公开(公告)号：US11814452B2

公开(公告)日：2023-11-14

申请号：US17314163

申请日：2021-05-07

Applicant: Korea University Research and Business Foundation

Inventor： Hyo Jae Yoon ,  Sangmin Jung

IPC: C08F136/20

CPC classification number: C08F136/20

Abstract: Disclosed are new polymeric materials that respond to a mechanical force. The novel polymeric compounds contain an isomer of aziridine, a three-membered N-heterocyclic compound. Also disclosed are methods for preparing the polymeric compounds. Mechanical force-induced cycloaddition of aziridines as mechanophores yields stereospecific products without covalent bond cleavage of aziridines. That is, a mechanical force makes the mechanochemical products stereospecific. The stereospecific products prepared from the isomeric mechanophores by a mechanical force can be widely used in various industrial fields, including new materials.

公开(公告)号：US20170283355A1

公开(公告)日：2017-10-05

申请号：US15472508

申请日：2017-03-29

Applicant: The University of Massachusetts

Inventor： Todd Emrick ,  E. Bryan Coughlin ,  Megan Szyndler ,  Aabid A. Mir ,  Justin C. Timmons

IPC: C07C49/84 ,  C08F36/20 ,  C09K21/06 ,  C08F36/22

CPC classification number: C08F36/22 ,  C07C49/84 ,  C08F12/34 ,  C08F16/36 ,  C08F36/20 ,  C08F112/34 ,  C08F116/36 ,  C08F136/20 ,  C08F136/22 ,  C08F212/34 ,  C08F216/36 ,  C08F236/20 ,  C08F236/22 ,  C09K21/06 ,  C09K21/14

Abstract: An unsaturated deoxybenzoin compound has the structure (I) wherein R1, R2, R3, R4, R5, R6, R7, R8, and n are defined herein. A polymer including at least one group derived from a deoxybenzoin compound having structure (I), (II), or a combination thereof is also described, wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, and n are defined herein.

公开(公告)号：US09273166B2

公开(公告)日：2016-03-01

申请号：US14032066

申请日：2013-09-19

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Ian C. Stewart ,  John R. Hagadorn ,  Mun F. Tse ,  George Rodriguez ,  Patrick Brant

IPC: C08F136/20 ,  C07C13/45 ,  C07C233/10 ,  C07C57/26 ,  C07C255/31 ,  C07C67/343 ,  C07C13/68 ,  C09J123/14 ,  C08G61/08 ,  C09J165/00 ,  C08L65/00

CPC classification number: C08F136/20 ,  C07C13/45 ,  C07C13/68 ,  C07C57/26 ,  C07C67/343 ,  C07C233/10 ,  C07C255/31 ,  C07C2603/91 ,  C08G61/08 ,  C08G2261/1644 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/72 ,  C08L57/02 ,  C08L65/00 ,  C09J123/14 ,  C09J165/00 ,  C07C69/608 ,  C08L23/06 ,  C08L23/14

Abstract: This invention relates to a reaction product obtained by contacting a polymer comprising units derived from dicyclopentadiene with a vinyl terminated macromonomer, a vinyl monomer or a vinylene monomer, in the presence of a metathesis catalyst, where the vinyl monomer or vinylene monomer is represented by the formula: wherein each X is, independently, —CO2R, —CONR1R2, CN, a C1 to a C20 alkyl group; R is a C1 to a C20 alkyl group or an aromatic group; each R1 and R2 is, independently, a hydrogen, a C1 to a C20 alkyl group, or an aromatic group; each R5 is, independently, a hydrogen atom or a C1 to a C40 alkyl group; each Ar is, independently, an aromatic group; and each n is, independently, from 0 to about 40.

Abstract translation: 本发明涉及通过在复分解催化剂存在下将包含衍生自二环戊二烯的单体的聚合物与乙烯基封端的大分子单体，乙烯基单体或亚乙烯基单体接触而获得的反应产物，其中乙烯基单体或亚乙烯基单体由 式：其中每个X独立地是-CO 2 R，-CONR 1 R 2，CN，C 1至C 20烷基; R是C1至C20烷基或芳基; 每个R 1和R 2独立地是氢，C 1至C 20烷基或芳基; 每个R 5独立地为氢原子或C 1至C 40烷基; 每个Ar独立地是芳族基团; 并且每个n独立地为0至约40。

公开(公告)号：US08623967B2

公开(公告)日：2014-01-07

申请号：US13470670

申请日：2012-05-14

Applicant: Steven Luo

Inventor： Steven Luo

IPC: C08F136/06 ,  C08L9/00 ,  C08L9/06 ,  C08L23/08 ,  C08L33/08 ,  C08L33/10 ,  C08L75/04 ,  C08L81/04 ,  C08L83/04

CPC classification number: C08F136/06 ,  C08C19/44 ,  C08F4/06 ,  C08F8/30 ,  C08F36/04 ,  C08F36/06 ,  C08F136/04 ,  C08F136/20 ,  C08K3/04 ,  C08L7/00 ,  C08L9/00 ,  C08L15/00 ,  C08L2666/08

Abstract: A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomer with a coordination catalyst to form a reactive polymer; and (ii) reacting the reactive polymer with a nitroso compound.

Abstract translation: 一种制备官能化聚合物的方法，所述方法包括以下步骤：（i）用配位催化剂聚合单体以形成反应性聚合物; 和（ii）使反应性聚合物与亚硝基化合物反应。

公开(公告)号：US20130303719A1

公开(公告)日：2013-11-14

申请号：US13880438

申请日：2011-10-19

Applicant: Bernard Miles Malofsky ,  Tanmoy Dey ,  Jeffrey M. Sullivan ,  Yangbin Chen ,  Stanley C. Wojciak ,  Bernard M. Malofsky

Inventor： Bernard Miles Malofsky ,  Tanmoy Dey ,  Jeffrey M. Sullivan ,  Yangbin Chen ,  Stanley C. Wojciak ,  Bernard M. Malofsky

IPC: C07C67/343 ,  C08G63/00 ,  C07C69/602

CPC classification number: C07C69/602 ,  C07C67/343 ,  C07C69/593 ,  C08F122/14 ,  C08F136/20 ,  C08G63/00 ,  C08L35/02 ,  C08L47/00 ,  C09D167/00 ,  Y02P20/127 ,  Y10T428/249921

Abstract: The present invention provides improved methods for the chemical synthesis of methylene malonates using the Knovenagel synthesis reaction. The method of the invention provides for improved methylene malonates by significantly reducing or eliminating the formation of alternative and/or deleterious side products, significantly reducing or eliminating unwanted consumption of methylene malonates, and significantly reducing or eliminating the degradation of methylene malonates. These advantages result in methylene malonates, which upon recovery, are of higher quality, greater purity, improved yield and possess overall improved performance characteristics (e.g., improved cure speed, retention of cure speed, improved shelf-life and/or stability).

Abstract translation: 本发明提供使用Knovenagel合成反应化学合成丙二酸亚甲酯的改进方法。 本发明的方法通过显着减少或消除替代和/或有害副产物的形成，显着减少或消除不需要的丙二酸亚丙酯消耗，以及显着降低或消除丙二酸亚甲酯的降解来提供改进的亚甲基丙二酸酯。 这些优点导致亚甲基丙二酸酯，其在回收时具有更高的质量，更高的纯度，更高的产率并且具有总体改进的性能特征（例如，改进的固化速度，固化速度的保持，改善的保存期限和/或稳定性）。

公开(公告)号：US20130197123A1

公开(公告)日：2013-08-01

申请号：US13877751

申请日：2011-10-05

Applicant: Tomomasa Kaneko

Inventor： Tomomasa Kaneko

IPC: C07C57/13 ,  C08F136/20

CPC classification number: C07C57/13 ,  C07C59/60 ,  C07C69/734 ,  C07F5/00 ,  C07F7/003 ,  C07F7/2224 ,  C07F9/005 ,  C07F9/94 ,  C07F15/025 ,  C07F15/045 ,  C08F136/20

Abstract: The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

Abstract translation: 要求保护的发明提供了一种未经过研究的新化合物，即含有特定结构的二烯羧酸盐阴离子及其盐。 要求保护的发明还可以提供一种易于溶于一般有机溶剂，反应性稀释剂和树脂的二烯羧酸盐阴离子及其盐，特别是其金属盐，在常温下可根据结构处于液态， 具有高聚合性。 这些聚合/固化产生了引入许多离子键和金属的树脂，提供了各种性能，例如硬度，耐擦伤性，抗指纹性，阻气性，水蒸气阻隔性，氧吸收性，紫外线防护 红外线保护，显色和着色，高折射率，附着力，各种催化能力，荧光能力和发光能力，光学放大，分散性和抗静电性能。 此外，阴离子和盐可用于功能性细颗粒和金属纳米颗粒复合材料的原料，也可用于MOD材料。 所要求保护的发明还提供了制备二烯羧酸根阴离子及其盐的有利方法。

公开(公告)号：US20080234450A1

公开(公告)日：2008-09-25

申请号：US11958905

申请日：2007-12-18

Applicant: Kohtaro OSAKADA ,  Daisuke TAKEUCHI ,  Sehoon PARK ,  Makoto UEMURA ,  Masayuki FUJITA

Inventor： Kohtaro OSAKADA ,  Daisuke TAKEUCHI ,  Sehoon PARK ,  Makoto UEMURA ,  Masayuki FUJITA

IPC: C08F4/12 ,  C08F30/08 ,  C08F2/00

CPC classification number: C08F136/20 ,  C08F4/7006 ,  C08F4/7042

Abstract: A polymer containing units represented by the defined formula (1); and a process for producing the polymer, which comprises the step of polymerizing a compound represented by the defined formula (3), the units represented by the formula (1) being polymerized units of the compound represented by the formula (3) such as 9,9-diallylfluorene.

Abstract translation: 含有由式（1）表示的单元的聚合物; 和聚合物的制造方法，其特征在于，包括使由式（3）表示的化合物聚合的方法，由式（1）表示的单元是由式（3）表示的化合物的聚合单元，例如9 ，9-二烯丙基芴。

公开(公告)号：US3879498A

公开(公告)日：1975-04-22

申请号：US17671271

申请日：1971-08-31

Applicant: ILIOPULOS MILTIADIS I ,  EGE WERNER K E

Inventor： ILIOPULOS MILTIADIS I ,  EGE WERNER K E

IPC: C07F9/40 ,  C08F136/20 ,  C08F3/00

CPC classification number: C08F136/20 ,  C07F9/4006 ,  C07F9/4015

Abstract: Dialkyl 1-acryloyloxy-2-alkenyl-1-phosphonates and dialkyl 1methacryloyloxy-2-alkenyl-1-phosphonates are prepared by reacting a dialkyl 1-hydroxy-2-alkenyl-1-phosphonate with acryloyl- or methacryloyl chloride in the presence of a base, using preferably an inert organic solvent. The dialkyl 1-acryloyloxy-2-alkenyl-1phosphonates and the dialkyl 1-methacryloyloxy-2-alkenyl-1phosphonates produced are novel compounds. They are useful as flame retardant and cross-linking comonomers in the preparation of self-extinguishing and/or flame retardant polymers. They also can be homopolymerized to give novel phosphorus containing, selfextinguishing polymers.

Abstract translation: 1-丙烯酰氧基-2-烯基-1-膦酸二烷基酯和1-甲基丙烯酰氧基-2-烯基-1-膦酸二烷基酯是通过1-羟基-2-烯丙基-2-链烯基-1-膦酸二烷基酯与丙烯酰基或甲基丙烯酰氯在 存在碱，优选使用惰性有机溶剂。 所生产的1-丙烯酰氧基-2-烯基-1-膦酸二烷基酯和1-甲基丙烯酰氧基-2-链烯基-1-膦酸二烷基酯是新化合物。 它们在制备自熄性和/或阻燃聚合物时可用作阻燃和交联共聚单体。 它们也可以均聚，得到新的含磷的自熄性聚合物。

公开(公告)号：US20230322983A1

公开(公告)日：2023-10-12

申请号：US17976526

申请日：2022-10-28

Applicant: SAMSUNG SDI CO., LTD.

Inventor： Jonggi KIM ,  Yonghee KANG ,  Kyunghee KANG ,  Jihyeon YIM ,  Bumjin LEE

IPC: C08K5/375 ,  C08K3/30 ,  C08K9/06 ,  C08F136/20

CPC classification number: C08F136/20 ,  C08K3/30 ,  C08K5/375 ,  C08K9/06

Abstract: A curable composition, a cured layer manufactured using the curable composition, a color filter including the cured layer, and a display device including the color filter, the curable composition including a quantum dot surface-modified with a first ligand and a second ligand having a structure different than the first ligand; and a polymerizable compound is provided. The first ligand is a silsesquioxane-based thiol ligand.

公开(公告)号：US20190210967A1

公开(公告)日：2019-07-11

申请号：US16299656

申请日：2019-03-12

Applicant: Novoset, LLC

Inventor： Sajal Das ,  Paul Boothe ,  Patrick Shipman ,  Scott Shuler

IPC: C07D209/76 ,  C08F299/00 ,  C08F236/22 ,  C08F12/34 ,  C08F110/14 ,  C08F32/06 ,  C08F136/20

CPC classification number: C07D209/76 ,  C08F12/34 ,  C08F32/06 ,  C08F110/14 ,  C08F136/20 ,  C08F236/22 ,  C08F299/00

Abstract: The present disclosure is directed to resins and to polymers, copolymers, and blends formed therefrom.