摘要:
A cement composition excelling in the slump retaining property which comprises at least cement admixture comprising as a main ingredient thereof (I) a copolymer (A) of short-chain polyalkylene glycol (meth)acrylate (a), a long-chain polyalkylene glycol (meth)acrylate (b), a carboxylic acid monomer (c), and a monomer copolymerizable with the monomers mentioned above or a salt of the copolymer (B), (II) a copolymer (A.sub.1) of the monomers (a), (c), and (d) mentioned above or a salt thereof, (III) a mixture of a copolymer (A.sub.1) of the monomers (a), (c), and (d) mentioned above or a salt (B.sub.1) of thereof with a known cement admixture, or (IV) a polycarboxylic acid based polymer (A.sub.3) manifesting to a calcium sulfoaluminate based expansive additive an adsorption ratio of not less than 90% in 5 minutes at room temperature when added in an amount of 0.1% by weight as solids or a salt (B.sub.3) thereof, or (V) a mixture of said polycarboxylic acid polymer with a known cement dispersant; cement; and water.
摘要:
A method for the dispersion of cement, which comprises incorporating in a cement composition consisting at least of cement and water a cement dispersing agent formed of a polymer obtained by polymerizing a monomer component containing an alkoxy polyalkylene glycol mono(meth)acrylic ester monomer produced by the interesterification of an alkoxy polyalkylene glycol and a (meth)acrylic ester. A cement composition comprising the cement dispersing agent, cement and water.
摘要:
A cement dispersant having excellent ability to prevent slump loss and high water-reducing property which comprises a polycarboxylic acid type polymer having a specific molecular weight distribution, a method for the production thereof, and a cement composition using the dispersant are provided. The cement dispersant comprises as a main component thereof a polycarboxylic acid type polymer (A), having a weight average molecular weight in the range of 10,000 to 500,000 in terms of polyethylene glycol determined by gel permeation chromatography, and having a value determined by subtracting the peak top molecular weight from the weight average molecular weight in the range of 0 to 8,000.
摘要:
A cement dispersant having excellent ability to prevent slump loss and high water-reducing property which comprises a polycarboxylic acid type polymer having a specific molecular weight distribution, a method for the production thereof, and a cement composition using the dispersant are provided. The cement dispersant comprises as a main component thereof a polycarboxylic acid type polymer (A), having a weight average molecular weight in the range of 10,000 to 500,000 in terms of polyethylene glycol determined by gel permeation chromatography, and having a value determined by subtracting the peak top molecular weight from the weight average molecular weight in the range of 0 to 8,000.
摘要:
An admixture for modifying the fluidity of a cementitious mixture comprises a cement-dispersing agent which is an aqueous solution of polymer, in which solution an oxyalkylene-based defoaming agent is dissolved or dispersed in particles of no greater that 20 .mu.M diameter. The polymer is preferably a polymer which comprises units derived from unsaturated carboxylic acid monomer and the polymer is preferably prepared in the presence of the defoaming agent. Particular addition copolymers give particularly good results. The admixture permits good control of the fluidity of cementitious compositions and has extended shelf life.
摘要:
A cement dispersant having as a main component thereof at least one polymer selected from the group consisting of polymers obtained from (A) 0.1 to 100 mol % of a sulfonic acid type monomer represented by the formula I: ##STR1## wherein R stands for hydrogen atom or methyl group, X stands for hydrogen atom, a monovalent metallic atom, a divalent metallic atom, ammonium group, or an organic amine group, A and B independently stand for an alkylene group of 2 to 4 carbon atoms, m stands for 0 or an integer of the value of 1 to 100, and the alkylene oxide group of 2 to 4 carbon atoms in the portion, (AO).sub.m may be bound in any desired sequence, and (B) 99.9 to 0 mol % of other monomer copolymerizable with said sulfonic acid type monomer, and polymers obtained by neutralizing said polymers with an alkaline substance, a cement composition containing the dispersant and a method for dispersing a cement.
摘要:
A cement dispersant having as a main component thereof at least one polymer selected from the group consisting of polymers obtained from (A) 0.1 to 100 mol % of a sulfonic acid type monomer represented by the formula I: ##STR1## wherein R stands for hydrogen atom or methyl group, X stands for hydrogen atom, a monovalent metallic atom, a divalent metallic atom, ammonium group, or an organic amine group, A and B independently stand for an alkylene group of 2 to 4 carbon atoms, m stands for 0 or an integer of the value of 1 to 100, and the alkylene oxide group of 2 to 4 carbon atoms in the portion, (AO).sub.m may be bound in any desired sequence, and (B) 99.9 to 0 mol % of olther monomer copolymerizable with said sulfonic acid type monomer, and polymers obtained by neutralizing said polymers with an alkaline substance, a cement composition containing the dispersant and a method for dispersing a cement.
摘要:
A cement dispersant containing a water-soluble polymer containing at least 10 mol % of structural units represented by the general formula I: ##STR1## wherein X is H or CH.sub.2 R.sup.1, R.sup.1 is H or COO--[--A).sub.m B).sub.n ]H, R is H, CH.sub.3, or COO--[--A).sub.m B).sub.n ]H (providing that R is H where X is CH.sub.2 R.sup.1), A is iminoalkylene having 2 to 4 carbon atoms, B is oxyalkylene having 2 to 4 carbon atoms, m is an average number in the range of 0.1 to 10, n is O or an average positive number not more than 100, --A).sub.m may be in a linear or branched configuration, wherein the sequence of A and B in the segment in parenthesis may be regular or random.
摘要:
An ionic compound is provided that has an anion represented by a: formula (1) and a cation represented by a formula (2): where X is an element selected from the group consisting of B, C, N, O, Al, Si, P, S, As, and Se, M1 and M2 are identical or different, and represent linking groups, and, when multiple M1s or multiple M2s are present, they may be identical or different, Q represents a monovalent element or organic group, a represents an integer of 1 or more, and b, c, d, and a each represent an integer of 0 or more; and RS-LH⊕(2) where L is an element selected from the group consisting of C, Si, N, P, S, and 0, R represents a monovalent element, functional group, or organic group, and s represents an integer of 2 to 4.
摘要:
The invention provides biodegradable crosslinked polymers, which have a chelating effect and a dispersing effect to disperse an oily substance and an inorganic substance hardly soluble in water and are excellent in dispersion into water. The crosslinked polymers comprise; an ingredient of molecular weight 5,000 or less in 50% by weight, a bond having at least one of a group (II) represented by the chemical formula --CO--O-- and a group (III) represented by the chemical formula --CO--NH-- as a composition unit between main chains having a water-soluble oligomer structure having the functional group (I) represented by the general formula --COOM (here, M denotes anyone of a hydrogen atom, monovalent metal, divalent metal, trivalent metal, an ammonium group and organic amine group.), and showing a viscosity of 1,000 cP or less at 20.degree. C. by a 20% by weight aqueous solution of the crosslinked polymer.