公开(公告)号：US09825287B2

公开(公告)日：2017-11-21

申请号：US14744433

申请日：2015-06-19

申请人： UChicago Argonne, LLC

发明人： Zonghai Chen ,  Khalil Amine ,  Ilias Belharouak

IPC分类号： H01M4/36 ,  H01M4/62 ,  H01M4/60 ,  H01M4/13 ,  H01M4/485 ,  H01M4/04 ,  H01M4/139 ,  H01M10/052 ,  H01M10/0567 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/505 ,  H01M10/0525

CPC分类号： H01M4/366 ,  H01M4/0416 ,  H01M4/0421 ,  H01M4/13 ,  H01M4/131 ,  H01M4/139 ,  H01M4/1391 ,  H01M4/485 ,  H01M4/505 ,  H01M4/604 ,  H01M4/62 ,  H01M4/623 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011 ,  Y10T29/49115

摘要： An active material for an electrochemical device wherein a surface of the active material is modified by a surface modification agent, wherein the surface modification agent is an organometallic compound.

公开(公告)号：US20240105908A1

公开(公告)日：2024-03-28

申请号：US17952583

申请日：2022-09-26

申请人： UCHICAGO ARGONNE, LLC

发明人： Zonghai Chen ,  Yingying Xie

IPC分类号： H01M4/04 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525

CPC分类号： H01M4/0471 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/028

摘要： A process for modifying a surface chemistry of a cathode active material includes providing a powder of the cathode active material, wetting the powder of cathode active material with an efficient amount of a solution to form a mixture, and baking the mixture to obtain a surface modified cathode active material, wherein: the cathode active material has a formula of LiNixMnyCo1-x-yO2, wherein 0≤x≤1, 0≤y≤1, and 0≤x+y≤1; the solution comprises a solvate and a solvent; and the solvate comprises H3BO3, H3PO4, a phosphate salt, a hydrogenphosphate salt, a dihydrogenphosphate salt, or a combination of any two or more thereof.

公开(公告)号：US20190319299A1

公开(公告)日：2019-10-17

申请号：US15955394

申请日：2018-04-17

申请人： UChicago Argonne, LLC

发明人： Khalil Amine ,  Chi Cheung Su ,  Meinan He ,  Zonghai Chen

IPC分类号： H01M10/0525 ,  H01M10/04 ,  H01M10/0565 ,  H01M10/0569

摘要： A lithium ion battery includes a cathode having a voltage of greater than 4.1 V v. Li/Li+ and an aluminum or stainless steel current collector; an anode; a separator; and an electrolyte that includes a first salt that is a lithium sulfonylimide, a lithium sulfonate, or a mixture of any two or more thereof, and the first salt is present in the electrolyte from about 0.1 M to about 2 M; an aprotic solvent; and a second salt which suppresses corrosion of the aluminum or stainless steel current collector.

公开(公告)号：US20190006662A1

公开(公告)日：2019-01-03

申请号：US15640100

申请日：2017-06-30

申请人： UChicago Argonne, LLC

发明人： Khalil Amine ,  Xiaoqiao Zeng ,  Zonghai Chen ,  Filippo Maglia

IPC分类号： H01M4/36 ,  H01M10/0525 ,  H01M4/505 ,  H01M4/525 ,  H01M4/48 ,  H01M4/131 ,  H01M4/62 ,  H01M4/04

摘要： An active cathode material containing particles with a core containing a lithium transition metal oxide, each core at least partially encapsulated by a layer including the lithium transition metal oxide and dopant cation; and an outer layer containing metal oxide; wherein the dopant cation is selected from the group consisting of Al, Ti, Sn, Mg, Zr, Cu, Fe, Ca, W, Ga, Sc, Y, La, Hf, V, In, Nb, Ta, and any combination of two or more thereof; and the dopant cation is present in an amount of 10 wt. % or less of the particle.

公开(公告)号：US20150287987A1

公开(公告)日：2015-10-08

申请号：US14744433

申请日：2015-06-19

申请人： UChicago Argonne, LLC

发明人： Zonghai Chen ,  Khalil Amine ,  Ilias Belharouak

IPC分类号： H01M4/36 ,  H01M4/62 ,  H01M4/60 ,  H01M4/13 ,  H01M4/485

CPC分类号： H01M4/366 ,  H01M4/0416 ,  H01M4/0421 ,  H01M4/13 ,  H01M4/131 ,  H01M4/139 ,  H01M4/1391 ,  H01M4/485 ,  H01M4/505 ,  H01M4/604 ,  H01M4/62 ,  H01M4/623 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0567 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011 ,  Y10T29/49115

摘要： An active material for an electrochemical device wherein a surface of the active material is modified by a surface modification agent, wherein the surface modification agent is an organometallic compound.

摘要翻译： 一种用于电化学装置的活性材料，其中活性材料的表面被表面改性剂改性，其中表面改性剂是有机金属化合物。

公开(公告)号：US20130273441A1

公开(公告)日：2013-10-17

申请号：US13912390

申请日：2013-06-07

申请人： Uchicago Argonne, LLC

发明人： Zonghai Chen ,  Khalil Amine

IPC分类号： H01M10/056 ,  H01M12/06

CPC分类号： H01M10/056 ,  H01M4/382 ,  H01M4/90 ,  H01M10/0525 ,  H01M10/0565 ,  H01M12/06 ,  H01M12/08 ,  H01M2300/0025 ,  H01M2300/0085 ,  Y02E60/128 ,  Y02E60/50 ,  Y02T10/7011

摘要： Lithium-air cells employing poly(ethyleneoxide) phosphate-based electrolytes may be prepared and exhibit improved charge carrying capacity. Such PEO phosphates generally have the formulas IIa, IIb, IIc, where:

摘要翻译： 可以制备使用聚（环氧乙烷）磷酸盐基电解质的锂空气电池，并显示出改进的电荷承载能力。 这种PEO磷酸盐通常具有式IIa，IIb，IIc，其中：

公开(公告)号：US12021226B2

公开(公告)日：2024-06-25

申请号：US15640100

申请日：2017-06-30

申请人： UChicago Argonne, LLC ,  Bayerische Motoren Werke Aktiengesellschaft

发明人： Khalil Amine ,  Xiaoqiao Zeng ,  Zonghai Chen ,  Filippo Maglia

IPC分类号： H01M4/36 ,  H01M4/02 ,  H01M4/04 ,  H01M4/131 ,  H01M4/48 ,  H01M4/505 ,  H01M4/525 ,  H01M4/62 ,  H01M10/0525

CPC分类号： H01M4/366 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/483 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/028 ,  H01M4/625

摘要： An active cathode material containing particles with a core containing a lithium transition metal oxide, each core at least partially encapsulated by a layer including the lithium transition metal oxide and dopant cation; and an outer layer containing metal oxide; wherein the dopant cation is selected from the group consisting of Al, Ti, Sn, Mg, Zr, Cu, Fe, Ca, W, Ga, Sc, Y, La, Hf, V, In, Nb, Ta, and any combination of two or more thereof; and the dopant cation is present in an amount of 10 wt. % or less of the particle.

公开(公告)号：US20210210795A1

公开(公告)日：2021-07-08

申请号：US17205099

申请日：2021-03-18

申请人： UCHICAGO ARGONNE, LLC

发明人： Daniel R. Vissers ,  Khalil Amine ,  Zonghai Chen ,  Ujjal Das

IPC分类号： H01M10/42 ,  H01M4/62 ,  H01M4/36 ,  H01M50/449 ,  H01M4/04 ,  H01M10/0525 ,  H01M10/054

摘要： A lithium or sodium battery includes a cathode containing manganese; an anode containing an active anode material; a separator; an electrolyte; and a transition metal ion sequestration agent; wherein the transition metal ion sequestration agent contains a micron or nano-sized inorganic compound and the transition metal ion sequestration agent is located at the anode, in the electrolyte, or any combination thereof.

公开(公告)号：US20200099099A1

公开(公告)日：2020-03-26

申请号：US16137037

申请日：2018-09-20

申请人： UChicago Argonne, LLC

发明人： Khalil Amine ,  Chi Cheung Su ,  Meinan He ,  Zonghai Chen

IPC分类号： H01M10/0567 ,  H01M10/42 ,  H01M10/0568 ,  H01M4/38 ,  H01M10/0569 ,  H01M10/0565 ,  H01M10/052

摘要： An electrochemical cell includes a cathode comprising a cathode active material; an anode comprising lithium metal (Li0); a separator; and an electrolyte comprising a lithium salt, an organic aprotic solvent, and a difluoroethylene carbonate which is: or a mixture of any two or more thereof.

公开(公告)号：US10601077B2

公开(公告)日：2020-03-24

申请号：US15280867

申请日：2016-09-29

申请人： UChicago Argonne, LLC

发明人： Gui-Liang Xu ,  Zonghai Chen ,  Khalil Amine

IPC分类号： H01M10/0569 ,  H01M4/38 ,  H01M10/054 ,  H01M4/62 ,  H01M4/139 ,  H01M4/13 ,  H01M10/052 ,  H01M4/02

摘要： An electrochemical device includes an anode, a separator, a cathode comprising a selenium-doped sulfur/carbon composite that includes a conductive carbon matrix and nano-sized selenium-doped sulfur particles of formula SxSey, where a ratio of x:y is from 2.5 to 1000, and an electrolyte comprising a salt and a non-aqueous fluorinated ether solvent.