公开(公告)号：US10468607B2

公开(公告)日：2019-11-05

申请号：US14237764

申请日：2012-08-02

申请人： Koji Takaku ,  Tetsu Kitamura ,  Wataru Sotoyama ,  Yasunori Yonekuta ,  Toru Watanabe ,  Toshihiro Ise ,  Saki Takada

发明人： Koji Takaku ,  Tetsu Kitamura ,  Wataru Sotoyama ,  Yasunori Yonekuta ,  Toru Watanabe ,  Toshihiro Ise ,  Saki Takada

IPC分类号： H01L51/00 ,  C07D403/04 ,  C07D405/04 ,  C07D471/04 ,  C07D487/04 ,  C07D491/052 ,  C07D491/16 ,  C07D209/86 ,  C07D209/88 ,  C09K11/06 ,  H05B33/10 ,  H01L51/50

摘要： An organic electroluminescent element including a substrate, a pair of electrodes including an anode and a cathode, disposed on the substrate, and at least one organic layer including a light emitting layer, disposed between the electrodes, in which the organic layer includes a compound represented by the following general formula (1), has high luminous efficiency, excellent blue color purity, and a small change in the chromaticity due to deterioration by driving, wherein Cy, Dn1, Ac1, L1, L2, L3, ring Z1, u1, q1, n1, m1, A11, and A12 are as defined herein.

公开(公告)号：US09876175B2

公开(公告)日：2018-01-23

申请号：US14239696

申请日：2012-08-06

申请人： Koji Takaku ,  Tetsu Kitamura ,  Toru Watanabe ,  Yosuke Yamamoto ,  Kimiatsu Nomura ,  Wataru Sotoyama ,  Saki Takada ,  Toshihiro Ise

发明人： Koji Takaku ,  Tetsu Kitamura ,  Toru Watanabe ,  Yosuke Yamamoto ,  Kimiatsu Nomura ,  Wataru Sotoyama ,  Saki Takada ,  Toshihiro Ise

IPC分类号： H01L51/00 ,  H05B33/14 ,  H01L51/50 ,  C07D209/56

CPC分类号： H01L51/0056 ,  C07D209/56 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1088 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/50 ,  H01L51/5012 ,  H05B33/14

摘要： An organic electroluminescent element including a substrate, a pair of electrodes including an anode and a cathode, disposed on the substrate, and at least one organic layer including a light emitting layer, disposed between the electrodes, in which a compound represented by the following formula (I) is contained in any layer of the at least one organic layer. The organic electroluminescent element has high luminous efficiency and a strong effect of improving the durability by driving aging: wherein X, A1, A2, A3, A4, and R1 to R8 are as defined herein.

公开(公告)号：US20140203252A1

公开(公告)日：2014-07-24

申请号：US14124851

申请日：2012-06-05

申请人： Tetsu Kitamura ,  Koji Takaku ,  Wataru Sotoyama ,  Yasunori Yonekuta ,  Toshihiro Ise ,  Saki Takada ,  Toru Watanabe

发明人： Tetsu Kitamura ,  Koji Takaku ,  Wataru Sotoyama ,  Yasunori Yonekuta ,  Toshihiro Ise ,  Saki Takada ,  Toru Watanabe

IPC分类号： H01L51/00 ,  H01L51/50

CPC分类号： H01L51/50 ,  C07D251/14 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  H01L51/0051 ,  H01L51/0054 ,  H01L51/0059 ,  H01L51/0061 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0081 ,  H01L51/0094 ,  H01L51/5012 ,  H01L51/5016 ,  H05B33/10

摘要： An organic electroluminescent element which has a substrate, a pair of electrodes disposed on this substrate and composed of an anode and a cathode, and at least one organic layer disposed between these electrodes and including a light-emitting layer, and in which a compound expressed by General Formula 1-1 is contained in at least one layer of the aforementioned light-emitting layer(s) exhibits high luminous efficiency, excellent blue color purity, and little change in chromaticity accompanying drive deterioration. (R1 to R10 [each] represent a hydrogen atom or a substituent, and at least one of R1 to R10 is a substituent expressed by General Formula 1-2; however, a pyrene skeleton is never contained in R1 to R10; the asterisk indicates the bonding position with a pyrene ring; X1 to X5 [each] represent a carbon atom or a nitrogen atom, and at least one of X1 to X5 is a nitrogen atom; R11 to R15 [each] represent a hydrogen atom or a substituent, and at least one of R11 to R15 is an alkyl group or a silyl group; however, if X1 to X5 represent nitrogen atoms, there is no R11 to R15 bonded on these nitrogen atoms.)

摘要翻译： 一种有机电致发光元件，其具有基板，一对电极，设置在该基板上，由阳极和阴极构成，以及至少一个有机层，设置在这些电极之间并且包括发光层，其中化合物表达 通式1-1包含在上述发光层的至少一层中，发光效率高，蓝色纯度优异，伴随着驱动劣化的色度变化小。 （R 1〜R 10各自表示氢原子或取代基，R 1〜R 10中的至少一个为通式1-2所示的取代基，但在R 1〜R 10中不含芘骨架，星号表示 与芘环的键合位置; X 1〜X 5各自表示碳原子或氮原子，X 1〜X 5中的至少一个为氮原子，R 11〜R 15为氢原子或取代基， 并且R 11〜R 15中的至少一个为烷基或甲硅烷基;但是，如果X 1〜X 5表示氮原子，则在这些氮原子上不存在R 11〜R 15键合。

公开(公告)号：US20120126691A1

公开(公告)日：2012-05-24

申请号：US13387913

申请日：2010-07-30

申请人： Toshihiro Ise ,  Tetsu Kitamura ,  Saki Takada ,  Toru Watanabe

发明人： Toshihiro Ise ,  Tetsu Kitamura ,  Saki Takada ,  Toru Watanabe

IPC分类号： H05B33/14 ,  B32B9/00

CPC分类号： H01L51/0072 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1044 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016 ,  H05B33/14

摘要： The organic electroluminescence device has, on a substrate thereof, a pair of electrodes and at least one organic layer including a light emitting layer between the electrodes, wherein the light emitting layer contains a phosphorescent complex material containing a specific monoanionic bidentate ligand and the device contains, in a layer sandwiched between the light emitting layer and a cathode, a compound represented by the following formula (1): (Cz)p-L-(A)q  (1) wherein, Cz represents a substituted or unsubstituted arylcarbazolyl or carbazolylaryl, L represents a single bond or a substituted or unsubstituted arylene, cycloalkylene, or aromatic heterocycle, A represents a substituted or unsubstituted nitrogen-containing 6-membered aromatic heterocycle, and each of p and q independently represents an integer from 1 to 6.

摘要翻译： 有机电致发光器件在其基板上具有一对电极和至少一个在电极之间包含发光层的有机层，其中发光层含有含有特定单阴离子二齿配体的磷光复合材料，该器件含有 在夹在发光层和阴极之间的层中，由下式（1）表示的化合物：（Cz）pL-（A）q（1）其中，Cz表示取代或未取代的芳基咔唑基或咔唑基芳基，L 表示单键或取代或未取代的亚芳基，亚环烷基或芳族杂环，A表示取代或未取代的含氮6元芳族杂环，p和q各自独立地表示1〜6的整数。

公开(公告)号：US20140246659A1

公开(公告)日：2014-09-04

申请号：US14239696

申请日：2012-08-06

申请人： Koji Takaku ,  Tetsu Kitamura ,  Toru Watanabe ,  Yosuke Yamamoto ,  Kimiatsu Nomura ,  Wataru Sotoyama ,  Saki Takada ,  Toshihiro Ise

发明人： Koji Takaku ,  Tetsu Kitamura ,  Toru Watanabe ,  Yosuke Yamamoto ,  Kimiatsu Nomura ,  Wataru Sotoyama ,  Saki Takada ,  Toshihiro Ise

IPC分类号： H01L51/00 ,  H01L51/50

CPC分类号： H01L51/0056 ,  C07D209/56 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1088 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/50 ,  H01L51/5012 ,  H05B33/14

摘要： An organic electroluminescent element including a substrate, a pair of electrodes including an anode and a cathode, disposed on the substrate, and at least one organic layer including a light emitting layer, disposed between the electrodes, in which a compound represented by the following formula (I) is contained in any layer of the at least one organic layer. The organic electroluminescent element has high luminous efficiency and a strong effect of improving the durability by driving aging: wherein X, A1, A2, A3, A4, and R1 to R8 are as defined herein.

摘要翻译： 一种有机电致发光元件，包括基板，一对电极，其包括阳极和阴极，设置在基板上，以及至少一个有机层，包括发光层，设置在电极之间，其中由下式表示的化合物 （I）包含在所述至少一个有机层的任何层中。 有机电致发光元件具有高发光效率和通过驱动老化提高耐久性的强烈效果：其中X，A1，A2，A3，A4和R1至R8如本文所定义。

公开(公告)号：US08609257B2

公开(公告)日：2013-12-17

申请号：US13387913

申请日：2010-07-30

申请人： Toshihiro Ise ,  Tetsu Kitamura ,  Saki Takada ,  Toru Watanabe

发明人： Toshihiro Ise ,  Tetsu Kitamura ,  Saki Takada ,  Toru Watanabe

IPC分类号： H01L51/54 ,  C09K11/06

CPC分类号： H01L51/0072 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1044 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016 ,  H05B33/14

摘要： The organic electroluminescence device has, on a substrate thereof, a pair of electrodes and at least one organic layer including a light emitting layer between the electrodes, wherein the light emitting layer contains a phosphorescent complex material containing a specific monoanionic bidentate ligand and the device contains, in a layer sandwiched between the light emitting layer and a cathode, a compound represented by the following formula (1): (Cz)p-L-(A)q  (1) wherein, Cz represents a substituted or unsubstituted arylcarbazolyl or carbazolylaryl, L represents a single bond or a substituted or unsubstituted arylene, cycloalkylene, or aromatic heterocycle, A represents a substituted or unsubstituted nitrogen-containing 6-membered aromatic heterocycle, and each of p and q independently represents an integer from 1 to 6.

摘要翻译： 有机电致发光器件在其基板上具有一对电极和至少一个在电极之间包含发光层的有机层，其中发光层含有含有特定单阴离子二齿配体的磷光复合材料，该器件含有 在夹在发光层和阴极之间的层中，由下式（1）表示的化合物：（Cz）pL-（A）q（1）其中，Cz表示取代或未取代的芳基咔唑基或咔唑基芳基，L 表示单键或取代或未取代的亚芳基，亚环烷基或芳族杂环，A表示取代或未取代的含氮6元芳族杂环，p和q各自独立地表示1〜6的整数。

公开(公告)号：US09691988B2

公开(公告)日：2017-06-27

申请号：US14238371

申请日：2012-08-06

申请人： Saki Takada ,  Yosuke Yamamoto ,  Toshihiro Ise ,  Tetsu Kitamura ,  Toru Watanabe ,  Wataru Sotoyama ,  Koji Takaku ,  Kimiatsu Nomura

发明人： Saki Takada ,  Yosuke Yamamoto ,  Toshihiro Ise ,  Tetsu Kitamura ,  Toru Watanabe ,  Wataru Sotoyama ,  Koji Takaku ,  Kimiatsu Nomura

IPC分类号： H01L51/54 ,  C09K11/06 ,  H01L51/00 ,  H05B33/14 ,  H01L51/50

CPC分类号： H01L51/0056 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1033 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0052 ,  H01L51/0061 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/5012 ,  H01L51/5024 ,  H05B33/14

摘要： An organic electroluminescent element using a compound represented by the following general formula emits dark blue light and has a small change in the chromaticity during luminance modulation: wherein each of R1 to R8 represents a hydrogen atom or a substituent; A1 to A4 represent CR31 or N; L and X each independently represent any one of CR32R33, NR34, O, S, and SiR35R36; and each of R31 to R36 represents a hydrogen atom or a substituent.

公开(公告)号：US20150053936A1

公开(公告)日：2015-02-26

申请号：US14237764

申请日：2012-08-02

申请人： Koji Takaku ,  Tetsu Kitamura ,  Wataru Sotoyama ,  Yasunori Yonekuta ,  Toru Watanabe ,  Toshihiro Ise ,  Saki Takada

发明人： Koji Takaku ,  Tetsu Kitamura ,  Wataru Sotoyama ,  Yasunori Yonekuta ,  Toru Watanabe ,  Toshihiro Ise ,  Saki Takada

IPC分类号： H01L51/00

摘要： An organic electroluminescent element including a substrate, a pair of electrodes including an anode and a cathode, disposed on the substrate, and at least one organic layer including a light emitting layer, disposed between the electrodes, in which the organic layer includes a compound represented by the following general formula (1), has high luminous efficiency, excellent blue color purity, and a small change in the chromaticity due to deterioration by driving, wherein Cy, Dn1, Ac1, L1, L2, L3, ring Z1, u1, q1, n1, m1, A11, and A12 are as defined herein.

摘要翻译： 一种有机电致发光元件，包括基板，一对包括阳极和阴极的电极，设置在基板上，以及至少一个包括发光层的有机层，设置在电极之间，其中有机层包括表示的化合物 通过以下通式（1），具有高发光效率，优异的蓝色纯度，以及由于驱动劣化引起的色度变化小，其中Cy，Dn1，Ac1，L1，L2，L3，环Z1， q1，n1，m1，A11和A12如本文所定义。

公开(公告)号：US20140159024A1

公开(公告)日：2014-06-12

申请号：US14124945

申请日：2012-06-05

申请人： Saki Takada ,  Yasunori Yonekuta ,  Toshihiro Ise ,  Tetsu Kitamura ,  Toru Watanabe ,  Wataru Sotoyama ,  Koji Takaku ,  Katsuyuki Youfu

发明人： Saki Takada ,  Yasunori Yonekuta ,  Toshihiro Ise ,  Tetsu Kitamura ,  Toru Watanabe ,  Wataru Sotoyama ,  Koji Takaku ,  Katsuyuki Youfu

IPC分类号： H01L51/00

CPC分类号： H01L51/0094 ,  C07C43/267 ,  C07C211/61 ,  C07C217/94 ,  C07C323/38 ,  C07C2601/14 ,  C07C2603/54 ,  C07D209/56 ,  C07D213/38 ,  C07D235/18 ,  C07D235/20 ,  C07D307/77 ,  C07D401/04 ,  C07D495/04 ,  C07F7/0805 ,  C07F7/0807 ,  C09B57/001 ,  C09B57/008 ,  C09B69/008 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01J29/20 ,  H01L51/0056 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0073 ,  H01L51/5012

摘要： An organic electroluminescent element that uses a compound expressed by the following general formula emits dark blue light and exhibits little change in chromaticity during brightness modulation. (n1 is an integer from 0 to 8; the R1 [groups] are each independently a substituent substituted for a hydrogen atom of the pyrene skeleton; X is CRaRb (Ra and Rb are each independently a hydrogen atom or a substituent), O, S, or SiRdRe (Rd and Re are each independently a hydrogen atom or a substituent); and A1 to A4 represent each independently either N or CRf (Rf represents a hydrogen atom or a substituent, and two adjacent Rf [groups] may jointly form a saturated or unsaturated ring, but no more than two rings may be formed jointly by two or more of the Rf [groups]).)

摘要翻译： 使用由以下通式表示的化合物的有机电致发光元件发出深蓝光，并且在亮度调制期间色度几乎没有变化。 （n1为0〜8的整数，R1 [基团]各自独立地为取代芘骨架的氢原子的取代基; X为CRaRb（Ra和Rb各自独立地为氢原子或取代基），O， S或SiRdRe（Rd和Re各自独立地为氢原子或取代基）; A1至A4各自独立地表示N或CRf（Rf表示氢原子或取代基，并且两个相邻的Rf [基团]可以共同形成 饱和或不饱和环，但不超过两个环可以由两个或更多个Rf [基团]共同形成）。

公开(公告)号：US09954190B2

公开(公告)日：2018-04-24

申请号：US14124945

申请日：2012-06-05

申请人： Saki Takada ,  Yasunori Yonekuta ,  Toshihiro Ise ,  Tetsu Kitamura ,  Toru Watanabe ,  Wataru Sotoyama ,  Koji Takaku ,  Katsuyuki Youfu

发明人： Saki Takada ,  Yasunori Yonekuta ,  Toshihiro Ise ,  Tetsu Kitamura ,  Toru Watanabe ,  Wataru Sotoyama ,  Koji Takaku ,  Katsuyuki Youfu

IPC分类号： H01L51/00 ,  C07D401/04 ,  C07D235/18 ,  C07D235/20 ,  C07D209/56 ,  C07D307/77 ,  C09K11/06 ,  H01J29/20 ,  H01L51/50 ,  C07C211/61 ,  C07C217/94 ,  C07C323/38 ,  C07D495/04 ,  C07F7/08 ,  C07D213/38 ,  C07C43/267 ,  C09B57/00 ,  C09B69/00

CPC分类号： H01L51/0094 ,  C07C43/267 ,  C07C211/61 ,  C07C217/94 ,  C07C323/38 ,  C07C2601/14 ,  C07C2603/54 ,  C07D209/56 ,  C07D213/38 ,  C07D235/18 ,  C07D235/20 ,  C07D307/77 ,  C07D401/04 ,  C07D495/04 ,  C07F7/0805 ,  C07F7/0807 ,  C09B57/001 ,  C09B57/008 ,  C09B69/008 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01J29/20 ,  H01L51/0056 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0073 ,  H01L51/5012

摘要： An organic electroluminescent element that uses a compound expressed by the following general formula emits dark blue light and exhibits little change in chromaticity during brightness modulation. (n1 is an integer from 0 to 8; the R1 [groups] are each independently a substituent substituted for a hydrogen atom of the pyrene skeleton; X is CRaRb (Ra and Rb are each independently a hydrogen atom or a substituent), O, S, or SiRdRe (Rd and Re are each independently a hydrogen atom or a substituent); and A1 to A4 represent each independently either N or CRf (Rf represents a hydrogen atom or a substituent, and two adjacent Rf [groups] may jointly form a saturated or unsaturated ring, but no more than two rings may be formed jointly by two or more of the Rf [groups]).)