摘要:
The present invention provides a process for producing a difluoromethyl ether derivative simple and efficient process for producing the difluoromethyl ether derivative represented by Formula (1d′) or a difluoromethyl ether derivative represented by Formula (1c′): wherein all the variables are defined in the specification.
摘要:
The present invention provides a difluoromethyl ether derivative which shows various suitable physical properties as a liquid crystal compound, a liquid crystal composition comprising the compound and a liquid crystal display element containing the composition, and also provides a simple and efficient process for producing the difluoromethyl ether derivative. According to the present invention, a process for producing a difluoromethyl ether derivative represented by Formula (1d): wherein the variables are defined in the specification, is characterized by using an &agr;&agr;-difluorocyclohexylidene derivative represented by Formula (1a): wherein R1, rings A1 and A2, Z1, Z2, k and l have the same meanings as defined in the specification, as a starting material.
摘要:
A liquid crystalline compound represented by Formula (1c′): wherein R1 and R2, rings A1, A2, A3, A4 and A5, Z1, Z2, Z3 and Z4, Y1, Y2, Y3 and Y4, and k, l, m and n are as defined in the specification. Also provided is a liquid crystal composition containing at least one of these liquid crystalline compounds.
摘要:
Liquid crystalline compounds having a large negative Δε low viscosity, a large K33/K11 value, a small Δε/Δ⊥ and mutually excellent solubility even at low temperature, compositions containing at least one of the compounds and liquid crystal display devices containing such a liquid crystal compositions are disclosed.
摘要翻译:具有较大的负值Deltaepsilon低粘度,较大的K 33 / K 11值的小晶体化合物,即使在低温下也具有相当优异的溶解度,组成 含有至少一种化合物和含有这种液晶组合物的液晶显示装置。
摘要:
Liquid crystalline compounds having a large negative &Dgr;∈ low viscosity, a large K33/K11 value, a small &Dgr;∈/&Dgr;⊥ and mutually excellent solubility even at low temperature, compositions containing at least one of the compounds and liquid crystal display devices containing such a liquid crystal compositions are disclosed.
摘要:
There is provided a liquid crystalline compound having a high voltage holding ratio which has a very small degree of temperature dependence, a low threshold voltage which has a very small degree of temperature dependence, a high &Dgr;n, and excellent miscibility with other liquid crystal materials at low temperature; a liquid crystal composition; and a liquid crystal display element, and the liquid crystalline compound is a substituted benzene derivative represented by general formula (1), where, R represents a straight chain or branched alkyl group having 1 to 20 carbon atoms in which each of optional and nonadjacent methylene groups (—CH2—) may be substituted by an oxygen atom; X represents a halogen atom, —CF3, —CF2H, —CFH2, —OCF3 or —OCF2H; each of Z1 and Z2 independently represents —(CH2)2—, —(CH2)4—, —CH2O—, —OCH2— or a covalent bond, but Z1 and Z2 are not covalent bonds simultaneously; each of Y1, Y2, Y3, Y4, Y5, and Y6 independently represents H or F, but at least one of Y1, Y2, Y3, and Y4 represents F.
摘要:
The present invention provides liquid crystalline compounds having a high voltage holding ratio and a low threshold voltage, little variation of these properties with temperature change, high &Dgr;n, and good compatibility with other liquid crystal materials particularly under a low temperature; liquid crystal compositions containing these crystalline compounds; and liquid crystal display devices made using these liquid crystal compositions. The liquid crystalline compounds are terphenyl derivatives represented by general formula (1): wherein R represents a straight or branched alkyl group of 1-20 carbon atoms, and any methylene groups (—CH2—) not adjacent each other in each alkyl group may be replaced by oxygen atoms; X is a halogen atom, —OCF3, —OCF2H, —CF3, —CF2H or —CFH2; Y1, Y2, Y3, Y4, Y5 and Y6 independently represents H or F, but at least two of Y1, Y2, Y3 and Y4 represent F; and any atom constituting these compounds may be substituted by its isotope.
摘要:
The present invention provides a liquid crystalline compound having a difluoropropyleneoxy group as a bonding group, which is represented by Formula (1): wherein R1 and R2 each independently represent hydrogen, halogen, a cyano group or an alkyl group having 1 to 20 carbon atoms; rings A1 to A5 each independently represent a 1,4-cyclohexylene group, a 1,4-cyclohexenylene group or a 1,4-phenylene group; Z1 to Z4 each independently represent a single bond, —CH2CH2—, —CH2O—, —OCH2—, —COO—, —OCO—, —CH═CH—, —C≡C—, —CF2O— or —OCF2—; Y1, Y2, Y3 and Y4 each independently represent hydrogen or fluorine; and k, l, m and n each independently represent 0 or 1. This liquid crystalline compound has a large absolute value (|&Dgr;&egr;|) of a dielectric anisotropy and shows a relatively small refractive anisotropy. The present invention further provides a liquid crystal composition comprising this compound which makes it possible to drive display elements of various modes at a low voltage, and a liquid crystal display element containing this liquid crystal composition.
摘要:
Liquid crystalline compounds which exhibit a negative dielectric anisotropy value, have an extremely high voltage holding ratio and a low threshold voltage, are small in their dependency on temperature, hardly exhibit smectic phase, and are excellent in miscibility with other liquid crystal materials at the same time; liquid crystal compositions comprising the compound; and liquid crystal display devices fabricated by using the liquid crystal composition are provided; the liquid crystalline compounds being specific 3,3′-difluorobiphenyl derivatives expressed by the following general formula (1):
摘要:
Liquid crystalline compounds which have excellent compatibility with other liquid crystal materials, especially at low temperatures, high voltage holding ratio, low threshold voltage, their small temperature dependency, high .DELTA.n, and broad liquid phase temperature range, the compounds being represented by formula (1)Ra--A.sub.1 --Z.sub.1 --A.sub.2 --Z.sub.2 --(--A.sub.3 --Z.sub.3 --).sub.m --A.sub.0 --Rf (1)(wherein m is 0 or 1; A.sub.0, A.sub.1, A.sub.2 and A.sub.3 represent a six-membered ring, ring A.sub.0 is 1,4-phenylene which may be substituted with 1 to 3 of F and/or Cl, rings A.sub.1, A.sub.2 and A.sub.3, independently of one another, are selected from trans-1,4-cyclohexylene, 1,4-phenylene which may be substituted with one or more halogen atoms, cyclohexene-1,4-diyl or 1,3-dioxane-2,5-diyl; Z.sub.1, Z.sub.2 and Z.sub.3 represent a bridge between the rings and independently of one another, are selected from --(CH.sub.2).sub.2 --, --(CH.sub.2).sub.4 --, --CH.sub.2 O--, --OCH.sub.2 -- bonds, one or more hydrogen atoms in these bonds being optionally substituted with a halogen atom, or a single bond (--); Rf represents --OCF.sub.2 CF.sub.2 H or --OCF.sub.2 CFHCF.sub.3 ; and Ra is a straight- or branched monovalent organic radical of 1 to 20 carbons); liquid crystal compositions comprising at least one of the compounds; and liquid crystal display devices composed of the compositions.