，算术平均分子量为800〜2500，异氰酸酯的用量为 导致异氰酸酯指数为150-300。 本发明可以提供一种涂层剂组合物，其形成具有透湿性，机械性能和耐黄变性优异，具有洗涤耐久性和耐汗水劣化，不含有机锡化合物的涂膜或膜。

公开(公告)号：US20070287823A1

公开(公告)日：2007-12-13

申请号：US11777532

申请日：2007-07-13

申请人： Hiroshi Wada ,  Tomeyoshi Ohori

发明人： Hiroshi Wada ,  Tomeyoshi Ohori

IPC分类号： C08G18/81

CPC分类号： C09D175/08 ,  C08G18/12 ,  C08G18/227 ,  C08G18/4808 ,  C08G18/4812 ,  C08G18/755 ,  Y10T428/31551 ,  C08G18/307

摘要： The invention relates to a coating agent composition comprising an isocyanate-group-containing prepolymer obtained by reacting a polyol comprising a polyoxyalkylene polyol having 2-4 hydroxyl groups on average, an oxyethylene group content of 85-100% by mass based on all oxyalkylene groups (100% by mass), and an arithmetic-average molecular weight of 800-2,500 with an alicyclic isocyanate and/or an aliphatic isocyanate in the presence of an organic acid bismuth salt catalyst, the isocyanate(s) being used in such an amount as to result in an isocyanate index of 150-300. The invention can provide a coating agent composition which forms a coating film or film having moisture permeability, excellent in mechanical properties and yellowing resistance, having laundering durability and resistance to sweat deterioration, and containing no organotin compounds.

摘要翻译： 本发明涉及包含含异氰酸酯基的预聚物的涂料组合物，其通过使包含平均具有2-4个羟基的聚氧化烯多元醇的多元醇，基于所有氧化烯基的氧乙烯基含量为85-100质量％ （100质量％），在脂肪族异氰酸酯和/或脂肪族异氰酸酯的存在下，在有机酸铋盐催化剂的存在下，算术平均分子量为800〜2500，异氰酸酯的用量为 导致异氰酸酯指数为150-300。 本发明可以提供一种涂层剂组合物，其形成具有透湿性，机械性能和耐黄变性优异，具有洗涤耐久性和耐汗水劣化，不含有机锡化合物的涂膜或膜。

公开(公告)号：US20070191567A1

公开(公告)日：2007-08-16

申请号：US11737252

申请日：2007-04-19

申请人： Yukio TSUGE ,  Tomeyoshi Ohori ,  Hiroshi Wada

发明人： Yukio TSUGE ,  Tomeyoshi Ohori ,  Hiroshi Wada

IPC分类号： C08G18/00

CPC分类号： C08G18/44 ,  C08G18/10 ,  C08G18/4854 ,  C08G18/4866 ,  C09D11/102 ,  C08G18/3228 ,  C08G18/285 ,  C08G18/3206

摘要： Provided is a method for producing a polyurethane resin solution having a low tensile elasticity and a low elastic modulus and excellent elastic recovery under low temperatures. A method for producing a polyurethane resin solution, which comprises reacting an isocyanate-terminated prepolymer with a chain extender and/or a curing agent in an organic solvent, wherein said prepolymer is obtained by reacting a polyisocyanate compound and a polyether polyol (A) having a number average molecular weight of from 750 to 4,000, which is obtained by addition of an alkylene oxide with a polyoxytetramethylene diol or a polycarbonate diol having a number average molecular weight of from 500 to 2,500 as an initiator, using a composite metal cyanide complex catalyst.

摘要翻译： 本发明提供低拉伸弹性和低弹性模量的聚氨酯树脂溶液的制造方法，在低温下具有良好的弹性恢复性。 一种制备聚氨酯树脂溶液的方法，其包括使异氰酸酯封端的预聚物与扩链剂和/或固化剂在有机溶剂中反应，其中所述预聚物是通过使多异氰酸酯化合物和聚醚多元醇（A） 通过使用复合金属氰化物配合物催化剂将数均分子量为500〜2,500的聚氧四亚甲基二醇或聚碳酸酯二醇加成环氧烷作为引发剂而得到的数均分子量为750〜4000 。

公开(公告)号：US08841402B2

公开(公告)日：2014-09-23

申请号：US12337286

申请日：2008-12-17

申请人： Hiroshi Wada ,  Tomeyoshi Ohori

发明人： Hiroshi Wada ,  Tomeyoshi Ohori

IPC分类号： C08G18/12 ,  C08G18/22 ,  C08G18/48 ,  C08G18/73 ,  C08G18/75

CPC分类号： C09D175/08 ,  C08G18/12 ,  C08G18/227 ,  C08G18/4808 ,  C08G18/4812 ,  C08G18/755 ,  Y10T428/31551 ,  C08G18/307

摘要： The invention relates to a coating agent composition comprising an isocyanate-group-containing prepolymer obtained by reacting a polyol comprising a polyoxyalkylene polyol having 2-4 hydroxyl groups on average, an oxyethylene group content of 85-100% by mass based on all oxyalkylene groups (100% by mass), and an arithmetic-average molecular weight of 800-2,500 with an alicyclic isocyanate and/or an aliphatic isocyanate in the presence of an organic acid bismuth salt catalyst, the isocyanate(s) being used in such an amount as to result in an isocyanate index of 150-300. The invention can provide a coating agent composition which forms a coating film or film having moisture permeability, excellent in mechanical properties and yellowing resistance, having laundering durability and resistance to sweat deterioration, and containing no organotin compounds.

摘要翻译： 本发明涉及包含含异氰酸酯基的预聚物的涂料组合物，其通过使包含平均具有2-4个羟基的聚氧化烯多元醇的多元醇，基于所有氧化烯基的氧乙烯基含量为85-100质量％ （100质量％），在脂肪族异氰酸酯和/或脂肪族异氰酸酯的存在下，在有机酸铋盐催化剂的存在下，算术平均分子量为800〜2500，异氰酸酯的用量为 导致异氰酸酯指数为150-300。 本发明可以提供一种涂层剂组合物，其形成具有透湿性，机械性能和耐黄变性优异，具有洗涤耐久性和耐汗水劣化，不含有机锡化合物的涂膜或膜。

公开(公告)号：US07714093B2

公开(公告)日：2010-05-11

申请号：US11507544

申请日：2006-08-22

申请人： Yukio Tsuge ,  Tomeyoshi Ohori ,  Hiroshi Wada

发明人： Yukio Tsuge ,  Tomeyoshi Ohori ,  Hiroshi Wada

IPC分类号： C08G18/40 ,  C08G18/10 ,  C08G18/42 ,  C08G18/48 ,  C08G63/08 ,  C08G63/68

CPC分类号： D01F6/70 ,  C08G18/10 ,  C08G18/4261 ,  C08G18/4277 ,  C08G18/4833 ,  C08G18/4854 ,  C08G18/4887 ,  C08G18/32

摘要： Provided are a urethane resin solution to provide a urethane resin having a low tensile elasticity, a low elastic modulus under low temperatures, good elastic recovery, excellent heat resistance and excellent adhesion, a production method of the solution and a production method of the urethane resin.An isocyanate group-terminated prepolymer is synthesized by reacting a polyisocyanate compound with a polyetherester diol having a molecular weight of from 800 to 4,000, which is obtained by a ring-opening polymerization of a mixture of an alkylene oxide and a lactone monomer using a polyoxy tetramethylene diol having a molecular weight of from 500 to 2,500 as an initiator and using a composite metal cyanide complex catalyst if necessary, and the resulting prepolymer is reacted with a chain extender, for example, comprised of a low molecular weight diamine and/or a low molecular weight diol, in an organic solvent. The urethane resin solution obtained is molded into a predetermined shape, or a substrate is coated or impregnated with the urethane resin solution and thereafter the organic solvent is removed to obtain a urethane resin.

摘要翻译： 提供一种聚氨酯树脂溶液，其提供具有低拉伸弹性，低温下的低弹性模量，良好的弹性恢复性，优异的耐热性和优异的粘合性的聚氨酯树脂，该溶液的制备方法和聚氨酯树脂的制备方法 。 通过使多异氰酸酯化合物与分子量为800〜4000的聚醚酯二醇反应来合成异氰酸酯基封端的预聚物，其通过使用聚氧化烯的环氧烷和内酯单体的混合物的开环聚合获得 分子量为500〜2,500的四亚甲基二醇作为引发剂，如果需要使用复合金属氰化物配合物催化剂，所得预聚物与扩链剂例如由低分子量二胺和/或 低分子量二醇，在有机溶剂中。 将得到的聚氨酯树脂溶液成型为规定形状，或者将基材涂布或浸渍聚氨酯树脂溶液，然后除去有机溶剂，得到聚氨酯树脂。

公开(公告)号：US07906607B2

公开(公告)日：2011-03-15

申请号：US11876200

申请日：2007-10-22

申请人： Tomeyoshi Ohori ,  Hiroshi Wada

发明人： Tomeyoshi Ohori ,  Hiroshi Wada

IPC分类号： C08G18/12 ,  C08G18/42 ,  C08G18/44 ,  C08G18/76 ,  C09J175/06

CPC分类号： D06M17/10 ,  C08G18/12 ,  C08G18/4202 ,  C08G18/4238 ,  C08G18/44 ,  C08G2170/20 ,  Y10S528/905 ,  C08G18/307

摘要： It is an object of the present invention to provide an isocyanate group-terminated urethane prepolymer which has a low viscosity at melting and a process for producing the same, and an adhesive which comprises the urethane prepolymer. The invention relates to a process for producing an isocyanate group-terminated urethane prepolymer which comprises reacting polyols with a polyisocyanate compound, wherein the polyols comprise 10 to 50% by mass of a polyester polyol and 90 to 50% by mass of a polycarbonate polyol and wherein a sebacic acid-derived polyester polyol which is a polycondensate of sebacic acid with a diol compound accounts for 50 to 100% by mass of the polyester polyol and wherein the polyisocyanate compound and the polyols are reacted in such amounts that the ratio (by mol) of the isocyanate group/hydroxyl group is 1.2 to 3.2.

摘要翻译： 本发明的目的是提供一种在熔融时具有低粘度的异氰酸酯基封端的氨基甲酸酯预聚物及其制备方法，以及包含该氨基甲酸酯预聚物的粘合剂。 本发明涉及一种异氰酸酯基封端的氨基甲酸酯预聚物的制备方法，该方法包括使多元醇与多异氰酸酯化合物反应，其中所述多元醇包含10至50质量％的聚酯多元醇和90至50质量％的聚碳酸酯多元醇， 其中，癸二酸与二醇化合物的缩聚物的癸二酸衍生的聚酯多元醇占聚酯多元醇的50〜100质量％，其中多异氰酸酯化合物和多元醇的反应量使得 ）的异氰酸酯基/羟基为1.2〜3.2。

公开(公告)号：US20060281891A1

公开(公告)日：2006-12-14

申请号：US11507544

申请日：2006-08-22

申请人： Yukio Tsuge ,  Tomeyoshi Ohori ,  Hiroshi Wada

发明人： Yukio Tsuge ,  Tomeyoshi Ohori ,  Hiroshi Wada

IPC分类号： C08G18/00

CPC分类号： D01F6/70 ,  C08G18/10 ,  C08G18/4261 ,  C08G18/4277 ,  C08G18/4833 ,  C08G18/4854 ,  C08G18/4887 ,  C08G18/32

摘要： Provided are a urethane resin solution to provide a urethane resin having a low tensile elasticity, a low elastic modulus under low temperatures, good elastic recovery, excellent heat resistance and excellent adhesion, a production method of the solution and a production method of the urethane resin. An isocyanate group-terminated prepolymer is synthesized by reacting a polyisocyanate compound with a polyetherester diol having a molecular weight of from 800 to 4,000, which is obtained by a ring-opening polymerization of a mixture of an alkylene oxide and a lactone monomer using a polyoxy tetramethylene diol having a molecular weight of from 500 to 2,500 as an initiator and using a composite metal cyanide complex catalyst if necessary, and the resulting prepolymer is reacted with a chain extender, for example, comprised of a low molecular weight diamine and/or a low molecular weight diol, in an organic solvent. The urethane resin solution obtained is molded into a predetermined shape, or a substrate is coated or impregnated with the urethane resin solution and thereafter the organic solvent is removed to obtain a urethane resin.

摘要翻译： 提供一种聚氨酯树脂溶液，其提供具有低拉伸弹性，低温下的低弹性模量，良好的弹性恢复性，优异的耐热性和优异的粘合性的聚氨酯树脂，该溶液的制备方法和聚氨酯树脂的制备方法 。 通过使多异氰酸酯化合物与分子量为800〜4000的聚醚酯二醇反应来合成异氰酸酯基封端的预聚物，其通过使用聚氧化烯的环氧烷和内酯单体的混合物的开环聚合获得 分子量为500〜2,500的四亚甲基二醇作为引发剂，如果需要使用复合金属氰化物配合物催化剂，所得预聚物与扩链剂例如由低分子量二胺和/或 低分子量二醇，在有机溶剂中。 将得到的聚氨酯树脂溶液成型为规定形状，或者将基材涂布或浸渍聚氨酯树脂溶液，然后除去有机溶剂，得到聚氨酯树脂。

公开(公告)号：US08752927B2

公开(公告)日：2014-06-17

申请号：US13429302

申请日：2012-03-23

申请人： Toru Takahashi ,  Takamitsu Kondo ,  Kazuyoshi Tanase ,  Hiroshi Wada

发明人： Toru Takahashi ,  Takamitsu Kondo ,  Kazuyoshi Tanase ,  Hiroshi Wada

IPC分类号： B41J29/38

CPC分类号： B41J2/2103 ,  B41J2/145 ,  B41J2/21 ,  B41J2/2132 ,  B41J2/2135 ,  B41J2202/19 ,  B41J2202/20

摘要： A printing apparatus is provided in which a position of a joint of a first yellow nozzle group and a second yellow nozzle group in a predetermined direction is offset from a position of a joint of a first magenta nozzle group and a second magenta nozzle group in a predetermined position and a position of a joint of a first cyan nozzle group and a second cyan nozzle group in the predetermined position, and the position of the joint of the first magenta nozzle group and the second magenta nozzle group in the predetermined position is the same as the position of the joint of the first cyan nozzle group and the second cyan nozzle group in the predetermined direction.

摘要翻译： 提供了一种打印装置，其中第一黄色喷嘴组和第二黄色喷嘴组的接头在预定方向上的位置偏离第一品红色喷嘴组和第二品红色喷嘴组的接头的位置， 预定位置和第一青色喷嘴组和第二青色喷嘴组的接头的位置在预定位置，并且第一品红色喷嘴组和第二品红色喷嘴组的接合位置在预定位置是相同的 作为第一青色喷嘴组和第二青色喷嘴组的接头在预定方向上的位置。

公开(公告)号：US08507036B2

公开(公告)日：2013-08-13

申请号：US13526162

申请日：2012-06-18

申请人： Katsuhiko Shimizu ,  Hiroshi Wada ,  Yoshinori Toyota

发明人： Katsuhiko Shimizu ,  Hiroshi Wada ,  Yoshinori Toyota

IPC分类号： B05D1/02

CPC分类号： C08G18/482 ,  C08G18/1825 ,  C08G18/1833 ,  C08G18/3206 ,  C08G18/4816 ,  C08G18/4829 ,  C08G18/4833 ,  C08G18/4837 ,  C08G18/4841 ,  C08G18/5021 ,  C08G18/6674 ,  C08G18/7664 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2101/0083

摘要： To provide a process capable of producing a light-weight rigid open-cell foam by a spraying method using mainly or solely water as a blowing agent, wherein a polyol system liquid is excellent in storage stability even when the blowing agent is used in a large amount, and the foam is excellent in dimensional stability without sagging and capable of forming a uniform thermal insulation layer having an excellent appearance for the purpose of constructing a whole constructions.

摘要翻译： 为了提供一种能够通过主要或单独的水作为发泡剂的喷雾法生产轻质刚性开孔泡沫的方法，其中多元醇系液体即使在发泡剂使用时也具有优异的储存稳定性 量，并且泡沫体在尺寸稳定性方面优异而没有下垂，并且能够形成具有优异外观的均匀保温层，以构成整个结构。

公开(公告)号：US20120058679A1

公开(公告)日：2012-03-08

申请号：US13150731

申请日：2011-06-01

申请人： Hiroharu IKARI ,  Hiroshi Wada ,  Takaki Kurachi

发明人： Hiroharu IKARI ,  Hiroshi Wada ,  Takaki Kurachi

IPC分类号： H01R24/60 ,  H01R43/16

CPC分类号： H01R12/592 ,  H01R4/023 ,  H01R12/594 ,  H01R12/65 ,  H01R12/79 ,  H01R13/405 ,  H01R43/16 ,  H01R43/20 ,  H01R43/24 ,  Y10T29/49204

摘要： To well prevent a conductive contact from being peeled off with a simple structure, a rear end portion of the conductive contact to which a cable-shaped signal transmission medium is coupled is directly held by a contact engaging part. Even when an external force due to so-called flapping or the like is added from the cable-shaped signal transmission medium to the conductive contact, the conductive contact is well prevented from being peeled off. Also, a guide inclined surface for positioning the cable-shaped signal transmission medium is provided at the contact engaging part, and the cable-shaped signal transmission medium can be stably mounted along the guide inclined surface of the contact engaging part, thereby easily and accurately performing operations at the time of mounting, such as positioning.

摘要翻译： 为了很好地防止导电接触用简单的结构剥离，电缆形信号传输介质连接到的导电接触件的后端部分由接触接合部分直接固定。 即使当由电缆形状的信号传输介质向导电接点添加由于所谓的拍打等引起的外力时，也能够良好地防止导电接触被剥离。 此外，在接触接合部设置有用于定位线形信号传输介质的引导倾斜面，并且可以沿着接触接合部的引导倾斜面稳定地安装电缆形信号传输介质，从而容易且准确地 在安装时执行诸如定位的操作。