摘要:
Dimethyl carbonate is obtained pure, from its solutions in methanol, by extractive distillation carried out with a temperature of from 60.degree. C. at the top to 250.degree. C. at the bottom of the column and employing, as the extractant, an aprotic organic liquid which is substantially inert toward dimethyl carbonate, boils at above 100.degree. C. at standard pressure, is miscible with dimethyl carbonate in all proportions and has a dielectric constant .epsilon. of from 4 to 90 and a dipole moment .mu. of from 1.5 to 5 Debye.
摘要:
Unsaturated ketones of the formula ##STR1## and saturated ketones of the formula ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, alkyl of 1 to 12 carbon atoms or a cycloalkyl, aryl, aralkyl or alkylaryl radical which inturn may be substituted, or R.sup.1 and R.sup.3 or R.sup.2 and R.sup.3, together with the carbon atoms to which they are bonded, may form a cycloalkane, are prepared by a process in which a 5-methylene-1,3-dioxolanone which is substituted in the 4-position and is of the forumla ##STR3## where R.sup.1, R.sup.2 and R.sup.3 have the above meanings, (a) for the preparation of an unsaturated ketone, is converted in the presence of a zeolite, of a phosphate having a zeolite structure and/or of B, Ce, Fe, Zr or Sr phosphate as catalysts and (b) for the preparation of a saturated ketone, is converted in the presence of the same catalysts which additionally carry one or more hydrogenation components.
摘要:
Production of oxyalkylated acetylenic alcohols by reaction of acetylenic alcohols with alkylene oxides in the presence of phosphines, polar aprotic solvents or thioethers.
摘要:
A device and a method for preventing vibrations (19) in a rotating spindle (1) mounted in at least one front 8 and one rear bearing (9) in a machine tool, wherein the device comprises measuring units (2, 3, 4, 5) for detecting the vibrations (19) and correction device (6) for preventing the vibrations (19) disposed directly about the periphery (10, 11) of the spindle (1) in a contacting or non-contacting manner and that a control unit (7) for processing the measuring units (2, 3, 4, 5) and for calculating the correction values for the correction device (6) is assigned to this device.
摘要:
A device and a method for preventing vibrations (19) in a rotating spindle (1) mounted in at least one front 8 and one rear bearing (9) in a machine tool, wherein the device comprises measuring units (2, 3, 4, 5) for detecting the vibrations (19) and correction means (6) for preventing the vibrations (19) disposed directly about the periphery (10, 11) of the spindle (1) in a contacting or non-contacting manner and that a control unit (7) for processing the measuring units (2, 3, 4, 5) and for calculating the correction values for the correction means (6) is assigned to this device.
摘要:
1,4-Diazabicyclo[2.2.2]octane and C-substituted 1,4-diazabicyclo[2.2.2]octanes of the formula (I) ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or alkyl or alkenyl, each of 1 to 4 carbon atoms, are prepared from a heterocyclic amine of the formula (II) ##STR2## where R.sup.1 and R.sup.2 have the above meanings, R.sup.3 is hydrogen, hydroxyethyl or aminoethyl and X is hydroxyl or amino, in the presence of borosilicate and/or iron silicate zeolites as catalysts. Particularly suitable catalysts are the borosilicate and iron silicate zeolites of the pentasil type.
摘要:
Polymer mixtures consisting essentially ofA. a polyethylene with a melt index of above 15 g/10 min,B. a graft polymer of an ethylene/(meth)acrylic acid copolymer as graft substrate and grafted polymerized units of .epsilon.-caprolactam, andC. a poly-.epsilon.-caprolactam.
摘要:
The production of glycol monoesters of .alpha.,.beta.-unsaturated carboxylic acids of three or four carbon atoms and 1,2-diols of two to four carbon atoms by the reaction of acids with 1,2-alkylene oxides of two to four carbon atoms at elevated temperature in the presence of catalysts and polymerization initiators and also of molecular oxygen as an additional agent for suppressing polymerization.
摘要:
A shaft cooler (1) for a tool motor spindle (2), which has a rotating shaft (3), a static lance (4), and at least one coolant loop (7), which comprises a coolant inlet (5) and a coolant outlet (6), said shaft cooler being implemented such that the flow of the coolant from the static lance (4) into the rotating shaft (3) is performed via a flow path that includes radially-extending cooling holes (31) to cause the coolant to flow from a radially inside location to a radially outside location.
摘要:
Ketones of the formula ##STR1## where R.sup.1 to R.sup.3 are each hydrogen and R.sup.1 to R.sup.4 are each alkyl of 1 to 12 carbon atoms, cycloalkyl of 4 to 8 carbon atoms, aryl, aralkyl or alkylaryl, which each in turn may be substituted, or R.sup.1 and R.sup.2 and R.sup.3 together with the carbon atoms to which they are bonded form a cycloalkane, are prepared by reacting ketones of the formula ##STR2## where one of R.sup.1, R.sup.2, R.sup.3 and R.sup.5 is hydroxyl, alkoxy or carboxyl while the remaining R.sup.1 to R.sup.4 have the abovementioned meanings, with hydrogen in the presence of acid catalysts supporting one or more hydrogenation components, zeolites of the pentasil type being particularly suitable.