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    Hemispherands and sodium-selective compositions and electrodes containing same
    2.
    发明授权
    Hemispherands and sodium-selective compositions and electrodes containing same 失效
    半球和钠选择性组合物和含有它们的电极

    公开(公告)号：US4476007A

    公开(公告)日：1984-10-09

    申请号：US496740

    申请日：1983-05-20

    申请人： John L. Toner ,  Daniel S. Daniel ,  Susan M. Geer

    发明人： John L. Toner ,  Daniel S. Daniel ,  Susan M. Geer

    IPC分类号： C07D273/01 ,  C07D498/22 ,  G01N27/333 ,  G01N27/30

    CPC分类号： C07D498/22 ,  G01N27/3335

    摘要： Ion-selective compositions which comprise an ion carrier, a compound capable of solvating the ion carrier, and a supporting matrix are disclosed.The ion carriers of this invention are hemispherand compounds represented by the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently hydrogen, alkyl, alkenyl, cycloalkyl, aryl or a heterocyclic group; and X is benzyl or an electron donating group capable of forming at least one coordinating site for sodium ions. A preferred hemispherand according to this invention is 2'-benzyloxy-3,3"-[2,6-pyridylenebis(methyleneoxymethylene)]-2,2"-tetramethylenedioxy-5,5',5"-trimethyl-1,1':3',1"-terphenyl. These compounds and the compositions containing same are particularly useful in ion-selective electrodes. Such an electrode is capable of selectively transporting sodium ions in preference to other cations. Dry-operative electrodes using these ion-selective compositions as membranes are also disclosed.

    摘要翻译： 公开了包含离子载体，能够溶剂化离子载体的化合物和支持基质的离子选择性组合物。 本发明的离子载体是由下式表示的半胱氨酸化合物，其中R 1，R 2，R 3和R 4独立地为氢，烷基，烯基，环烷基，芳基或杂环基; X是苄基或能形成钠离子的至少一个配位部位的给电子基团。 根据本发明的优选的半球是2'-苄氧基-3,3“ - [2,6-亚吡啶基二（亚甲氧基亚甲基）] - 2,2” - 叔亚甲基二氧基-5,5'，5“ - 三甲基 - 1,1'：3'，1“ - 三联苯。 这些化合物和含有它们的组合物在离子选择性电极中特别有用。 这种电极能够选择性地输送钠离子优于其它阳离子。 还公开了使用这些离子选择性组合物作为膜的干手术电极。

    Hemispherands in ion-selective compositions
    3.
    发明授权
    Hemispherands in ion-selective compositions 失效
    离子选择性组合物中的半球

    公开(公告)号：US4933070A

    公开(公告)日：1990-06-12

    申请号：US873017

    申请日：1986-06-11

    申请人： John L. Toner ,  Daniel S. Daniel

    发明人： John L. Toner ,  Daniel S. Daniel

    IPC分类号： G01N27/333

    CPC分类号： G01N27/3335

    摘要： Ion-selective compositions which comprise an ion carrier, a compound capable of solvating the ion carrier, and a supporting matrix are disclosed. The ion carrier according to the invention is a lipophilic hemispherand compound. These compositions are particularly useful in ion-selective electrodes. Such an electrode is capable of selectively transporting a first ion in preference to a second ion. Particularly useful hemispherands have a .DELTA.G of complexation with the first ion which is at least 0.3 Kcal/mole greater than the .DELTA.G of complexation with the second ion. Dry-operative electrodes using these ion-selective compositions as membranes are also disclosed.

    摘要翻译： 公开了包含离子载体，能够溶剂化离子载体的化合物和支持基质的离子选择性组合物。 根据本发明的离子载体是亲脂半胱氨酸化合物。 这些组合物特别适用于离子选择性电极。 这样的电极能够优选选择性地输送第一离子而不是第二离子。 特别有用的半球具有与第一离子络合的DELTA G，其比与第二离子络合的DELTA G高至少0.3Kcal /摩尔。 还公开了使用这些离子选择性组合物作为膜的干手术电极。

    Sodium-selective compositions and electrodes containing same
    4.
    发明授权
    Sodium-selective compositions and electrodes containing same 失效
    钠选择性组合物和含有它们的电极

    公开(公告)号：US4505800A

    公开(公告)日：1985-03-19

    申请号：US496738

    申请日：1983-05-20

    申请人： John L. Toner ,  Daniel S. Daniel

    发明人： John L. Toner ,  Daniel S. Daniel

    IPC分类号： G01N27/333 ,  G01N27/30

    CPC分类号： G01N27/3335

    摘要： Ion-selective compositions which comprise an ion carrier, a compound capable of solvating the ion carrier, and a supporting matrix are disclosed. The ion carrier useful in this invention is a hemispherand compound represented by the structure: ##STR1## wherein X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are independently alkyl or alkenyl, or any one of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 is taken with one of the others of X.sub.1, X.sub.2, X.sub.3 and X.sub.4 to form an alkylene group or an alkylene group interrupted with hetero atoms; and R represents the atoms necessary to complete a macrocyclic ring structure having from 16 to 19 atoms in the backbone of the ring structure, with the proviso that R contains (a) at least one coordinating site for sodium ions and (b) at least two alkylene groups as part of the ring structure. These compounds and the compositions containing same are particularly useful in ion-selective electrodes. Such an electrode is capable of selectively transporting sodium ion in preference to other cations. Dry-operative electrodes using these ion-selective compositions as membranes are also disclosed.

    摘要翻译： 公开了包含离子载体，能够溶剂化离子载体的化合物和支持基质的离子选择性组合物。 可用于本发明的离子载体是由以下结构表示的半胱氨酸化合物：其中X 1，X 2，X 3和X 4独立地为烷基或烯基，或者X 1，X 2，X 3和X 4中的任一个与 X 1，X 2，X 3，X 4的其它基团，形成亚烷基或被杂原子间隔的亚烷基; R表示在环结构的主链中完成具有16至19个原子的大环环结构所必需的原子，条件是R包含（a）至少一个钠离子的配位点和（b）至少两个 亚烷基作为环结构的一部分。 这些化合物和含有它们的组合物在离子选择性电极中特别有用。 这样的电极能够选择性地输送钠离子优于其它阳离子。 还公开了使用这些离子选择性组合物作为膜的干手术电极。

    Potassium ion-selective compositions and electrodes containing same
    7.
    发明授权
    Potassium ion-selective compositions and electrodes containing same 失效
    钾离子选择性组合物和含有它们的电极

    公开(公告)号：US4608149A

    公开(公告)日：1986-08-26

    申请号：US781364

    申请日：1985-09-30

    申请人： Daniel S. Daniel ,  Thomas R. Kissel

    发明人： Daniel S. Daniel ,  Thomas R. Kissel

    IPC分类号： G01N27/333 ,  G01N27/46

    CPC分类号： G01N27/3335 ,  G01N2410/10

    摘要： Potassium ion-selective compositions which comprise valinomycin and a particular carrier solvent capable of solvating valinomycin are disclosed. The carrier solvent is a dicarboxylic acid diester having at least 25 carbon atoms, a viscosity of less than about 120 centipoise at 20.degree. C. and a boiling point greater than about 170.degree. C. at 5 mm pressure. A preferred carrier solvent is diisodecyl phthalate. Membranes prepared from these compositions preferably have a glass transition temperature greater than about -50.degree. C. These membranes are particularly useful in dry-operative potassium ion-selective electrodes which are capable of selectively determining potassium ions in preference to other ions.

    摘要翻译： 公开了包含缬氨霉素和能够溶剂化缬氨霉素的特定载体溶剂的钾离子选择性组合物。 载体溶剂是具有至少25个碳原子的二羧酸二酯，在20℃下的粘度小于约120厘泊，在5mm压力下的沸点大于约170℃。 优选的载体溶剂是邻苯二甲酸二异癸酯。 由这些组合物制备的膜优选具有大于约-50℃的玻璃化转变温度。这些膜特别适用于能干燥操作的钾离子选择性电极，其能够优选选择性地测定其它离子中的钾离子。

    Thermally responsive battery charger
    8.
    发明授权
    Thermally responsive battery charger 失效
    热敏电池充电器

    公开(公告)号：US5013993A

    公开(公告)日：1991-05-07

    申请号：US237962

    申请日：1988-08-29

    申请人： Pradeep M. Bhagwat ,  Daniel S. Daniel ,  Samuel G. Woods

    发明人： Pradeep M. Bhagwat ,  Daniel S. Daniel ,  Samuel G. Woods

    IPC分类号： H02J7/00

    CPC分类号： H02J7/0091

    摘要： A battery charger 10 includes a capacitor 20 which establishes a level of current sufficient to fast charge in one-hour a battery 18 having from one to twenty cells. An SCR 16 is controlled by a timer 42 to initially delay the supply of current while determining whether the battery 18 is hot or cool. If battery 18 is cool, charger 10 proceeds to fast charge the battery. After battery 18 is fully charged, the battery heats to a temperature where a NTC thermistor 58 responds to trigger a second timer 52 which controls SCR 16 to stop the fast charging operation. Charger 10 is then controlled to prevent the charger from thereafter re-entering a fast charge mode.If battery 18 is initially hot, charger 10 is controlled to further delay the initiation of a fast charge operation until the battery cools to or below the charge-start temperature.A second NTC thermistor 90 is provided to compensate for the potential effect on the operation of thermistor 58 in response to temperature levels emanating from any environment other than from battery 18.

    摘要翻译： 电池充电器10包括电容器20，电容器20建立足够电流的电流，该电流足以在一个小时内快速充电，电池18具有一至二十个电池。 定时器42控制SCR16，以便在确定电池18是热还是冷却的同时最初延迟电流供应。 如果电池18是冷却的，充电器10继续对电池进行快速充电。 在电池18充满电后，电池加热到NTC热敏电阻58响应的温度，触发控制SCR 16停止快速充电操作的第二定时器52。 然后控制充电器10以防止充电器此后重新进入快速充电模式。 如果电池18最初是热的，则控制充电器10进一步延迟快速充电操作的启动，直到电池冷却到或低于充电开始温度。 第二NTC热敏电阻90被提供以补偿响应于从电池18以外的任何环境发出的温度水平对热敏电阻58的操作的潜在影响。

    Compositions and elements containing triarylmethane leuco dyes and methods using same
    10.
    发明授权
    Compositions and elements containing triarylmethane leuco dyes and methods using same 失效
    含有三芳基甲烷无色染料的组合物和元素及其使用方法

    公开(公告)号：US4670385A

    公开(公告)日：1987-06-02

    申请号：US612509

    申请日：1984-05-21

    申请人： Bruce E. Babb ,  Daniel S. Daniel

    发明人： Bruce E. Babb ,  Daniel S. Daniel

    IPC分类号： G01N33/50 ,  C12Q1/00 ,  C12Q1/28

    CPC分类号： C12Q1/28 ,  C12Q2326/40 ,  Y10S435/805 ,  Y10T436/206664

    摘要： A particular class of triarylmethane leuco dyes are useful in analytical compositions, elements and methods. These leuco dyes are triarylmethane compounds having an aromatic heterocyclic moiety attached to the central methane carbon and which, upon interaction with hydrogen peroxide, provide dyes having a maximum absorption at a wavelength equal to or greater than about 600 nm. Particularly useful leuco dyes have the structure: ##STR1## wherein R is a 5- to 15-membered aromatic heterocyclic moiety; and R' and R" are independently open chain or cyclic amines. These compounds are useful for providing detectable dyes in compositions and elements useful for detection of hydrogen peroxide or other analytes which react to produce hydrogen peroxide in aqueous liquids, e.g. biological fluids.

    摘要翻译： 特定类型的三芳基甲烷无色染料可用于分析组合物，元素和方法。 这些无色染料是具有连接到中心甲烷碳上的芳族杂环部分的三芳基甲烷化合物，并且在与过氧化氢相互作用时提供在等于或大于约600nm的波长处具有最大吸收的染料。 特别有用的无色染料具有以下结构：其中R是5至15元芳族杂环部分; 且R'和R“独立地为开链或环状胺。 这些化合物可用于在用于检测过氧化氢或其它分析物的组合物和元件中提供可检测的染料，所述分析物在含水液体中产生过氧化氢反应。 生物体液。