ZINC-BASED ALLOYS FOR STABLE AND HIGH-PERFORMANCE SEAWATER-BASED AQUEOUS BATTERIES

    公开(公告)号:US20220223856A1

    公开(公告)日:2022-07-14

    申请号:US17571976

    申请日:2022-01-10

    Inventor: Yang Yang

    Abstract: An alloy anode for a seawater based aqueous battery and a universal strategy for preparing anodes for use in seawater based aqueous batteries. Zn-M alloys (where M can be manganese or other transition metal) were prepared by co-electrodeposition in the presence of hydrogen bubble formation to produce a porous nanostructured alloy that can serve as an anode for a seawater based aqueous battery. Exemplary Zn—Mn alloy anodes achieved stability over thousands of cycles even under harsh electrochemical conditions, including testing in seawater-based aqueous electrolytes and using a high current density of 80 mA cm−2. The anode design strategy allows for the production of durable electrodes for aqueous batteries and other applications.

    HIGH-ENTROPY ALLOY FOR HIGH-PERFORMANCE DIRECT ETHANOL FUEL CELLS

    公开(公告)号:US20240014410A1

    公开(公告)日:2024-01-11

    申请号:US18219983

    申请日:2023-07-10

    CPC classification number: H01M4/925 H01M4/921 H01M8/1013

    Abstract: Described herein relates to a high-entropy alloy (hereinafter “HEA”) catalyst and a method of optimizing a catalytic reaction within an electrochemical cell. The HEA catalyst may be fabricated from the following which includes but is not limited to Platinum acetylacetonate, Palladium acetylacetonate, Iron acetylacetonate, Cobalt acetylacetonate, Nickel acetylacetonate, Manganese acetylacetonate, Potassium, Ethanol, Perchloric Acid, Oleylamine, 1-Octadecene, and/or Cyclohexane. The HEA catalyst may provide a substantially decreased polarization overpotential and active energy barrier for the electrochemical cell. In addition, the HEA catalyst may operate stably at a constant working voltage for a substantial period of time, with a negligible performance decay of the output density, whether using O2 and/or air as cathode feeding. As such, the HEA catalyst may be used with the electrochemical cell to replace a H2—O2 fuel cell, since the HEA catalyst provides similar power density with long-term operating, solving the storage and transportation problems of H2.

    Self-standing tin sulfide film for flexible batteries

    公开(公告)号:US11177473B2

    公开(公告)日:2021-11-16

    申请号:US15929608

    申请日:2020-05-12

    Inventor: Yang Yang

    Abstract: High-performance flexible batteries are promising energy storage devices for portable and wearable electronics. The major obstacle to develop flexible batteries is the shortage of flexible electrodes with excellent electrochemical performance. Another challenge is the limited progress in the flexible batteries beyond Li-ion because of safety concerns for the Li-based electrochemical system. Accordingly, a self-supported tin sulfide (SnS) porous film (PF) was fabricated as a flexible cathode material in Al-ion battery, which delivers a high specific capacity of 406 mAh/g. A capacity decay rate of 0.03% per cycle was achieved, indicating a good stability. The self-supported and flexible SnS film also shows an outstanding electrochemical performance and stability during dynamic and static bending tests. Microscopic images demonstrated that the porous structure of SnS is beneficial for minimizing the volume expansion during charge/discharge. This leads to an improved structural stability and superior long-term cyclability.

    COMPOSITION OF AND METHOD FOR OPTIMIZING A CATALYTIC REACTION

    公开(公告)号:US20230061520A1

    公开(公告)日:2023-03-02

    申请号:US17830816

    申请日:2022-06-02

    Abstract: Described, herein, relates to a fluorinated electrocatalyst and a method of optimizing a catalytic reaction within an electrochemical cell, in which fluorine atoms may be introduced to the local coordination environment sites to weaken the carbon-nonmetal bonds and drive the nonmetallic chemical elements towards metallic chemical elements. The method may include introducing fluorine atoms to the metal-nonmetal-carbon catalysts to occupy the LCE site within the catalysts in order prevent the nonmetallic chemical elements from occupying the LCE sites, thereby driving the nonmetallic chemical element to form a nonmetallic chemical element layer on a surface of the metallic chemical elements. The nonmetallic chemical element layer may also inhibit the agglomeration and migration of the metallic chemical elements about the LCE site, optimizing catalyst activity through the regulation of the LCE site. The resulting fluorine-doped high-performance catalysts may be usable within electrochemical cells, with long-term stability and reduced degradation.

    Liquid metal buffer layer for lithium batteries

    公开(公告)号:US11522195B2

    公开(公告)日:2022-12-06

    申请号:US16746398

    申请日:2020-01-17

    Abstract: Enabling the use of lithium metal as an anode electrode is a key for developing next generation energy storage device beyond current lithium ion battery technology. However, there are major obstacles that need to be overcome before it can be used in commercial applications; specifically, dendrite formation can short the cell, and electrolyte decomposition contributes to decreased battery lifetimes. Each obstacle can be overcome by coating a lithium metal anode with a liquid metal buffer that enables uniform deposition of lithium ions thereon, preventing dendritic growth and forming a stable solid electrolyte interface to separate the lithium metal anode from the electrolyte within a battery cell. The liquid metal buffer becomes a semi-liquid buffer when contributing to forming a solid electrolyte interface, and can regain its liquid state when the lithium ions flow to the cathode of the battery cell.

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