公开(公告)号：US06296797B1

公开(公告)日：2001-10-02

申请号：US09509599

申请日：2000-05-22

申请人： Ursula Ziegler ,  Klaus Kurz ,  Frank Reil

发明人： Ursula Ziegler ,  Klaus Kurz ,  Frank Reil

IPC分类号： B28B722

CPC分类号： B29C45/1676 ,  B29K2059/00 ,  B60R13/04

摘要： Process for producing a composite article from a polyacetal (component a) with directly molded-on functional elements made from one or more thermoplastic elastomers (component b), and wherein components a and b have differing hardness, and the material with the greater hardness (component a) is initially premolded in a first step in a mold, and then is either cooled and removed from the mold and then placed into another, larger cavity, or is partially removed from the mold, but remains in a portion of the mold, and is then moved to a larger cavity, or, without removal from the mold, remains in the same mold, which is enlarged by means of a movable device, and in a second step, by overmolding with the material with the lesser hardness (component b), the molding formed from component a is firmly bonded to this material and is then removed from the mold as a composite article.

摘要翻译： 由聚缩醛（组分a）和由一种或多种热塑性弹性体（组分b）制成的直接成型的功能元件制备复合制品的方法，其中组分a和b具有不同的硬度，以及硬度较高的材料 组件a）最初在模具中的第一步骤中预成型，然后被冷却并从模具中取出，然后被放置到另一个更大的空腔中，或者部分地从模具中移除，但是保留在模具的一部分中， 然后移动到更大的空腔，或者不从模具中取出，保持在相同的模具中，该模具通过可移动装置而被扩大，并且在第二步骤中，通过用较低硬度的材料（部件 b），由组分a形成的模制品牢固地粘合到该材料上，然后作为复合制品从模具中取出。

公开(公告)号：US20080029934A1

公开(公告)日：2008-02-07

申请号：US11846964

申请日：2007-08-29

申请人： Ursula Ziegler ,  Klaus Kurz ,  Frank Reil ,  Fritz Schmidt ,  Rudi Herbst

发明人： Ursula Ziegler ,  Klaus Kurz ,  Frank Reil ,  Fritz Schmidt ,  Rudi Herbst

IPC分类号： B29C45/03

CPC分类号： B32B25/08 ,  B29C45/16 ,  B29C45/1676 ,  B29K2059/00 ,  B29K2221/003 ,  B32B7/12 ,  B32B27/28 ,  B32B27/42 ,  B32B37/12 ,  B32B2037/243 ,  B32B2309/02 ,  C08J5/12 ,  C08J7/047 ,  C08J2359/02 ,  C08J2453/00

摘要： A composite article made from polyacetal and from at least one modified styrene-olefin elastomer, which comprises from 15 to 70% by weight, based on the weight of the modified styrene-olefin elastomer, of non-olefinic thermoplastic material, and also a process for producing the same, where a molding made from polyacetal is firstly molded, onto which is then molded a coating or at least one molding made from the modified styrene-olefin elastomer, and an adhesive bond is formed between the polyacetal and the modified styrene-olefin elastomer.

摘要翻译： 由聚缩醛和至少一种改性的苯乙烯 - 烯烃弹性体制成的复合制品，其包含基于改性苯乙烯 - 烯烃弹性体的重量的15至70重量％的非烯烃热塑性材料，以及一种方法 首先将由聚缩醛制成的模制品成型，然后将其上模塑成型或由改性苯乙烯 - 烯烃弹性体制成的至少一种模制品，并且在聚缩醛和改性苯乙烯 - 烯烃弹性体。

公开(公告)号：US20070154727A1

公开(公告)日：2007-07-05

申请号：US10584745

申请日：2004-12-22

申请人： Ursula Ziegler ,  Frank Reil ,  Klaus Kurz

发明人： Ursula Ziegler ,  Frank Reil ,  Klaus Kurz

IPC分类号： B32B27/34

CPC分类号： B29C45/1676 ,  B29C45/1657 ,  B29C66/71 ,  B29C66/73152 ,  B29C2045/1659 ,  B29K2059/00 ,  B29K2077/00 ,  B29K2221/003 ,  Y10T428/31725 ,  B29K2021/003 ,  B29K2019/00

摘要： Composites are described, comprising polyacetal and at least one thermoplastic polyamide elastomer formed by a polyacetal molding which has been partially or completely coated with the thermoplastic polyamide elastomer or onto which one or more moldings composed of the thermoplastic polyamide elastomer have been directly molded. The composites are characterized in that the polyacetal and the thermoplastic polyamide elastomer have been bonded adhesively or cohesively to one another via injection of the polyamide elastomer onto the polyacetal molding, and in that the tensile bond strength between the polyacetal and the thermoplastic polyamide elastomer is at least 0.5 N/mm2. The composites may be used as connectors, as functional components with integrated sealing properties and/or with integrated damping properties, or else as non-slip and easy-grip elements.

摘要翻译： 描述了包含聚缩醛和至少一种热塑性聚酰胺弹性体的复合材料，所述热塑性聚酰胺弹性体通过已经部分或完全地涂覆有热塑性聚酰胺弹性体的聚缩醛成型体形成，或者由热塑性聚酰胺弹性体组成的一个或多个模制品已被直接模塑。 复合材料的特征在于聚缩醛和热塑性聚酰胺弹性体通过将聚酰胺弹性体注入到聚缩醛成型体上而粘合地或内聚地粘合，并且聚缩醛和热塑性聚酰胺弹性体之间的拉伸粘合强度在 至少0.5N / mm 2。 复合材料可用作连接器，作为具有集成密封性能和/或具有整体阻尼性能的功能部件，或者作为防滑和易抓握元件。

公开(公告)号：US20060040120A1

公开(公告)日：2006-02-23

申请号：US10533984

申请日：2003-11-03

申请人： Ursula Ziegler ,  Klaus Kurz ,  Frank Reil

发明人： Ursula Ziegler ,  Klaus Kurz ,  Frank Reil

IPC分类号： B32B27/08 ,  B32B27/30 ,  B32B27/32

CPC分类号： B32B7/12 ,  B32B27/08 ,  B32B27/28 ,  B32B27/32 ,  B32B37/12 ,  B32B37/153 ,  B32B2250/05 ,  B32B2250/24 ,  B32B2323/04 ,  B32B2439/00 ,  B32B2553/00 ,  B32B2597/00 ,  Y10T428/31859 ,  Y10T428/31913 ,  Y10T428/31928 ,  Y10T428/31935 ,  Y10T428/31938

摘要： Composite products are described and encompass at least one polyacetal molding and at least one polyolefin molding, which have been bonded at at least one of their surfaces using an adhesion-promoting layer which is substantially composed of a copolymer or of a mixture of these which derives from at least one alpha-olefin and from at least one ethylenically unsaturated carboxylic acid, and/or from at least one ethylenically unsaturated carboxylic acid derivative, where the molar ratio of alpha-olefin to ethylenically unsaturated carboxylic acid and/or to ethylenically unsaturated carboxylic acid derivative is selected so as to obtain composites with a bond strength (measured by the tensile test at 23° C.) of at least 0.2 N/mm2. The composite products described can in particular be used for producing components which come into contact with fuels.

摘要翻译： 复合产品被描述并且包括至少一个聚缩醛模制品和至少一种聚烯烃模塑件，它们已使用基本上由共聚物或它们的混合物组成的粘合促进层在其至少一个表面上结合 来自至少一种α-烯烃和至少一种烯键式不饱和羧酸和/或至少一种烯属不饱和羧酸衍生物，其中α-烯烃与烯属不饱和羧酸和/或烯属不饱和羧酸的摩尔比 选择酸衍生物以获得具有至少0.2N / mm 2的粘合强度（通过23℃的拉伸试验测量）的复合材料。 所述的复合制品特别可用于制造与燃料接触的部件。

公开(公告)号：US08236430B2

公开(公告)日：2012-08-07

申请号：US10584745

申请日：2004-12-22

申请人： Ursula Ziegler ,  Frank Reil ,  Klaus Kurz

发明人： Ursula Ziegler ,  Frank Reil ,  Klaus Kurz

IPC分类号： B32B27/08 ,  B29B13/02 ,  C08G2/08

CPC分类号： B29C45/1676 ,  B29C45/1657 ,  B29C66/71 ,  B29C66/73152 ,  B29C2045/1659 ,  B29K2059/00 ,  B29K2077/00 ,  B29K2221/003 ,  Y10T428/31725 ,  B29K2021/003 ,  B29K2019/00

摘要： Composites are described, comprising polyacetal and at least one thermoplastic polyamide elastomer formed by a polyacetal molding which has been partially or completely coated with the thermoplastic polyamide elastomer or onto which one or more moldings composed of the thermoplastic polyamide elastomer have been directly molded. The composites are characterized in that the polyacetal and the thermoplastic polyamide elastomer have been bonded adhesively or cohesively to one another via injection of the polyamide elastomer onto the polyacetal molding, and in that the tensile bond strength between the polyacetal and the thermoplastic polyamide elastomer is at least 0.5 N/mm2. The composites may be used as connectors, as functional components with integrated sealing properties and/or with integrated damping properties, or else as non-slip and easy-grip elements.

摘要翻译： 描述了包含聚缩醛和至少一种热塑性聚酰胺弹性体的复合材料，所述热塑性聚酰胺弹性体通过已经部分或完全地涂覆有热塑性聚酰胺弹性体的聚缩醛成型体形成，或者由热塑性聚酰胺弹性体组成的一个或多个模制品已被直接模塑。 复合材料的特征在于聚缩醛和热塑性聚酰胺弹性体通过将聚酰胺弹性体注入到聚缩醛成型体上而粘合地或内聚地粘合，并且聚缩醛和热塑性聚酰胺弹性体之间的拉伸粘合强度在 至少0.5 N / mm2。 复合材料可用作连接器，作为具有集成密封性能和/或具有整体阻尼性能的功能部件，或者作为防滑和易抓握元件。

公开(公告)号：US07618714B2

公开(公告)日：2009-11-17

申请号：US10533984

申请日：2003-11-03

申请人： Ursula Ziegler ,  Klaus Kurz ,  Frank Reil

发明人： Ursula Ziegler ,  Klaus Kurz ,  Frank Reil

IPC分类号： B32B27/08 ,  B32B27/30 ,  B32B27/32

CPC分类号： B32B7/12 ,  B32B27/08 ,  B32B27/28 ,  B32B27/32 ,  B32B37/12 ,  B32B37/153 ,  B32B2250/05 ,  B32B2250/24 ,  B32B2323/04 ,  B32B2439/00 ,  B32B2553/00 ,  B32B2597/00 ,  Y10T428/31859 ,  Y10T428/31913 ,  Y10T428/31928 ,  Y10T428/31935 ,  Y10T428/31938

摘要： Composite products are described and encompass at least one polyacetal molding and at least one polyolefin molding, which have been bonded at at least one of their surfaces using an adhesion-promoting layer which is substantially composed of a copolymer or of a mixture of these which derives from at least one alpha-olefin and from at least one ethylenically unsaturated carboxylic acid, and/or from at least one ethylenically unsaturated carboxylic acid derivative, where the molar ratio of alpha-olefin to ethylenically unsaturated carboxylic acid and/or to ethylenically unsaturated carboxylic acid derivative is selected so as to obtain composites with a bond strength (measured by the tensile test at 23° C.) of at least 0.2 N/mm2.The composite products described can in particular be used for producing components which come into contact with fuels.

摘要翻译： 复合产品被描述并且包括至少一个聚缩醛模制品和至少一种聚烯烃模塑件，它们已使用基本上由共聚物或它们的混合物组成的粘合促进层在其至少一个表面上结合 来自至少一种α-烯烃和至少一种烯键式不饱和羧酸和/或至少一种烯属不饱和羧酸衍生物，其中α-烯烃与烯属不饱和羧酸和/或烯属不饱和羧酸的摩尔比 选择酸衍生物以获得具有至少0.2N / mm 2的粘合强度（通过23℃下的拉伸试验测量）的复合材料。 所述的复合制品特别可用于制造与燃料接触的部件。

公开(公告)号：US20070166561A1

公开(公告)日：2007-07-19

申请号：US10584746

申请日：2004-12-22

申请人： Ursula Ziegler ,  Frank Reil ,  Klaus Kurz

发明人： Ursula Ziegler ,  Frank Reil ,  Klaus Kurz

IPC分类号： B32B27/36

CPC分类号： B29C45/1676 ,  B29C45/1657 ,  B29C2045/1659 ,  B29K2059/00 ,  B29K2221/003 ,  Y10T428/31786 ,  Y10T428/31942

摘要： Composites are described, comprising polyacetal and at least one thermoplastic polyester elastomer formed by a polyacetal molding which has been partially or completely coated with the thermoplastic polyester elastomer or onto which one or more moldings composed of the thermoplastic polyester elastomer have been directly molded. The composites are characterized in that the polyacetal and the thermoplastic polyester elastomer have been bonded adhesively or cohesively to one another via injection of the thermoplastic polyester elastomer onto the polyacetal molding, and in that the tensile bond strength between the polyacetal and the thermoplastic polyester elastomer is at least 0.5 N/mm2. The composites may be used as connectors, as functional components with integrated sealing properties and/or with integrated damping properties, or else as non-slip and easy-grip elements.

摘要翻译： 描述了包含聚缩醛和至少一种热塑性聚酯弹性体的复合材料，所述热塑性聚酯弹性体通过已经部分或完全地涂覆有热塑性聚酯弹性体的聚缩醛成型体形成，或者由热塑性聚酯弹性体组成的一个或多个模制品已被直接模制。 复合材料的特征在于聚缩醛和热塑性聚酯弹性体通过将热塑性聚酯弹性体注入到聚缩醛成型体上而粘合或粘合，并且聚缩醛和热塑性聚酯弹性体之间的拉伸粘合强度为 至少0.5N / mm 2。 复合材料可用作连接器，作为具有集成密封性能和/或具有整体阻尼性能的功能部件，或者作为防滑和易抓握元件。

公开(公告)号：US07858202B2

公开(公告)日：2010-12-28

申请号：US11576309

申请日：2005-09-28

申请人： Marco Prigandt ,  Frank Reil ,  Ursula Ziegler ,  Werner Aumüller ,  Uwe Stenglin ,  Bernhard Ulmer

发明人： Marco Prigandt ,  Frank Reil ,  Ursula Ziegler ,  Werner Aumüller ,  Uwe Stenglin ,  Bernhard Ulmer

IPC分类号： B32B27/08 ,  B32B27/30 ,  B32B27/32 ,  B32B27/42 ,  B29C45/14

CPC分类号： B29C45/1676 ,  B29C45/1657 ,  B29K2059/00 ,  B29K2221/003 ,  B32B25/08 ,  Y10T428/31507 ,  Y10T428/31594 ,  Y10T428/31761 ,  Y10T428/31786 ,  Y10T428/31833 ,  Y10T428/31859 ,  Y10T428/31942

摘要： Composite bodies, processes for making them, and their uses are disclosed, the composite bodies comprising a polyacetal portion and a modified thermoplastic vulcanizate portion bonded together, wherein the modified thermoplastic vulcanizate portion comprises a modified thermoplastic vulcanizate elastomer having a hardness of 30 to 90 Shore A and wherein the modified thermoplastic vulcanizate elastomer comprises: (a) 2 to 75% by weight of an at least partially crosslinked ethylene-propylene-diene rubber in from 1 to 50% by weight of a polyolefinic matrix further comprising 0.05 to 10% by weight of an ingredient selected from the group consisting of stabilizers, crosslinking aids, and mixtures thereof; (b) 1 to 30% by weight of a compatibilizer; and (c) 10 to 70% by weight of a non-olefinic thermoplastic material, all percentages by weight based on a total weight of the modified thermoplastic vulcanizate elastomer.

摘要翻译： 公开了复合体，其制造方法及其用途，所述复合体包含聚缩醛部分和改性热塑性硫化橡胶部分结合在一起，其中改性热塑性硫化橡胶部分包含硬度为30〜90 Shore的改性热塑性硫化橡胶弹性体 A，其中所述改性的热塑性硫化橡胶弹性体包含：（a）2至75重量％的至少部分交联的乙烯 - 丙烯 - 二烯橡胶，其含量为1-50重量％的聚烯烃基体，还包含0.05至10重量％ 选自稳定剂，交联助剂及其混合物的成分的重量; （b）1〜30重量％的增容剂; 和（c）10至70重量％的非烯烃热塑性材料，所有重量百分数均为改性热塑性硫化橡胶弹性体的总重量。

公开(公告)号：US20070264514A1

公开(公告)日：2007-11-15

申请号：US11576309

申请日：2005-09-28

申请人： Marco Prigandt ,  Frank Reil ,  Ursula Ziegler ,  Werner Aumuller ,  Uwe Stenglin ,  Bernhard Ulmer

发明人： Marco Prigandt ,  Frank Reil ,  Ursula Ziegler ,  Werner Aumuller ,  Uwe Stenglin ,  Bernhard Ulmer

IPC分类号： B29C45/18 ,  C08L53/02

CPC分类号： B29C45/1676 ,  B29C45/1657 ,  B29K2059/00 ,  B29K2221/003 ,  B32B25/08 ,  Y10T428/31507 ,  Y10T428/31594 ,  Y10T428/31761 ,  Y10T428/31786 ,  Y10T428/31833 ,  Y10T428/31859 ,  Y10T428/31942

摘要： Composite bodies, processes for making them, and their uses are disclosed, the composite bodies comprising a polyacetal portion and a modified thermoplastic vulcanizate portion bonded together, wherein the modified thermoplastic vulcanizate portion comprises a modified thermoplastic vulcanizate elastomer having a hardness of 30 to 90 Shore A and wherein the modified thermoplastic vulcanizate elastomer comprises: (a) 2 to 75% by weight of an at least partially crosslinked ethylene-propylene-diene rubber in from 1 to 50% by weight of a polyolefinic matrix further comprising 0.05 to 10% by weight of an ingredient selected from the group consisting of stabilizers, crosslinking aids, and mixtures thereof; (b) 1 to 30% by weight of a compatibilizer; and (c) 10 to 70% by weight of a non-olefinic thermoplastic material, all percentages by weight based on a total weight of the modified thermoplastic vulcanizate elastomer.

摘要翻译： 公开了复合体，其制造方法及其用途，所述复合体包含聚缩醛部分和改性热塑性硫化橡胶部分结合在一起，其中改性热塑性硫化橡胶部分包含硬度为30〜90 Shore的改性热塑性硫化橡胶弹性体 A，其中所述改性的热塑性硫化橡胶弹性体包含：（a）2至75重量％的至少部分交联的乙烯 - 丙烯 - 二烯橡胶，其含量为1-50重量％的聚烯烃基体，还包含0.05至10重量％ 选自稳定剂，交联助剂及其混合物的成分的重量; （b）1〜30重量％的增容剂; 和（c）10至70重量％的非烯烃热塑性材料，所有重量百分数均为改性热塑性硫化橡胶弹性体的总重量。

公开(公告)号：US07247665B1

公开(公告)日：2007-07-24

申请号：US10088656

申请日：2000-09-01

申请人： Carsten Woerner ,  Ursula Ziegler ,  Kurt Witan ,  Klaus Kurz

发明人： Carsten Woerner ,  Ursula Ziegler ,  Kurt Witan ,  Klaus Kurz

IPC分类号： C08K5/3432 ,  C08K3/20 ,  C08K5/053

CPC分类号： C08L59/02 ,  C08K3/22 ,  C08K5/3435 ,  C08K5/34922 ,  C08K5/34928 ,  C08K2003/2296 ,  C08L59/00 ,  C08L59/04 ,  C08L71/02 ,  C08L2666/22 ,  C08L2666/16

摘要： Polyoxymethylene with improved resistance to acids, comprising A from 84 to 99.79% by weight of at least one polyoxymethylene homo- or copolymer, B from 0.1 to 5% by weight of at least one polyalkylene glycol, C from 0.1 to 10% by weight of zinc oxide, and D from 0.01 to 1% by weight of one or more nitrogen-containing costabilizers, where the total of the percentages by weight of components A to D is 100%. This polyoxymethylene is particularly advantageous when used for producing moldings for use in contact with aggressive acids or with aggressive acid-containing cleaning agents, in particular for applications in the sanitary sector or the white goods sector.

摘要翻译： 具有改善的耐酸性的聚甲醛，包含A为84至99.79重量％的至少一种聚甲醛均聚物或共聚物，B为0.1至5重量％的至少一种聚亚烷基二醇，C为0.1至10重量％ 氧化锌和D为0.01至1重量％的一种或多种含氮成本稳定剂，其中组分A至D的重量百分比的总和为100％。 当用于生产用于与腐蚀性酸或含腐蚀性酸的清洁剂接触的模制品时，该聚氧化亚胺是特别有利的，特别是用于卫生领域或白色家电领域的应用。