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1.发明授权Tetraacetonitrilolithiumhexafluorophosphate and method for the preparation thereof 失效四氢十六烷基六氟磷酸盐及其制备方法
公开(公告)号：US3594402A
公开(公告)日：1971-07-20
申请号：US3594402D
申请日：1969-05-29
发明人： WIESBOECK ROBERT A
CPC分类号： C08G2/06 , C01D15/005 , C01G28/004 , C01P2002/72 , C01P2002/74 , C01P2006/34 , C01P2006/80 , C07F1/005 , C07F9/00 , C08F10/00 , C08G2/10 , C08F4/00
摘要： TETRAACETONIRILOLITHIUMHEXAFLUOROPHOSPHATE, A NEW COMPOUND PREPARED BY REACTING LITHIUM FLUORIDE AND PF5 OR PREVIOUSLY PREPARED LIPF6 WITH EXCESS CH3CN, IS DISCLOSED. TETRAACETIONITRILOLITHIUMHEXAFLUOROPHOSPHATE IS USEFUL FOR THE PRODUCTION OF HIGH PURITY EXCEPTIONALLY ACTIVE LIPF6 WHICH IS ALSO A NEW COMPOSITION OF MATTER. THE PREPARATIONS OF THESE NEW COMPOSITIONS ARE ALSO DISCLOSED.
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公开(公告)号：US3690821A
公开(公告)日：1972-09-12
申请号：US3690821D
申请日：1971-03-23
发明人： WIESBOECK ROBERT A
CPC分类号： C01B35/06
摘要： AN ANNHYDROUS OXO-SALT OF BORON OR BORIC OXIDE IS MIXED WITH AN ALKALI OR ALKALINE EARTH FLUOROSULFONATE AND HEATED, PREFERABLY IN THE RANGE OF ABOUT 100-200*C. TO EVOLVE BORON TRIFLUORIDE WICH IS RECOVERED AS PRODUCT.
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公开(公告)号：US3592594A
公开(公告)日：1971-07-13
申请号：US3592594D
申请日：1968-01-05
发明人： WIESBOECK ROBERT A
IPC分类号： C01B25/10
摘要： PHOSPHORYL FLUORIDE IS REACTED WITH SULFUR TRIOXIDE TO FORM A PHOSPHORYL FLUORIDE-SULFUR TRIOXIDE ADDUCT AND THE ADDUCT CAN BE SOLVOLYZED BY HYDROGEN FLUORIDE TO FORM PHOSPHORUS PENTAFLUORIDE AND SULFURIC ACID. THE PHOSPHORYL FLUORIDE-SULFUR TRIOXIDE ADDUCT IS A NEW COMPOUND IN THE FORM OF A COLORLESS LIQUID HAVING A LOWER VAPOR PRESSURE THAN ITS INDIVIDUAL COMPONENTS BY A FACTOR OF ABOUT 10.
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4.发明授权Method for the preparation of high purity, highly surface active LiAsF{HD 6 失效制备高纯度，高表面活性LiAsF（HD 6
公开(公告)号：US3907977A
公开(公告)日：1975-09-23
申请号：US46427274
申请日：1974-04-25
发明人： WIESBOECK ROBERT A
CPC分类号： C01G28/004 , C01D15/005 , C01P2002/72 , C01P2002/74 , C08G2/10
摘要： High purity, highly surface active LiAsF6 is prepared by warming a pure tetraacetonitrilolithium hexafluoroarsenate complex under temperature and pressure conditions sufficient to dissociate the complex and evolve all the CH3CN, said conditions being below that at which the LiAsF6 will dissociate.
摘要翻译： 高纯度，高表面活性的LiAsF6是通过在温度和压力条件下温热和纯化的四亚乙基三锂六氟砷酸盐络合物来制备的，该条件足以使络合物解离并释放所有CH 3 CN，所述条件低于LiAsF 6将离解的条件。
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5.发明授权Tetraacetonitrilolithium hexafluorophosphate tetraacetonitrilolithium hexafluoroarsenate and method for the preparation thereof 失效四氢十六烷基十六烷基四氢呋喃六氟硼酸十六烷基酯及其制备方法
公开(公告)号：US3654330A
公开(公告)日：1972-04-04
申请号：US3654330D
申请日：1970-05-01
发明人： WIESBOECK ROBERT A
CPC分类号： C08G2/06 , C01D15/005 , C08F10/00 , C08G2/10 , C08F4/00
摘要： TETRAACETONITRILOLITHIUM HEXAFLUOROPHOSPHATE AND TETRAACETONITRILOLITHIUM HEXAFLUOROARSENATE, NEW COMPOUNDS, AND THEIR PREPARATION FROM LITHIUM FLUOIDE AND PF5 OR PREVIOUSLY PREPARED LIPF6 WITH EXCESS CH3CN, AND LIASF6 WITH EXCESS CH3CN, RESPECTIVELY, ARE DISCLOSED. TETRAACETONITRILOLITHIUM HEXAFLUOROPHOSPHATE AND TETRAACETONITRILOLITHIUM HEXAFLUOROARSENATE ARE USEFUL FOR THE PRODUCTION OF HIGH PURITY EXCEPTIONALLY ACTIVE LIPF6 AND LIASF6. THE PREPARATIONS OF THESE NEW COMPOSITIONS ARE ALSO DISCLOSED.
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公开(公告)号：US3635673A
公开(公告)日：1972-01-18
申请号：US3635673D
申请日：1970-07-31
发明人： WIESBOECK ROBERT A
摘要： A method of producing boron trifluoride or phosphorus trifluoride using a metal fluorosulfonate fluoride, MF(FSO3), as the fluorinating agent is disclosed. Boric acid, H3BO3, and phosphorous acid, H3PO3, respectively, are employed as the boron or phosphorus source.
摘要翻译： 公开了使用氟化磺酸金属氟化物MF（FSO 3）作为氟化剂生产三氟化硼或三氟化磷的方法。 硼酸，H3BO3和亚磷酸，H3PO3分别用作硼或磷源。
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公开(公告)号：US3634034A
公开(公告)日：1972-01-11
申请号：US3634034D
申请日：1968-02-02
IPC分类号： C01B25/10
摘要： Phosphorus pentafluoride and fluorophosphoric acids are prepared from a fluoride salt, phosphoric acid or monofluorophosphoric acid, and sulfur trioxide by heating the mixture to evolve phosphorus pentafluoride and/or fluorophosphoric acid gases, and recovering the gases.
摘要翻译： 五氟化磷和氟磷酸由氟化物盐，磷酸或单氟磷酸和三氧化硫通过加热该混合物以产生五氟化磷和/或氟磷酸气体并回收气体制备。
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公开(公告)号：US3875292A
公开(公告)日：1975-04-01
申请号：US38375073
申请日：1973-07-30
CPC分类号： C01B25/00 , C01B25/10 , C01G28/007
摘要： Phosphorus pentafluoride and fluorophosphoric acids are prepared from a fluorine source selected from fluorosulfonate fluorides and mixtures of fluorides and fluorosulfonates and a phosphorus source selected from phosphoric acid and mono- or difluorophosphoric acid. By an analogous process, arsenic pentafluoride and fluoroarsenic acids are prepared by fluorinating an arsenic source selected from arsenic acid and monofluoroarsenic acid.
摘要翻译： 五氟化磷和氟磷酸由选自氟磺酸氟化物和氟化物和氟磺酸盐的混合物的氟源和选自磷酸和单氟或二氟磷酸的磷源制备。 通过类似的方法，通过氟化选自砷酸和一氟砷酸的砷源制备五氟化砷和氟代酸。
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公开(公告)号：US3584999A
公开(公告)日：1971-06-15
申请号：US3584999D
申请日：1968-01-16
发明人： WIESBOECK ROBERT A
IPC分类号： C01B25/10
摘要： PHOSPHORYL FLUORIDE IS REACTED WITH HYDROGEN FLUORIDE TO FORM PHOSPHORUS PENTAFLUORIDE AND HEXAFLUOROPHOSPHORIC ACID, AND THE HEXAFLUOROPHOSPHORIC ACID MAY BE REACTED WITH SULFUR TROXIDE, PYROSULFURIC ACID OR FLUOROSULFONIC ACID TO FORM ADDITIONAL PHOSPHORUS PENTAFLUORIDE. THE HEXAFLUOROPHOSPHORIC ACID FROM ANY SOURCE MAY BE REACTED WITH THE SULFUR TRIOXIDE AND/OR PYROSULFURIC ACID TO LIBERATE PHOSPHORUS PENTAFLUORIDE.
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公开(公告)号：US3579301A
公开(公告)日：1971-05-18
申请号：US3579301D
申请日：1968-06-28
IPC分类号： C01B25/24
CPC分类号： C01B25/24
摘要： TO REDUCE THE VISCOSITY OF CONDENSED PHOSPHORIC ACIDS SO THAT THEY CAN BE PUMPED OR OTHERWISE READILY HANDLED OR TREATED, THE F CONTENT OF THE ACIDS IS RAISED ABOVE TWO PERCENT AND PREFERABLY ABOVE FOUR PERCENT. THE FLUORINE MAY BE ADDED IN THE FORM OF A FLUORINE-CONTAINING COMPOUND, SUCH AS FLUOROPHOSPHORIC ACID, DIFFLUOROPHOSPHORIC ACID, HEXAFLUOROPHOSPHORIC ACID, HYDROGEN FLUORIDE, ETC. THE FLUORINE TREATMENT INHIBITS CRYSTALLIZATION OF THE ACID AND, IN THE CASE OF WET PROCESS PHOSPHORIC ACID CONTAINING SOLIDS, DISSOLVES SOLIDS IN THE ACIDS.
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