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公开(公告)号：US11498890B1
公开(公告)日：2022-11-15
申请号：US17770188
申请日：2020-10-26
发明人： Florent Dubray , Svetlana Mintova , Jean-Pierre Gilson , Stanislav Konnov , Stijn Van Daele , Nikolai Nesterenko
摘要： Process for the conversion of non-oxidative coupling of methane to ethylene, under non-oxidative conditions, comprising: providing a first stream containing at least 50 vol. % of methane based on the total volume of said first stream; providing a catalyst; putting in contact said first stream with said catalyst at a weight hour space velocity ranging from 0.5 to 100 h−1, a temperature ranging from 500° C. to 1100° C. and a pressure ranging from 0.1 MPa to 5 Mpa in the absence of oxygen; recovering a second stream containing unconverted methane if any, ethylene and hydrocarbons having at least 2 carbon atoms. Said process is remarkable in that said catalyst is a synthetic zeolite material, containing at least one metal M with silicon to metal M molar ratio Si/M as determined by inductively coupled plasma optical emission spectrometry ranging from 100 to 65440 and in that said metal M is incorporated inside of the zeolite tetrahedral sites.
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公开(公告)号：US11485643B1
公开(公告)日：2022-11-01
申请号：US17768590
申请日：2020-10-13
发明人： Cindy Aquino , Svetlana Mintova , Jean-Pierre Gilson , Florent Dubray , Delphine Minoux , Julien Grand , Nikolai Nesterenko
摘要： The present disclosure relates to a novel method for introducing various metals in the structure of zeolite frameworks by isomorphous substitution. This new method is based on a hydrothermal reaction of the metal with the zeolite. This method allows obtaining zeolite with a structure and with control of the metal location.
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公开(公告)号：US11655158B2
公开(公告)日：2023-05-23
申请号：US17768391
申请日：2020-10-13
发明人： Svetlana Mintova , Jean-Pierre Gilson , Nikolai Nesterenko , Delphine Minoux , Cindy Aquino , Julien Grand , Florent Dubray
IPC分类号： C01B39/48
CPC分类号： C01B39/48 , C01P2002/72 , C01P2002/82 , C01P2002/85 , C01P2002/86 , C01P2004/03 , C01P2004/04 , C01P2006/12 , C01P2006/14
摘要： The present disclosure relates to a novel staged-synthesis method for introduction of various metals in the structure of zeolite frameworks by isomorphous substitution. This new method is based on a hydrothermal synthesis in which the metal addition to the precursor suspensions (gel) is delayed. This so-called “staged-synthesis method” allows to obtain nanosized silanol highly homo-geneous crystalline zeolite structures with a control of the metal location.
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4.发明申请公开(公告)号：US20190168194A1
公开(公告)日：2019-06-06
申请号：US16269320
申请日：2019-02-06
发明人： Kok-Giap Haw , Jean-Michel Goupil , Jean-Pierre Gilson , Valentin Valtchev , Nikolai Nesterenko , Delphine Minoux , Jean-Pierre Dath
IPC分类号： B01J29/40 , B01J29/00 , B01J35/10 , B01J29/04 , B01J29/44 , B01J37/08 , C07C4/18 , B01J37/28 , B01J37/02 , B01J35/00 , B01J35/02 , B01J37/00 , C10G11/18 , C10G11/02 , C10G3/00 , C10G47/12 , C10G47/02 , C10G45/62 , C10G45/60 , C10G35/085 , C10G35/06 , C10G29/20 , C10G50/00
摘要： Catalyst compositions comprising an inorganic porous material with pore diameters of at least 2 nm and of crystals of molecular sieve, characterized in that the crystals of molecular sieve have an average diameter, measured by scanning electron microscopy, not bigger than 50 nm, and in that the catalyst composition presents a concentration of acid sites ranges from 50 to 1200 μmol/g measured by TPD NH3 adsorption; and the XRD pattern of said catalyst composition is the same as the X ray diffraction pattern of said inorganic porous material.
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5.发明授权公开(公告)号：US10239051B2
公开(公告)日：2019-03-26
申请号：US14902233
申请日：2014-07-03
发明人： Kok-Giap Haw , Jean-Michel Goupil , Jean-Pierre Gilson , Valentin Valtchev , Nikolai Nesterenko , Delphine Minoux , Jean-Pierre Dath
IPC分类号： B01J29/06 , B01J29/40 , B01J29/44 , B01J29/04 , B01J29/00 , B01J37/02 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/00 , C10G50/00 , C07C4/18 , C10G29/20 , C10G35/06 , C10G35/085 , C10G45/60 , C10G45/62 , C10G47/02 , C10G47/12 , C10G3/00 , C10G11/02 , C10G11/18 , B01J37/28 , B01J37/08
摘要： A catalyst composition contains an inorganic porous material with pore diameters of at least 2 nm and of crystals of molecular sieve. The crystals of molecular sieve have an average diameter, measured by scanning electron microscopy, not bigger than 50 nm. The catalyst composition has a concentration of acid sites ranges from 50 to 1200 μmol/g measured by TPD NH3 adsorption. An XRD pattern of the catalyst composition is the same as an XRD pattern of the inorganic porous material.
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6.发明授权公开(公告)号：US10894246B2
公开(公告)日：2021-01-19
申请号：US16269320
申请日：2019-02-06
发明人： Kok-Giap Haw , Jean-Michel Goupil , Jean-Pierre Gilson , Valentin Valtchev , Nikolai Nesterenko , Delphine Minoux , Jean-Pierre Dath
IPC分类号： B01J29/06 , B01J29/40 , B01J29/44 , B01J29/04 , B01J29/00 , B01J37/02 , C07C4/18 , C10G29/20 , C10G35/06 , C10G35/085 , C10G45/60 , C10G45/62 , C10G47/02 , C10G47/12 , C10G3/00 , C10G11/02 , C10G11/18 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/00 , C10G50/00 , B01J37/28 , B01J29/068 , B01J29/12 , B01J37/08
摘要： Catalyst compositions comprising an inorganic porous material with pore diameters of at least 2 nm and of crystals of molecular sieve, characterized in that the crystals of molecular sieve have an average diameter, measured by scanning electron microscopy, not bigger than 50 nm, and in that the catalyst composition presents a concentration of acid sites ranges from 50 to 1200 μmol/g measured by TPD NH3 adsorption; and the XRD pattern of said catalyst composition is the same as the X ray diffraction pattern of said inorganic porous material.
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