Low loss chalcogenide glass fiber
    2.
    发明授权
    Low loss chalcogenide glass fiber 有权
    低损耗硫族化物玻璃纤维

    公开(公告)号:US07807595B2

    公开(公告)日:2010-10-05

    申请号:US12183095

    申请日:2008-07-31

    IPC分类号: C03C3/32 C03C13/04

    摘要: This invention pertains to a chalcogenide glass of low optical loss that can be on the order of 30 dB/km or lower, and to a process for preparing the chalcogenide glass. The process includes the steps of optionally preparing arsenic monochalcogenide precursor or the precursor can be provided beforehand; dynamically distilling the precursor in an open system under vacuum from a hot section to a cold section to purify same; homogenizing the precursor in a closed system so that it is of a uniform color; disposing the distilled or purified precursor and at least one chalcogenide element at a hot section of an open distillation system; dynamically distilling under vacuum in an open system so that the precursor and the at least one chalcogenide element are deposited at a cold section of the open system in a more purified state; homogenizing the precursor and the at least chalcogenide element in a closed system while converting the precursor and the at least one chalcogenide element from crystalline phase to glassy phase.

    摘要翻译: 本发明涉及低光损耗的硫属化物玻璃,其数量级可以在30dB / km以下,以及制备硫族化物玻璃的方法。 该方法包括任选地制备砷单体前体的步骤,或者可以预先提供前体; 在开放系统中在真空下从热部分到冷部分动态蒸馏前体以净化其; 在封闭系统中使前体均匀化,使其具有均匀的颜色; 将蒸馏或纯化的前体和至少一种硫族化物元素置于开放蒸馏系统的热段; 在开放系统中在真空下动态蒸馏,使得前体和至少一种硫族化物元素以更纯化的状态沉积在开放系统的冷部分; 在将前体和至少一种硫属元素元素从结晶相转化为玻璃相的同时使封闭体系中的前体和至少硫属元素元素均化。

    Barium copper sulfur fluoride transparent conductive thin films and bulk material
    3.
    发明授权
    Barium copper sulfur fluoride transparent conductive thin films and bulk material 失效
    钡铜硫氟化物透明导电薄膜和散装材料

    公开(公告)号:US08158096B2

    公开(公告)日:2012-04-17

    申请号:US12250808

    申请日:2008-10-14

    IPC分类号: C01B9/00

    摘要: The present invention is generally directed to a bulk barium copper sulfur fluoride (BCSF) material made by combining Cu2S, BaS and BaF2, heating the ampoule between 400 and 550 ° C. for at least two hours, and then heating the ampoule at a temperature between 550 and 950 ° C. for at least two hours. The BCSF material may be doped with potassium, rubidium, or sodium. The present invention also provides for a BCSF transparent conductive thin film made by forming a sputter target by either hot pressing bulk BCSF or hot pressing Cu2S, BaS and BaF2 powders and sputtering a BCSF thin film from the target onto a substrate. The present invention is further directed to a p-type transparent conductive material comprising a thin film of BCSF on a substrate where the film has a conductivity of at least 1 S/cm. The substrate may be a plastic substrate, such as a polyethersulfone, polyethylene terephthalate, polyimide, or some other suitable plastic or polymeric substrate.

    摘要翻译: 本发明一般涉及通过组合Cu2S,BaS和BaF2制备的块状钡铜氟化硫(BCSF)材料,将安瓿在400和550℃之间加热至少2小时,然后在温度下加热安瓿 在550和950℃之间至少2小时。 BCSF材料可掺杂有钾,铷或钠。 本发明还提供了通过热压体BCSF或热压Cu2S,BaS和BaF2粉末形成溅射靶并将BCSF薄膜从靶溅射到衬底上而制成的BCSF透明导电薄膜。 本发明进一步涉及一种p型透明导电材料,其包括在衬底上的BCSF薄膜,其中该膜的导电率至少为1S / cm。 基底可以是塑料基底,例如聚醚砜,聚对苯二甲酸乙二醇酯,聚酰亚胺或一些其它合适的塑料或聚合物基材。

    Thermally stable IR transmitting chalcogenide glass
    4.
    发明授权
    Thermally stable IR transmitting chalcogenide glass 有权
    热稳定的红外透射硫族化物玻璃

    公开(公告)号:US07693388B1

    公开(公告)日:2010-04-06

    申请号:US12210467

    申请日:2008-09-15

    IPC分类号: G02B6/00 G02B6/02

    摘要: A thermally stable chalcogenide glass, a process for making the same, and an optical fiber drawn therefrom are provided. A chalcogenide glass having the composition Ge(5−y)As(32−x)Se(59+x)Te(4+y) (0≦y≦1 and 0≦x≦2) is substantially free from crystallization when it is heated past the glass transition temperature Tg or drawn into optical fibers. A process for making the thermally stable chalcogenide glass includes purifying the components to remove oxides and scattering centers, batching the components in a preprocessed distillation ampoule, gettering oxygen impurities from the mixture, and heating the components to form a glass melt. An optical fiber formed from the chalcogenide glass is substantially free from crystallization and exhibits low signal loss in the near-infrared region, particularly at wavelengths of about 1.55 μm.

    摘要翻译: 提供了热稳定的硫族化物玻璃,其制造方法和从其中提取的光纤。 具有Ge(5-y)As(32-x)Se(59 + x)Te(4 + y)(0≦̸ y≦̸ 1和0≦̸ x≦̸ 2)组成的硫族化物玻璃基本上没有结晶 被加热超过玻璃化转变温度Tg或拉制成光纤。 制造热稳定的硫族化物玻璃的方法包括纯化组分以除去氧化物和散射中心,将组分在预处理的蒸馏安瓿中进行配料,从混合物中吸收氧杂质,并加热组分以形成玻璃熔体。 由硫族化物玻璃形成的光纤基本上没有结晶,并且在近红外区域特别是在约1.55μm的波长下表现出低信号损失。

    Gas filled hollow core chalcogenide photonic bandgap fiber Raman device and method
    5.
    发明授权
    Gas filled hollow core chalcogenide photonic bandgap fiber Raman device and method 有权
    气体填充中空硫族化合物光子带隙光纤拉曼装置及方法

    公开(公告)号:US07327928B2

    公开(公告)日:2008-02-05

    申请号:US11532148

    申请日:2006-09-15

    IPC分类号: G02B6/02 G02B6/32 G02B6/00

    摘要: A hollow core photonic bandgap chalcogenide glass fiber includes a hollow core for passing light therethrough, a Raman active gas disposed in said core, a microstructured region disposed around said core, and a solid region disposed around said microstructured region for providing structural integrity to said microstructured region. A coupler can introduce at least one light signal into the hollow core of the chalcogenide photonic bandgap fiber. The method includes the steps of introducing a light beam into a hollow core chalcogenide photonic bandgap glass fiber filled with a Raman active gas disposed in the core, conveying the beam through the core while it interacts with the gas to form a Stokes beam of a typically higher wavelength, and removing the Stokes beam from the core of the fiber.

    摘要翻译: 中空核光子带隙硫族化物玻璃纤维包括用于使光通过的中空芯,设置在所述芯中的拉曼活性气体,设置在所述芯周围的微结构化区域,以及设置在所述微结构化区域周围的固体区域,用于向所述微结构化 地区。 耦合器可以将至少一个光信号引入到硫族化物光子带隙光纤的中空芯中。 该方法包括以下步骤:将光束引入填充有设置在芯中的拉曼活性气体的中空核心硫族化物光子带隙玻璃纤维中,在与气体相互作用的同时将光束输送通过芯体,以形成典型的斯托克斯光束 更高的波长,并从纤芯的核心去除斯托克斯光束。