摘要:
There is provided a secondary cell having a positive electrode and a negative electrode which is made of solid active materials and an electrolyte layer which has been intervened between the positive electrode and the negative electrode. At least one of solid active materials for constituting the positive electrode and the negative electrode is composed of a mixed oxygen ion and electron conductor capable of inserting and eliminating oxygen ion or absorbing and releasing oxygen.
摘要:
The present invention provides a secondary battery which is less expensive, whose safety is extremely high, which is of large capacity as well as good cyclic characteristic, and which uses an aqueous solution for the electrolytic solution. A lithium secondary battery according to the present invention is constituted by including a positive electrode, formed by binding a positive-electrode raw-material mixture including a positive electrode active material, a negative electrode, formed by binding a negative-electrode raw-material mixture including a negative electrode active material, and an electrolytic solution, comprising an aqueous solution in which a lithium salt is dissolved, said positive electrode active material including at least one of a layered structure lithium-manganese composite oxide whose basic composition is LiMnO2 and an olivine structure lithium-iron composite phosphorus oxide whose basic composition is LiFePO4. The present lithium secondary battery can be used in the fields of communication appliances and information-related appliances, and as an electric source for electric automobiles and the like.
摘要:
The present invention is to provide a cathode active material for an alkaline battery with a lamellar crystal structure including nickel oxyhydroxide. The cathode active material has a diffraction peak at a position that ranges from 8.4 degrees to 10.4 degrees in diffraction angle 2θ by X-ray diffraction using CuKα-rays. In addition, the present invention provides an alkaline battery having a cathode having a cathode active material, an anode having an anode active material, and an alkaline water solution as an electrolytic solution. Furthermore, the present invention provides a manufacturing method for a cathode active material for an alkaline battery with a lamellar crystal structure including nickel oxyhydroxide. The manufacturing method has an oxidation process for manufacturing the cathode active material by oxidizing a starting material made from β-type nickel hydroxide with a lamellar crystal structure in an airstream including alkaline water solution or alkali.
摘要:
An alkaline storage battery 1 has: a cathode 2 containing β-type nickel hydroxide and/or β-type nickel oxyhydroxide as a cathode active material; an anode 3 containing an anode active material; and an alkaline aqueous solution as an electrolytic solution 4. The alkaline storage battery 1 is configured to restrain at least part of a crystal structure of the cathode active material from changing due to charging or discharging and to restrain the cathode active material from exhibiting a new diffraction peak at a position that ranges from 8.4 degrees to 10.4 degrees in X-ray diffraction angle 2θ by X-ray diffraction using CuKα-rays. It is preferable that an anion-exchange membrane layer 25 should be provided on a surface of the cathode 2.
摘要:
A battery characteristic detecting method according to the invention includes a first step in which constant current discharge from a battery is performed at a predetermined current value, and a voltage during constant current discharge is measured; a second step in which overpotential for mass transfer control in the battery or resistance for the mass transfer control in the battery is calculated based on the voltage measured in the first step; and a third step in which a determination that a characteristic change has occurred in the battery is made, when the overpotential for the mass transfer control in the battery or the resistance for the mass transfer control in the battery calculated in the second step is larger than a predetermined threshold value.
摘要:
One of the most important subject of the present invention is to provide a new lithium manganese composite oxide which does not include the cobalt which is few as the resource and expensive. For the above purpose, a lithium manganese composite oxide for a lithium secondary battery cathode active material represented by a composition formula of Li1−x Ax MnO2 (A is an alkali metal except for Li:0
摘要:
The present invention provides a water based lithium secondary battery that can inhibit deteriorations in capacity owing to charge-and-discharge operations and maintain a high capacity even after it is charged and discharged repeatedly. The water based lithium secondary battery includes a positive electrode, a negative electrode, a separator 4 sandwiched between these, and an aqueous electrolyte solution obtained by dissolving an electrolyte made of a lithium salt in a water based solvent. As the water based solvent, a pH buffer solution is employed. The buffer solution is obtained by dissolving an acid and its conjugate base's salt, a base and its conjugate acid's salt, a salt made from a weak acid and a strong base, a salt made from a weak base and a strong acid, or a salt made from a weak acid and a weak base in water.
摘要:
The present invention provides a water based lithium secondary battery that can inhibit deteriorations in capacity owing to charge-and-discharge operations and maintain a high capacity even after it is charged and discharged repeatedly. The water based lithium secondary battery includes a positive electrode, a negative electrode, a separator sandwiched between these, and an aqueous electrolyte solution obtained by dissolving an electrolyte made of a lithium salt in a water based solvent. As the water based solvent, a pH buffer solution is employed. The buffer solution is obtained by dissolving an acid and its conjugate base's salt, a base and its conjugate acid's salt, a salt made from a weak acid and a strong base, a salt made from a weak base and a strong acid, or a salt made from a weak acid and a weak base in water.
摘要:
A catalyst for purifying exhaust gases includes a porous support; a cerium oxide or a solid solution of a cerium oxide and a zirconium oxide in a state of mutual solid solution, loaded on the porous support; and a noble metal element loaded on the porous support. The cerium oxide or the solid solution has an average particle diameter of from 5 to 100 nm. The cerium oxide is present in the solid solution in an amount of from 0.2 to 4.0 by molar ratio with respect to the zirconium oxide therein. The catalyst can be prepared by: coating and calcinating on a support substrate a slurry of a cerium oxide sol, a cerium oxide sol and a zirconium oxide sol, on a solid solution powder of a cerium oxide and a zirconium oxide in a state of mutual solid solution; and loading a noble metal element thereon. The cerium oxide or its solid solution has a surface area large enough to effect an oxygen storage function, and has an average particle diameter large enough to prevent the same from entering deeply into fine pores of a porous support, thereby providing a catalyst fully exhibiting both of the oxygen storage capability and the catalytic activity.
摘要:
A sintered body composed of .alpha.'-silicon nitride and .beta.'-silicon nitride, and having a surface portion which contains a greater proportion of .alpha.'-silicon nitride than its inner portion does. It has high strength and excellent wear resistance. It is produced by preparing a molded body from a sintering material, disposing about the molded body a sintering material which can form a sintered product containing a greater proportion of .alpha.'-silicon nitride than the sintered product of the molded body will, and sintering the molded body and the material disposed about it.