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公开(公告)号：US5900517A
公开(公告)日：1999-05-04
申请号：US695400
申请日：1996-08-12
IPC分类号： B01J27/16 , B01J31/22 , C07B61/00 , C07C2/00 , C07C13/28 , C07C13/32 , C07C13/36 , C07C13/39 , C07C13/45 , C07C13/47 , C07C13/52 , C07C13/615 , C07C1/32
CPC分类号： C07C13/32 , C07C13/52 , C07C2102/14 , C07C2102/30 , C07C2102/32
摘要： Cyclopentadienyl derivatives are described having general formula (I) ##STR1## where R, R.sub.1, R.sub.2, R.sub.4, equivalent to or different from one another, are selected from: --H, alkyl radicals having a number of carbon atoms from 1 to 5, cycloalkyl radicals having a number of carbon atoms from 5 to 8, aryl and alkylaryl radicals having a number of carbon atoms from 6 to 8, aralkyl radicals having a number of carbon atoms from 7 to 9; n is an integer from 2 to 18; with the proviso that the number of R different from H does not exceed 2; with the exclusion of the compound having n=3, R.dbd.R.sub.1 .dbd.R.sub.2 .dbd.R.sub.4 .dbd.H. The invention a-so describes the process for the preparation of the above-mentioned cyclopentadienyl derivatives.
摘要翻译： 描述了具有通式（I）的环戊二烯基衍生物，其中R，R 1，R 2，R 4彼此相当或不同，选自：-H，具有1至5个碳原子数的烷基，环烷基具有 5至8个碳原子数，6至8个碳原子数的芳基和烷芳基，7至9个碳原子的芳烷基; n是2至18的整数; 条件是与H不同的R数不超过2; 排除n = 3的化合物，R = R 1 = R 2 = R 4 = H。 本发明a-描述了制备上述环戊二烯基衍生物的方法。
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公开(公告)号：US06139484A
公开(公告)日：2000-10-31
申请号：US729302
申请日：1996-10-10
IPC分类号： C07C2/56 , B01J29/04 , C07C2/86 , C07C13/32 , C07C13/44 , C07C13/465 , C07C13/47 , C07C13/52 , C07C13/567 , C07F7/02 , C07F7/08
CPC分类号： C07F7/0818 , C07C13/32 , C07C2102/22 , C07C2102/24 , C07C2102/26 , C07C2102/32
摘要： Bridged cyclopentadienyl derivatives having general formula (I)A--X--B (I)wherein:1) A is a monofunctional hydrocarbyl radical having general formula (II) ##STR1## 2) --X-- is the bridge between A and B and consists of a bifunctional radical selected from an alkylene group, a silanylene group, an alkyl substituted silaalkylene group, a siloxasilanylene group;3) B is a monofunctional hydrocarbyl radical selected from:e) any of the A radicals defined above,f) a cyclopentadienyl radical.
摘要翻译： 具有通式（I）AXB（I）的桥连环戊二烯基衍生物其中：1）A是具有通式（II）的单官能烃基2）-X-是A和B之间的桥，由双官能基团组成， 亚烷基，亚硅烷基，烷基取代的硅亚烷基，硅氧烷亚苯基; 3）B是选自以下的单官能烃基：e）上文定义的任何A基团，f）环戊二烯基。
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公开(公告)号：US5917072A
公开(公告)日：1999-06-29
申请号：US761140
申请日：1996-12-06
IPC分类号： C07F17/00 , C08F4/60 , C08F4/602 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F210/00 , C08F210/06 , C08F210/16 , C08F210/18 , C07F7/00
CPC分类号： C08F210/16 , C07F17/00 , C08F210/18 , C08F210/06 , C08F4/65908 , C08F4/65912 , C08F4/65925 , Y10S526/943
摘要： A description follows of catalysts of the metallocene type which can be used in the (co)polymerization of alpha-olefins, particularly in the preparation of elastomeric copolymers of ethylene.
摘要翻译： 以下描述可用于α-烯烃的（共）聚合的茂金属型催化剂，特别是在制备乙烯的弹性体共聚物中。
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4.发明授权Metallocenes, their preparation and use in the polymerization of alpha-olefins 失效金属茂，它们的制备和在α-烯烃聚合中的应用
公开(公告)号：US5948873A
公开(公告)日：1999-09-07
申请号：US994568
申请日：1997-12-19
IPC分类号： C07F17/00 , C08F2/18 , C08F4/18 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/06 , C07F7/00
CPC分类号： C07F17/00 , C08F10/00 , C08F210/06 , C08F4/65908 , C08F4/65912 , Y10S526/943
摘要： Catalytic component for the copolymerization of ethylene with alpha-olefins having general formula (I): ##STR1## wherein: A is a cyclopentadienyl derivative having general formula (II) ##STR2## B is selected from: 1) any of the cyclopentadienyl derivatives A defined above2) a monofunctional cyclopentadienyl radical (F) selected from cyclopentadienyl, indenyl, fluorenyl and the relative alkyl, aryl, trialkylsilyl substituted derivatives;Q, a bridge between A and B, is a bifunctional radical.
摘要翻译： 用于使乙烯与具有通式（I）的α-烯烃共聚的催化组分：其中：A是具有通式（II）的环戊二烯基衍生物B选自：1）任何上述定义的环戊二烯基衍生物A 2）单官能 环戊二烯基（F）选自环戊二烯基，茚基，芴基和相对烷基，芳基，三烷基甲硅烷基取代的衍生物; Q，A和B之间的桥梁是一个双功能的激进。
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公开(公告)号：US06211110B1
公开(公告)日：2001-04-03
申请号：US09262318
申请日：1999-03-04
申请人： Roberto Santi , Giampietro Borsotti , Gianfranco Longhini , Paolo Biagini , Antonio Proto , Francesco Masi , Viviano Banzi
发明人： Roberto Santi , Giampietro Borsotti , Gianfranco Longhini , Paolo Biagini , Antonio Proto , Francesco Masi , Viviano Banzi
IPC分类号： B01J2100
CPC分类号： C07F17/00 , C07C13/465 , C07C2602/08 , C08F4/65908 , C08F4/65912 , C08F10/02 , C08F210/16 , C08F210/18 , Y10S526/943 , C08F4/65927 , C08F210/14 , C08F2500/03 , C08F210/06 , C08F2500/17 , C08F2500/13 , C08F2500/25 , C08F2500/15
摘要： A “bridged” bis-cyclopentadienyl complex which can be advantageously used for the formation of a catalytic system active in the (co)polymerization of ethylene and other &agr;-olefins is represented by means of the following formula (II): wherein: M represents a metal selected from titanium, zirconium or hafnium; A′ and A″ each independently represent an anion containing an &eegr;5-cyclopentadienyl ring coordinated to M; R′ or R″ each independently represents a group of an anionic nature a-bound to the metal M; B represents an unsaturated bivalent organic residue having from 1 to 30 carbon atoms, bound, respectively, to the ring of group A′ and to the —CH2— methylene group by means of carbon atoms. This complex, combined with a suitable cocatalyst, forms a catalyst with a high activity in the polymerization of olefins, producing polymers with a high molecular weight, especially in the case of the copolymerization of ethylene with a second &agr;-olefin.
摘要翻译： 可以有利地用于形成在乙烯和其它α-烯烃的（共）聚合中活化的催化体系的“桥接”双环戊二烯基络合物通过下式（II）表示：其中：M表示 选自钛，锆或铪的金属; A'和A“各自独立地表示含有与M配位的η5-环戊二烯基环的阴离子; R'或R“各自独立地表示与金属M键合的阴离子性质的基团; B表示具有1至30个碳原子的不饱和二价有机残基，其分别通过碳原子与A'的环和-CH 2 - 亚甲基结合。 该络合物与合适的助催化剂组合形成了在烯烃聚合中具有高活性的催化剂，产生了具有高分子量的聚合物，特别是在乙烯与第二α-烯烃共聚的情况下。
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公开(公告)号：US6124413A
公开(公告)日：2000-09-26
申请号：US841396
申请日：1997-04-30
IPC分类号： C07F17/00 , C08F4/52 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F210/06 , C08F210/16 , C08F210/18 , C08F4/42
CPC分类号： C07F17/00 , C08F210/16 , C08F210/06 , C08F210/18 , C08F4/65908 , C08F4/65912 , C08F4/65927
摘要： Process for preparing elastomeric copolymers of ethylene-propylene (EPM) type and elastomeric terpolymers of ethylene-propylene-diene (EPDM) type with a propylene content comprised within the range of from 15 to 75%, carried out in the presence of metallocenes of formula (I) ##STR1##
摘要翻译： 制备乙烯 - 丙烯（EPM）型和乙烯 - 丙烯 - 二烯（EPDM）型弹性共聚物的弹性体共聚物的方法，丙烯含量为15-75％，丙烯含量在式 （一世）
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公开(公告)号：US06417418B2
公开(公告)日：2002-07-09
申请号：US09790570
申请日：2001-02-23
申请人： Roberto Santi , Giampietro Borsotti , Gianfranco Longhini , Paolo Biagini , Antonio Proto , Francesco Masi , Viviano Banzi
发明人： Roberto Santi , Giampietro Borsotti , Gianfranco Longhini , Paolo Biagini , Antonio Proto , Francesco Masi , Viviano Banzi
IPC分类号： C07C1300
CPC分类号： C07F17/00 , C07C13/465 , C07C2602/08 , C08F4/65908 , C08F4/65912 , C08F10/02 , C08F210/16 , C08F210/18 , Y10S526/943 , C08F4/65927 , C08F210/14 , C08F2500/03 , C08F210/06 , C08F2500/17 , C08F2500/13 , C08F2500/25 , C08F2500/15
摘要： A “bridged” bis-cyclopentadienyl complex which can be advantageously used for the formation of a catalytic system active in the (co)polymerization of ethylene and other &agr;-olefins is represented by means of the following formula (II): wherein: M represents a metal selected from titanium, zirconium or hafnium; A′ and A″ each independently represent an anion containing an &eegr;5-cyclopentadienyl ring coordinated to M; R′ or R″ each independently represents a group of an anionic nature &sgr;-bound to the metal M; B represents an unsaturated bivalent organic residue having from 1 to 30 carbon atoms, bound, respectively, to the ring of group A′ and to the —CH2-methylene group by means of carbon atoms. This complex, combined with a suitable cocatalyst, forms a catalyst with a high activity in the polymerization of olefins, producing polymers with a high molecular weight, especially in the case of the copolymerization of ethylene with a second &agr;-olefin.
摘要翻译： 可以有利地用于形成在乙烯和其它α-烯烃的（共）聚合中活化的催化体系的“桥接”双环戊二烯基络合物通过下式（II）表示：其中：M表示 选自钛，锆或铪的金属; A'和A“各自独立地表示含有与M配位的η5-环戊二烯基环的阴离子; R'或R“各自独立地表示与金属M结合的阴离子性质的一组基团; B表示具有1至30个碳原子的不饱和二价有机残基，分别通过碳原子与A'环结合，并与-CH 2 - 亚甲基结合。 该络合物与合适的助催化剂组合形成了在烯烃聚合中具有高活性的催化剂，产生了具有高分子量的聚合物，特别是在乙烯与第二α-烯烃共聚的情况下。
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8.发明授权Process for the preparation of N-alkyl substituted metal carbamate solutions and their use 失效制备N-烷基取代的金属氨基甲酸酯溶液及其用途的方法
公开(公告)号：US5808013A
公开(公告)日：1998-09-15
申请号：US677903
申请日：1996-07-10
申请人： Paolo Biagini , Gabriele Lugli , Fausto Calderazzo , Daniela Belli Dell'Amico , Alessandra Merigo
发明人： Paolo Biagini , Gabriele Lugli , Fausto Calderazzo , Daniela Belli Dell'Amico , Alessandra Merigo
IPC分类号： C07C269/06 , C07F5/00 , B01J31/00 , C07F7/00 , C07F9/00
CPC分类号： C07C269/06
摘要： Process for the preparation of N-alkyl substituted metal carbamate solutions characterized in that a water solution of the salt of the metal of which the corresponding carbamate is to be obtained, is reacted with an organic solution, basically consisting of an aprotic solvent and a secondary amine, saturated with carbon dioxide. The above solutions can be used as catalysts in polymerization reactions of unsaturated monomers or for supporting metals on inorganic oxides.
摘要翻译： 制备N-烷基取代的金属氨基甲酸酯溶液的方法，其特征在于将要得到相应氨基甲酸酯的金属盐的水溶液与基本上由非质子溶剂和仲 胺，饱和二氧化碳。 上述溶液可用作不饱和单体的聚合反应中的催化剂或用于在无机氧化物上负载金属的催化剂。
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公开(公告)号：US5627119A
公开(公告)日：1997-05-06
申请号：US383234
申请日：1995-02-03
申请人： Paolo Biagini , Gabriele Lugli , Fabio Garbassi , Piero Andreussi
发明人： Paolo Biagini , Gabriele Lugli , Fabio Garbassi , Piero Andreussi
IPC分类号： C08F36/06 , C08F4/52 , C08F4/54 , C08F4/60 , C08F4/626 , C08F36/00 , C08F36/04 , C08F136/04 , B01J31/14
CPC分类号： C08F36/04
摘要： A catalytic system to polymerize diolefinic monomers consists of a lanthanide salt, an organometallic compound of a metal belonging to groups I, II and III of the periodic table of elements and an organometallic compound of boron. The polymers obtained are characterized in that they have a high degree of 1,4 chain units and ratio between 1.4-cis/1,4-trans units which can vary as desired, and also a narrow molecular weight distribution.
摘要翻译： 聚合二烯单体的催化体系由镧系元素盐，属于元素周期表第I，II和III族的金属的有机金属化合物和硼的有机金属化合物组成。 所获得的聚合物的特征在于它们具有高度的1,4-链单元，并且可以根据需要变化的1,4-顺式/ 1,4-反式单元之间的比例以及窄的分子量分布。
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公开(公告)号：US5659101A
公开(公告)日：1997-08-19
申请号：US516285
申请日：1995-08-17
申请人： Paolo Biagini , Gabriele Lugli , Fabio Garbassi , Piero Andreussi
发明人： Paolo Biagini , Gabriele Lugli , Fabio Garbassi , Piero Andreussi
IPC分类号： C08F36/06 , C08F4/52 , C08F4/54 , C08F4/60 , C08F4/626 , C08F36/00 , C08F36/04 , C08F136/04 , C07C2/38
CPC分类号： C08F36/04
摘要： A catalytic system to polymerize diolefinic monomers consists of a lanthanide salt, an organometallic compound of a metal belonging to groups I, II and III of the periodic table of elements and an organometallic compound of boron. The polymers obtained are characterized in that they have a high degree of 1,4 chain units and ratio between 1.4-cis/1,4-trans units which can vary as desired, and also a narrow molecular weight distribution.
摘要翻译： 聚合二烯单体的催化体系由镧系元素盐，属于元素周期表第I，II和III族的金属的有机金属化合物和硼的有机金属化合物组成。 所获得的聚合物的特征在于它们具有高度的1,4-链单元，并且可以根据需要变化的1,4-顺式/ 1,4-反式单元之间的比例以及窄的分子量分布。
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