公开(公告)号：US09079174B2

公开(公告)日：2015-07-14

申请号：US13723616

申请日：2012-12-21

申请人： Total Raffinage Marketing ,  IFP Energies Nouvelles

发明人： Laurent Simon ,  Bertrand Guichard ,  Gregory Lapisardi ,  Hugues Dulot ,  Valentina De Grandi ,  Delphine Minoux ,  Jean Pierre Dath

IPC分类号： C10G47/02 ,  C10G47/18 ,  C10G47/20 ,  B01J31/04 ,  B01J37/00 ,  B01J29/076 ,  B01J31/34 ,  B01J37/20 ,  B01J37/26 ,  B01J37/28 ,  B01J37/02 ,  B01J29/16 ,  B01J29/78 ,  B01J29/064 ,  B01J31/02 ,  B01J35/00 ,  B01J27/188 ,  B01J27/19

CPC分类号： B01J31/34 ,  B01J27/188 ,  B01J27/19 ,  B01J29/064 ,  B01J29/076 ,  B01J29/166 ,  B01J29/7815 ,  B01J31/0209 ,  B01J31/04 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/20 ,  B01J37/26 ,  B01J37/28 ,  B01J2229/42 ,  C10G47/20

摘要： The invention concerns a catalyst containing a support comprising at least one binder and at least one zeolite having at least one series of channels the opening of which is defined by a ring containing 12 oxygen atoms, said catalyst comprising phosphorus, at least one C1-C4 dialkyl succinate, acetic acid and a hydrodehydrogenating function comprising at least one element from group VI B and at least one element from group VIII, the Raman spectrum of the catalyst comprising bands at 990 and/or 974 cm-1, characteristic of at least one Keggin heteropolyanion, the characteristic bands of said succinate and the characteristic principal band of acetic acid at 896 cm-1. The invention also concerns the process for preparing the catalyst and its use in hydroconversion.

摘要翻译： 本发明涉及一种含有载体的催化剂，其包括至少一种粘合剂和至少一种沸石，该沸石具有至少一个通道，其开口由含有12个氧原子的环所限定，所述催化剂包含磷，至少一个C 1 -C 4 琥珀酸二烷基酯，乙酸和脱氢功能，其包含来自VIB族的至少一种元素和来自VIII族的至少一种元素，催化剂的拉曼光谱包括990和/或974cm -1处的带，其特征在于至少一种 Keggin杂多阴离子，所述琥珀酸的特征带和896cm-1乙酸的特征主带。 本发明还涉及制备催化剂的方法及其在加氢转化中的用途。