摘要:
Compounds of the formula ##STR1## WHEREIN Z is alkyl with 2 to 6 carbom atoms, x is oxygen, NH or sulfur, n and m are integers from 2 to 6, r is zero or 1, R.sup.4, R.sup.5 R.sup.6 and R.sup.7 are hydrogen or methyl and R.sup.3 is methyl, ethyl or phenyl. They are obtained by reacting 1 mole of a compound of formulaZ--(X--H).sub.nwith n.multidot.m moles of an alkylencoxide or alkylenecarbonate of the formulas ##STR2## and n(m+r) moles of a phospholane of formula ##STR3## These compounds are used as flameproofing agents especially for pile carpets.
摘要:
Compounds of the formula ##STR1## WHEREIN Z is alkyl with 2 to 6 carbon atoms, x is oxygen, NH or sulfur, n and m are integers from 2 to 6, r is zero or 1, R.sup.4, R.sup.5 R.sup.6 and R.sup.7 are hydrogen or methyl and R.sup.3 is methyl, ethyl or phenyl. They are obtained by reacting 1 mole of a compound of formulaZ--(X--H).sub.nwith n.m moles of an alkyleneoxide or alkylenecarbonate of the formulas ##STR2## and n(m+r) moles of a phospholane of formula ##STR3## These compounds are used as flameproofing agents especially for pile carpets.
摘要:
2-(Meth)acrylamido-2-methylpropanephosphonic acid is prepared by reaction of 2-methylprop-1-ene-1-phosphonic acid or 2-methylpro-2-ene-1-phosphonic acid with (meth)acrylonitrile in the presence of an equimolar amount of a strong acid. The compounds are suitable as such or in the form of their salts as comonomer for the manufacture of copolymers, which are used inter alia as dyeing auxiliaries and as scale inhibitors.
摘要:
A continuous process for the preparation of perfluorinated carbonyl fluorides from hexafluoropropene oxide (HFPO), in which HFPO is continuously oligomerized in a catalyst solution in devices which allow separation of the heavy product phase from the catalyst phase during the reaction, is described. Different oligomer distributions can be achieved by choice of the catalyst and different operating temperatures. The reaction itself takes place always in the substantial absence of the product which is formed, and achieves a considerable saving in time.
摘要:
A process for the preparation of the dimer of hexafluoropropene oxide (HFPO), in which the HFPO is dimerized in an aprotic polar solvent in the presence of a catalyst mixture, is described. The catalyst mixture is composed of a metal salt of the elements of the 1st transition metal series of the periodic table and of a tertiary diamine. By bringing in a molar ratio of metal salt to tertiary diamine in the range from 2:1 to 1:2, in particular 1:1, the selectivity for the dimeric compound is greatest, with high yields of the dimer being obtained.
摘要:
Herbicidal agents, containing as active ingredient a compound of the formula ##STR1## or their salts with acids, are useful for combatting a great variety of mono- and dicotyledonous weeds. In the formula R.sub.1 is methyl or halomethyl, R.sub.2 is OH, SH, OM or SM (M=equivalent of a base), R.sub.3 is the same as R.sub.2 or an ester, amide or hydrazide group, R.sub.4 and R.sub.5 are preferably hydrogen and X is oxygen or sulfur.
摘要:
Process for preparing cyclic phosphinic acid esters of the formula (I) ##STR1## wherein R.sub.1 is an alkyl radical having up to 18 carbon atoms or a phenyl radical being optionally substituted by alkyl, halogen or alkylated amino groups, R.sub.2 stands for a hydrogen atom or has the same meaning as R.sub.1 and n is 1 or 2, which comprises reacting phosphinic acid monoesters of the formula (II) ##STR2## wherein R.sub.3 is an alkyl radical having up to 8 carbon atoms optionally substituted by chlorine atoms and R.sub.1 has the meaning given above, with an alkenol of the formula (III) ##STR3## wherein R.sub.2 and n have the aforesaid meaning, in the presence of catalytic quantities of free radical forming agents, splitting off the alcohol of formula (IV)r.sub.3 oh (iv)simultaneously or subsequently and separating the reaction products, preferably by distillation.
摘要:
Curing component (A) based on polyisocyanates for binders (B) which contain groups containing active hydrogen, wherein the curing component (A) is a product of the reaction of (a1) polyisocyanates with (a2) .alpha.-hydroxyalkylpyridines.Mixtures of (A) and (B), and also, if appropriate, diluents (C) and additives (D), are stable on storage and give, even at temperatures of 120.degree.-140.degree. C., curing products which are sufficiently solvent-stable. They are suitable, in particular, for surface-coating preparations.
摘要:
The invention relates to aminourethanes essentially composed of structural units derived from (.alpha.) polyamines of the general formula (I) ##STR1## and of structural units derived from (.beta.) oligomeric or polymeric compounds which contain at least one terminal 2-oxo-1,3-dioxolane group.The invention further relates to a process for preparing these aminourethanes and to their use in particular in paint formulations.The aminourethanes according to the invention are suitable in particular for use as curable water-dispersible binders in particular for cationic electrocoating.
摘要:
Flame-repellant linear polyesters are obtained by incorporating by condensation phosphorus-compounds having the formula ##STR1## wherein R and R.sub.1 are organic radicals which may also contain hereto atoms into the linear polyesters, preferably those from terephthalic acid and ethylene glycol. These polyesters are materials of which flame-repellent filaments, fibers, sheets, press-moulded and injection-moulded articles may be made. Products of the invention can be used whereever especially acute risks of ignition and fire exist.