公开(公告)号：US20100297443A1

公开(公告)日：2010-11-25

申请号：US12745389

申请日：2009-11-28

申请人： Toshio Kamisasa ,  Nobuo Ogata

发明人： Toshio Kamisasa ,  Nobuo Ogata

IPC分类号： D01F8/04 ,  D02J1/22 ,  D01D5/08 ,  D01F1/09

CPC分类号： D04H3/16 ,  D01D1/04 ,  D01D5/0023 ,  D01D5/30 ,  D01D10/00 ,  D04H1/728 ,  D04H3/00 ,  D04H3/005 ,  D04H3/016 ,  D04H3/147 ,  Y10T428/2929 ,  Y10T428/2931

摘要： An ultrafine composite fiber of the present invention is obtained by heating and melting a composite-resin-formed product in front of a supply-side electrode and/or in a space between electrodes and extending the composite-resin-formed product by electrospinning, wherein the composite-resin-formed product is a solid-state composite-resin-formed product having two or more phases and including a resin that has a volume specific resistance of 1015 Ω·cm or less, and that is exposed on 30% or more of a surface of the composite-resin-formed product. With this, an ultrafine composite synthetic fiber and an ultrafine synthetic fiber can be obtained by electrospinning, without a solvent being mixed in a supply resin, and further, a method for manufacturing an ultrafine composite fiber, as well as a fiber structure containing an ultrafine composite fiber, are provided.

摘要翻译： 本发明的超细复合纤维是通过在供给侧电极前面和/或电极之间的空间中加热熔融复合树脂成形品而通过静电纺丝延伸复合树脂成形体而得到的，其中， 复合树脂成形体是具有两相以上相的固态复合树脂成形体，具有体积电阻率为1015〜OHgr·cm以下的树脂，其暴露于30％以上 更多的复合树脂成型产品的表面。 由此，通过静电纺丝可以获得超细复合合成纤维和超细合成纤维，在供给树脂中没有混合溶剂，另外，超细复合纤维的制造方法以及含有超细复合纤维 复合纤维。

公开(公告)号：US20110177395A1

公开(公告)日：2011-07-21

申请号：US13062333

申请日：2009-09-04

申请人： Toshio Kamisasa

发明人： Toshio Kamisasa

IPC分类号： H01M2/16 ,  D04H13/00 ,  B32B5/02 ,  D01D5/12 ,  D01D5/08

CPC分类号： H01M2/162 ,  D01D5/0023 ,  D01D5/34 ,  D01D5/36 ,  D01F8/06 ,  D04H1/728 ,  D04H3/016 ,  D04H3/147 ,  H01M2/145 ,  H01M2/1673 ,  H01M4/13 ,  H01M4/139 ,  H01M4/661 ,  H01M10/0525 ,  Y02E60/122 ,  Y02P70/54 ,  Y10T428/2929 ,  Y10T428/2931 ,  Y10T442/637 ,  Y10T442/638 ,  Y10T442/64 ,  Y10T442/641

摘要： The present invention relates to a fiber assembly obtained by electrifying a resin in a melted state by application of voltage between a supply-side electrode and a collection-side electrode so as to extend the resin into an ultrafine composite fiber by electrospinning, and accumulating the ultrafine composite fiber, wherein the ultrafine composite fiber includes at least two polymeric components and the ultrafine composite fiber includes at least one type of composite fiber selected from a sea-island structure composite fiber and a core-sheath structure composite fiber as viewed in fiber cross section, at least one selected from an island component and a core component has a volume specific resistance of 1015Ω·cm or less, and at least one selected from a sea component and a sheath component has a volume specific resistance exceeding 1015Ω·cm. Thereby, the present invention provides a fiber assembly obtained by accumulating an ultrafine composite fiber obtained by electrospinning without the use of any solvent or water as a spinning solution, a composite of an electro conductive substrate and such a fiber assembly, and production methods thereof.

摘要翻译： 本发明涉及通过在供电侧电极和收集侧电极之间施加电压使熔融状态的树脂通电而获得的纤维集合体，以便通过静电纺丝将树脂延伸到超细复合纤维中，并且积聚 超细复合纤维，其中所述超细复合纤维包括至少两种聚合物组分，并且所述超细复合纤维包括选自海岛结构复合纤维和芯鞘结构复合纤维中的至少一种复合纤维，如纤维交叉 从岛成分和核成分中选出的至少一种体积电阻率为1015Ω·cm·cm以下，选自海成分和鞘成分中的至少一种体积电阻率超过1015Ω·cm·cm 。 因此，本发明提供一种通过将不经溶剂或水作为纺丝溶液静电纺丝得到的超细复合纤维，导电性基材与这种纤维集合体的复合体及其制造方法而获得的纤维集合体。

公开(公告)号：US08889573B2

公开(公告)日：2014-11-18

申请号：US13062333

申请日：2009-09-04

申请人： Toshio Kamisasa

发明人： Toshio Kamisasa

IPC分类号： D04H3/02 ,  D02G3/00 ,  D01D5/36 ,  H01M2/14 ,  H01M4/139 ,  H01M2/16 ,  H01M4/66 ,  H01M4/13 ,  D04H3/016 ,  D04H3/147 ,  D01D5/00 ,  D01D5/34 ,  D04H1/728 ,  D01F8/06 ,  H01M10/0525

CPC分类号： H01M2/162 ,  D01D5/0023 ,  D01D5/34 ,  D01D5/36 ,  D01F8/06 ,  D04H1/728 ,  D04H3/016 ,  D04H3/147 ,  H01M2/145 ,  H01M2/1673 ,  H01M4/13 ,  H01M4/139 ,  H01M4/661 ,  H01M10/0525 ,  Y02E60/122 ,  Y02P70/54 ,  Y10T428/2929 ,  Y10T428/2931 ,  Y10T442/637 ,  Y10T442/638 ,  Y10T442/64 ,  Y10T442/641

摘要： The present invention relates to a fiber assembly obtained by electrifying a resin in a melted state by application of voltage between a supply-side electrode and a collection-side electrode so as to extend the resin into an ultrafine composite fiber by electrospinning, and accumulating the ultrafine composite fiber, wherein the ultrafine composite fiber includes at least two polymeric components and the ultrafine composite fiber includes at least one type of composite fiber selected from a sea-island structure composite fiber and a core-sheath structure composite fiber as viewed in fiber cross section, at least one selected from an island component and a core component has a volume specific resistance of 1015Ω·cm or less, and at least one selected from a sea component and a sheath component has a volume specific resistance exceeding 1015Ω·cm. Thereby, the present invention provides a fiber assembly obtained by accumulating an ultrafine composite fiber obtained by electrospinning without the use of any solvent or water as a spinning solution, a composite of an electro conductive substrate and such a fiber assembly, and production methods thereof.

摘要翻译： 本发明涉及通过在供电侧电极和收集侧电极之间施加电压使熔融状态的树脂通电而获得的纤维集合体，以便通过静电纺丝将树脂延伸到超细复合纤维中，并且积聚 超细复合纤维，其中所述超细复合纤维包括至少两种聚合物组分，并且所述超细复合纤维包括选自海岛结构复合纤维和芯鞘结构复合纤维中的至少一种复合纤维，如纤维交叉 从岛成分和核成分中选出的至少一种体积电阻率为1015Ω·cm·cm以下，选自海成分和鞘成分中的至少一种体积电阻率超过1015Ω·cm·cm 。 因此，本发明提供一种通过将不经溶剂或水作为纺丝溶液静电纺丝得到的超细复合纤维，导电性基材与这种纤维集合体的复合体及其制造方法而获得的纤维集合体。

公开(公告)号：US20060154140A1

公开(公告)日：2006-07-13

申请号：US10532322

申请日：2003-10-23

申请人： Hiroyuki Yamamoto ,  Hitoshi Tateno ,  Toshio Kamisasa

发明人： Hiroyuki Yamamoto ,  Hitoshi Tateno ,  Toshio Kamisasa

IPC分类号： H01M2/16 ,  D04H13/00

CPC分类号： D21H13/16 ,  H01M2/162 ,  H01M2/1653 ,  H01M10/0566 ,  H01M2300/0025 ,  Y10T442/607

摘要： An organic electrolyte battery separator is composed of a nonwoven comprising a heat-and-humidity gelling resin capable of gelling by heating in the presence of moisture and another fiber. The other fiber is fixed with a gel material obtained by causing the heat-and-humidity gelling resin to gel under heat and humidity. The nonwoven has a mean flow pore diameter of 0.3 μm to 5 μm and a bubble point pore diameter of 3 μm to 20 μm as measured in accordance with ASTM F 316 86. Thereby, the other fiber constituting the nonwoven can be fixed with the heat-and-humidity gelling resin, thereby making it possible to obtain a desired mean flow pore diameter and bubble point pore diameter. As a result, an organic electrolyte battery having a high level of safety, less occurrence of a short circuit, high battery characteristics is provided.

摘要翻译： 有机电解质电池隔板由包含能够在水分和另一纤维的存在下通过加热而凝胶化的热湿胶凝树脂的无纺布构成。 另一种纤维用凝胶材料固定，其通过使热湿湿胶凝树脂在热和湿度下凝胶而获得。 根据ASTM F 316 86测量，非织造材料的平均流动孔径为0.3μm至5μm，气泡孔径为3μm至20μm。由此，构成非织造材料的其它纤维可以用热量固定 湿度的胶凝树脂，从而可以获得所需的平均流动孔径和起泡孔径。 结果，提供了具有高安全性，较少发生短路，高电池特性的有机电解质电池。

公开(公告)号：US20060147804A1

公开(公告)日：2006-07-06

申请号：US10541622

申请日：2004-01-23

申请人： Hiroyuki Yamamoto ,  Tatsunori Kida ,  Toshio Kamisasa

发明人： Hiroyuki Yamamoto ,  Tatsunori Kida ,  Toshio Kamisasa

IPC分类号： H01M2/16 ,  B32B27/08 ,  D04H1/54

CPC分类号： H01M2/162 ,  D04H1/54 ,  H01M10/24 ,  Y10T428/2964 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T442/692 ,  Y10T442/698

摘要： A separator material of the present invention is a sulfonated nonwoven that comprises a polyolefin ultra-fine short fiber having a fineness of less than 0.5 dtex and other polyolefin short fiber(s). The other polyolefin short fibers include a polyolefin thermal bonding short fiber. At least a portion of the polyolefin thermal bonding short fiber is flattened to bond the component fibers together. The nonwoven has a specific surface area in a range of 0.6 m2/g to 1.5 m2/g and satisfies the following ranges. (1) A ratio (S/C)E of the number of sulfur atoms (S) to the number of carbon atoms (C) in the nonwoven, as measured by Electron Spectroscopy for Chemical Analysis (ESCA), is in a range of 5×10−3 to 60×10−3. (2) A ratio (S/C)B of the number of sulfur atoms (S) to the number of carbon atoms (C) in the nonwoven, as measured by a flask combustion technique, is in a range of 2.5×10−3 to 7×10−3. (3) A ratio (S/C)E/(S/C)B (depth of sulfonation) of (S/C)E to (S/C)B is in a range of 1.5 to 12. Thus, a separator material that has a high level of self-discharging performance when charge and discharge are repeatedly performed, a high level of process performance when assembling a battery, and a high level of short-circuit withstand capability; a method of producing the same; and an alkali secondary battery separator, are provided.

摘要翻译： 本发明的隔膜材料是磺化非织造布，其包括细度小于0.5dtex的聚烯烃超细短纤维和其它聚烯烃短纤维。 其他聚烯烃短纤维包括聚烯烃热粘短纤维。 聚烯烃热粘短纤维的至少一部分变平，将组分纤维粘合在一起。 非织造布的比表面积为0.6m 2 / g〜1.5m 2 / g，满足以下范围。 （1）通过化学分析的电子光谱法（ESCA）测定的非织造物中硫原子数（S）与碳原子数（C）的比（S / C） ）在5×10 -3至60×10 -3 -3的范围内。 （2）通过烧瓶燃烧技术测定的非织造布中硫原子数（S）与碳原子数（C）之比（S / C）B B在 范围为2.5x10 -3至7×10 -3 -3。 （3）（S / C）的比例（S / C） /（S / C）B（磺化深度） >（S / C）B 在1.5〜12的范围内。因此，重复执行充放电时的自放电性能高的隔板材料，高水平 组装电池时的工艺性能，以及高水平的短路耐受能力; 其制造方法; 和碱性二次电池隔板。