公开(公告)号：US20130197123A1

公开(公告)日：2013-08-01

申请号：US13877751

申请日：2011-10-05

申请人： Tomomasa Kaneko

发明人： Tomomasa Kaneko

IPC分类号： C07C57/13 ,  C08F136/20

CPC分类号： C07C57/13 ,  C07C59/60 ,  C07C69/734 ,  C07F5/00 ,  C07F7/003 ,  C07F7/2224 ,  C07F9/005 ,  C07F9/94 ,  C07F15/025 ,  C07F15/045 ,  C08F136/20

摘要： The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

摘要翻译： 要求保护的发明提供了一种未经过研究的新化合物，即含有特定结构的二烯羧酸盐阴离子及其盐。 要求保护的发明还可以提供一种易于溶于一般有机溶剂，反应性稀释剂和树脂的二烯羧酸盐阴离子及其盐，特别是其金属盐，在常温下可根据结构处于液态， 具有高聚合性。 这些聚合/固化产生了引入许多离子键和金属的树脂，提供了各种性能，例如硬度，耐擦伤性，抗指纹性，阻气性，水蒸气阻隔性，氧吸收性，紫外线防护 红外线保护，显色和着色，高折射率，附着力，各种催化能力，荧光能力和发光能力，光学放大，分散性和抗静电性能。 此外，阴离子和盐可用于功能性细颗粒和金属纳米颗粒复合材料的原料，也可用于MOD材料。 所要求保护的发明还提供了制备二烯羧酸根阴离子及其盐的有利方法。

公开(公告)号：US06774192B2

公开(公告)日：2004-08-10

申请号：US10012083

申请日：2001-12-02

申请人： Hideo Asano ,  Kenichi Ueda ,  Minoru Yamaguchi ,  Masatoshi Yoshida ,  Tomomasa Kaneko ,  Shingo Kataoka

发明人： Hideo Asano ,  Kenichi Ueda ,  Minoru Yamaguchi ,  Masatoshi Yoshida ,  Tomomasa Kaneko ,  Shingo Kataoka

IPC分类号： C08E1614

CPC分类号： C08F220/14 ,  C08F8/16 ,  C08F220/28 ,  C08F2810/20 ,  C08F2810/30 ,  G02F1/133514 ,  G03F7/0007 ,  G03F7/033 ,  G03F7/0388

摘要： The present invention provides: a photosensitive resin composition, which can form uniform coating films having higher coating film strength without causing surface contamination, decrease of evenness of coating films, decrease of film thickness, and coloring by decomposition in heat treatment of subsequent steps, and has good sensitivity of exposure. The photosensitive resin composition comprises a lactone-ring-containing polymer (A) as an essential component, wherein: the lactone-ring-containing polymer (A) is obtained by carrying out polymerization of comonomers and lactonization at the same time wherein the comonomers include a 2-(hydroxyalkyl)acrylate ester and an acidic-group-containing monomer; and the lactone-ring-containing polymer (A) is obtained by almost quantitatively carrying out lactonization of a 2-(hydroxyalkyl)acrylate ester structural unit.

摘要翻译： 本发明提供一种光敏树脂组合物，其可以形成具有更高涂膜强度的均匀涂膜，而不会引起表面污染，涂膜的均匀性降低，膜厚度降低和后续步骤的热处理中的分解着色， 具有良好的曝光敏感度。 感光性树脂组合物含有含有内酯环的聚合物（A）作为必要成分，其中：含内酯环的聚合物（A）通过共聚单体的聚合和内酯化的同时获得，其中共聚单体包括 2-（羟基烷基）丙烯酸酯和含酸性基团的单体; 含有内酯环的聚合物（A）通过几乎定量地进行2-（羟基烷基）丙烯酸酯结构单元的内酯化而得到。

公开(公告)号：US08796492B2

公开(公告)日：2014-08-05

申请号：US13260110

申请日：2010-03-31

申请人： Makoto Saito ,  Hiroko Izumi ,  Toshimitsu Moriguchi ,  Tomomasa Kaneko ,  Atsushi Tachibana ,  Mitsuaki Makino ,  Yasuhiro Mimura

发明人： Makoto Saito ,  Hiroko Izumi ,  Toshimitsu Moriguchi ,  Tomomasa Kaneko ,  Atsushi Tachibana ,  Mitsuaki Makino ,  Yasuhiro Mimura

IPC分类号： C07C43/11 ,  C07C41/06 ,  C07C41/46 ,  C07C43/15

CPC分类号： C07C43/15 ,  C07C41/06 ,  C07C41/46 ,  C07C67/31 ,  C07C67/62 ,  C07C69/734 ,  C08F220/40 ,  Y02P20/582

摘要： An α-(unsaturated alkoxyalkyl)acrylate composition is provided which enables an α-(unsaturated alkoxyalkyl)acrylate product to be stored at a high purity for an extended period of time and can fully suppress problems such as discoloration and gelation from arising during polymerization, and a method of safely preparing α-(unsaturated alkoxyalkyl)acrylate compositions industrially, with high purity. The composition includes an α-(unsaturated alkoxyalkyl)acrylate of a specific structure and an antioxidant, the content of the antioxidant being from 0.03 to 0.5 wt % per 100 wt % of the α-(unsaturated alkoxyalkyl)acrylate.

摘要翻译： 提供了丙烯酸α-（不饱和烷氧基烷基）丙烯酸酯组合物，其能够使α-（不饱和烷氧基烷基）丙烯酸酯产物以高纯度长时间储存​​，并且可以完全抑制聚合过程中出现的变色和凝胶化等问题， 以及在工业上以高纯度安全地制备α-（不饱和烷氧基烷基）丙烯酸酯组合物的方法。 该组合物包括特定结构的α-（不饱和烷氧基烷基）丙烯酸酯和抗氧化剂，抗氧化剂的含量为每100重量％的α-（不饱和烷氧基烷基）丙烯酸酯为0.03-0.5重量％。

公开(公告)号：US20110263805A1

公开(公告)日：2011-10-27

申请号：US13142142

申请日：2009-12-28

申请人： Tomomasa Kaneko

发明人： Tomomasa Kaneko

IPC分类号： C08F220/06 ,  C08F220/28

CPC分类号： C09B67/0013 ,  C08F220/14 ,  C08F220/40 ,  C08L2666/02 ,  C09J133/08

摘要： The present invention provides: resins which can be used for various applications such as radical curable resin compositions, colorant-dispersed compositions, and photosensitive resin compositions; resin compositions; and means for producing the resins. Specifically, the present invention provides an α-allyloxymethylacrylic copolymer having in its main chain a structural unit represented by formula (1): wherein R is a hydrogen atom or a C1-C30 organic group.

摘要翻译： 本发明提供：可用于各种用途的树脂，例如可自由基固化树脂组合物，着色剂分散组合物和感光性树脂组合物; 树脂组合物; 以及用于生产树脂的方法。 具体而言，本发明提供了一种α-烯丙氧基甲基丙烯酸共聚物，其主链具有由式（1）表示的结构单元：其中R是氢原子或C1-C30有机基团。

公开(公告)号：US08497332B2

公开(公告)日：2013-07-30

申请号：US13142142

申请日：2009-12-28

申请人： Tomomasa Kaneko

发明人： Tomomasa Kaneko

IPC分类号： C08F220/06 ,  C08F220/28

CPC分类号： C09B67/0013 ,  C08F220/14 ,  C08F220/40 ,  C08L2666/02 ,  C09J133/08

摘要： The present invention provides: resins which can be used for various applications such as radical curable resin compositions, colorant-dispersed compositions, and photosensitive resin compositions; resin compositions; and means for producing the resins. Specifically, the present invention provides an α-allyloxymethylacrylic copolymer having in its main chain a structural unit represented by formula (1): wherein R is a hydrogen atom or a C1-C30 organic group.

摘要翻译： 本发明提供：可用于各种用途的树脂，例如可自由基固化树脂组合物，着色剂分散组合物和感光性树脂组合物; 树脂组合物; 以及用于生产树脂的方法。 具体地说，本发明提供一种α-烯丙氧基甲基丙烯酸共聚物，其主链具有由式（1）表示的结构单元：其中R是氢原子或C 1 -C 30有机基团。

公开(公告)号：US20050074563A1

公开(公告)日：2005-04-07

申请号：US10490658

申请日：2002-09-24

申请人： Masahiro Tatsuzawa ,  Kiyoshi Ito ,  Shinji Hayashi ,  Shunsuke Sega ,  Tomonobu Sumino ,  Minoru Yamaguchi ,  Tomomasa Kaneko ,  Kenichi Ueda

发明人： Masahiro Tatsuzawa ,  Kiyoshi Ito ,  Shinji Hayashi ,  Shunsuke Sega ,  Tomonobu Sumino ,  Minoru Yamaguchi ,  Tomomasa Kaneko ,  Kenichi Ueda

IPC分类号： C08F222/40 ,  G02F1/1335 ,  G03F7/00 ,  G03F7/037 ,  G03F7/038 ,  G03F7/004 ,  G02B5/20

CPC分类号： C08F222/40 ,  G02F1/133514 ,  G03F7/0007 ,  G03F7/037 ,  G03F7/0387 ,  Y10T428/10

摘要： It is an object of the present invention to provide an alkali-soluble maleimide-based copolymer excellent in resistance for thermally yellowing, high in hardness, excellent in solubility in solvents and capable of readily forming uniform coat films and, in addition, capable of being satisfactorily dissolved in alkali water when remaining uncured, as well as a pigment dispersion composition comprising such copolymer and an ionizing radiation-curable resin composition comprising such copolymer. Another object of the present invention is to provide a color filter and a liquid crystal display which are formed by using the ionizing radiation-curable resin composition. The present invention is related to an alkali-soluble maleimide-based copolymer which comprises, as essential constituents, 5 to 50% by mass of a maleimide monomer unit which is at least one unit selected from the group consisting of a N-cyclohexylmaleimide monomer unit, a N-benzylmaleimide monomer unit and a substituted N-benzylmaleimide monomer unit, 8 to 30% by mass of the (meth)acrylic acid monomer unit and 30 to 87% by mass of a (meth)acrylic acid ester monomer unit and which satisfies the condition represented by the formula: 0.4×X≦Y≦0.5×X+10  where X is the content, in % by mass, of the N-cyclohexylmaleimide monomer unit, the N-benzylmaleimide monomer unit and the substituted N-benzylmaleimide monomer unit and Y is the content, in % by mass, of the (meth)acrylic acid monomer unit.

摘要翻译： 本发明的目的是提供一种耐热黄变性，硬度高，在溶剂中溶解性优异并且能够容易地形成均匀涂膜的碱溶性马来酰亚胺基共聚物，并且还能够 保留未固化时，令人满意地溶解在碱水中，以及包含这种共聚物的颜料分散体组合物和包含这种共聚物的电离辐射固化树脂组合物。 本发明的另一个目的是提供一种通过使用电离辐射固化树脂组合物形成的滤色器和液晶显示器。 本发明涉及一种碱溶性马来酰亚胺类共聚物，其中，作为必要成分，含有5〜50质量％的马来酰亚胺单体单元，该单体单元为选自N-环己基马来酰亚胺单体单元 ，N-苄基马来酰亚胺单体单元和取代的N-苄基马来酰亚胺单体单元，8〜30质量％的（甲基）丙烯酸单体单元和30〜87质量％的（甲基）丙烯酸酯单体单元， 满足由下式表示的条件：0.4xX <= Y <= 0.5×X + 10其中X是N-环己基马来酰亚胺单体单元，N-苄基马来酰亚胺单体单元和取代的N-苄基马来酰亚胺的含量（以质量％计） 单体单元，Y为（甲基）丙烯酸单体单元的质量％。

公开(公告)号：US09499466B2

公开(公告)日：2016-11-22

申请号：US13877751

申请日：2011-10-05

申请人： Tomomasa Kaneko

发明人： Tomomasa Kaneko

IPC分类号： C07C57/13 ,  C07C59/60 ,  C07F5/00 ,  C07F7/00 ,  C07F7/22 ,  C08F136/20 ,  C07C69/734 ,  C07F9/00 ,  C07F9/94 ,  C07F15/02 ,  C07F15/04

CPC分类号： C07C57/13 ,  C07C59/60 ,  C07C69/734 ,  C07F5/00 ,  C07F7/003 ,  C07F7/2224 ,  C07F9/005 ,  C07F9/94 ,  C07F15/025 ,  C07F15/045 ,  C08F136/20

摘要： The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

摘要翻译： 要求保护的发明提供了一种未经过研究的新化合物，即含有特定结构的二烯羧酸盐阴离子及其盐。 要求保护的发明还可以提供一种易于溶于一般有机溶剂，反应性稀释剂和树脂的二烯羧酸盐阴离子及其盐，特别是其金属盐，在常温下可根据结构处于液态， 具有高聚合性。 这些聚合/固化产生了引入许多离子键和金属的树脂，提供了各种性能，例如硬度，耐擦伤性，抗指纹性，阻气性，水蒸气阻隔性，氧吸收性，紫外线防护 红外线保护，显色和着色，高折射率，附着力，各种催化能力，荧光能力和发光能力，光学放大，分散性和抗静电性能。 此外，阴离子和盐可用于功能性细颗粒和金属纳米颗粒复合材料的原料，也可用于MOD材料。 所要求保护的发明还提供了制备二烯羧酸根阴离子及其盐的有利方法。

公开(公告)号：US20120016095A1

公开(公告)日：2012-01-19

申请号：US13260110

申请日：2010-03-31

申请人： Makoto Saito ,  Hiroko Izumi ,  Toshimitsu Moriguchi ,  Tomomasa Kaneko ,  Atsushi Tachibana ,  Mitsuaki Makino ,  Yasuhiro Mimura

发明人： Makoto Saito ,  Hiroko Izumi ,  Toshimitsu Moriguchi ,  Tomomasa Kaneko ,  Atsushi Tachibana ,  Mitsuaki Makino ,  Yasuhiro Mimura

IPC分类号： C08F136/20

CPC分类号： C07C43/15 ,  C07C41/06 ,  C07C41/46 ,  C07C67/31 ,  C07C67/62 ,  C07C69/734 ,  C08F220/40 ,  Y02P20/582

摘要： An α-(unsaturated alkoxyalkyl)acrylate composition is provided which enables an α-(unsaturated alkoxyalkyl)acrylate product to be stored at a high purity for an extended period of time and can fully suppress problems such as coloration and gelation from arising during polymerization, and also a method of preparing α-(unsaturated alkoxyalkyl)acrylate compositions for enabling to obtain industrially α-(unsaturated alkoxyalkyl)acrylates safely in a high purity is also provided.The composition includes an α-(unsaturated alkoxyalkyl)acrylate of a specific structure and an antioxidant, the content of the antioxidant being from 0.03 to 0.5 wt % per 100 wt % of the α-(unsaturated alkoxyalkyl)acrylate.

摘要翻译： 提供了丙烯酸α-（不饱和烷氧基烷基）丙烯酸酯组合物，其能够使α-（不饱和烷氧基烷基）丙烯酸酯产物以高纯度长时间储存​​，并且可以完全抑制聚合期间产生的着色和凝胶化等问题， 还提供了能够以高纯度安全地获得工业上得到的α-（不饱和烷氧基烷基）丙烯酸酯的α-（不饱和烷氧基烷基）丙烯酸酯组合物的方法。 该组合物包括特定结构的α-（不饱和烷氧基烷基）丙烯酸酯和抗氧化剂，抗氧化剂的含量为每100重量％的α-（不饱和烷氧基烷基）丙烯酸酯为0.03-0.5重量％。

公开(公告)号：US07371783B2

公开(公告)日：2008-05-13

申请号：US10490658

申请日：2002-09-24

申请人： Masahiro Tatsuzawa ,  Kiyoshi Ito ,  Shinji Hayashi ,  Shunsuke Sega ,  Tomonobu Sumino ,  Minoru Yamaguchi ,  Tomomasa Kaneko ,  Kenichi Ueda

发明人： Masahiro Tatsuzawa ,  Kiyoshi Ito ,  Shinji Hayashi ,  Shunsuke Sega ,  Tomonobu Sumino ,  Minoru Yamaguchi ,  Tomomasa Kaneko ,  Kenichi Ueda

IPC分类号： C08F2/46 ,  C08F20/52 ,  G03C1/00

CPC分类号： C08F222/40 ,  G02F1/133514 ,  G03F7/0007 ,  G03F7/037 ,  G03F7/0387 ,  Y10T428/10

摘要： Provided is an alkali-soluble maleimide-based copolymer which comprises, as essential constituents, 5 to 50% by mass of a maleimide monomer unit which is at least one unit selected from the group consisting of a N-cyclohexylmaleimide monomer unit, a N-benzylmaleimide monomer unit and a substituted N-benzylmaleimide monomer unit, 8 to 30% by mass of the (meth)acrylic acid monomer unit and 30 to 87% by mass of a (meth)acrylic acid ester monomer unit and which satisfies the condition represented by the formula: 0.4×X≦Y≦0.5×X+10 where X is the content, in % by mass, of the N-cyclohexylmaleimide monomer unit, the N-benzylmaleimide monomer unit and the substituted N-benzylmaleimide monomer unit and Y is the content, in % by mass, of the (meth)acrylic acid monomer unit. Also provided are a color filter and a liquid crystal display which are formed by using the ionizing radiation-curable resin composition.

摘要翻译： 本发明提供一种碱溶性马来酰亚胺系共聚物，作为必要成分，含有5〜50质量％的马来酰亚胺单体单元，该单体单元为选自N-环己基马来酰亚胺单体单元，N- 苄基马来酰亚胺单体单元和取代的N-苄基马来酰亚胺单体单元，8〜30质量％的（甲基）丙烯酸单体单元和30〜87质量％的（甲基）丙烯酸酯单体单元， 通过以下公式：<？in-line-formula description =“In-line formula”end =“lead”？> 0.4xX <= Y <= 0.5xX + 10 <？in-line-formula description =“In-line 式“end =”tail“？>其中X是N-环己基马来酰亚胺单体单元，N-苄基马来酰亚胺单体单元和取代的N-苄基马来酰亚胺单体单元的含量，以质量％计，Y为含量％ 的（甲基）丙烯酸单体单元。 还提供了通过使用电离辐射固化树脂组合物形成的滤色器和液晶显示器。