Degradation of organic compounds in effluents by wet oxidation
    1.
    发明授权
    Degradation of organic compounds in effluents by wet oxidation 失效
    通过湿氧化降解废水中的有机化合物

    公开(公告)号:US4124505A

    公开(公告)日:1978-11-07

    申请号:US748074

    申请日:1976-12-06

    IPC分类号: C02F1/74 C02F11/08 C02C5/04

    CPC分类号: C02F11/08

    摘要: In the degradation of organic compounds in an effluent by oxidizing the effluent at an elevated temperature with oxygen, the improvement which comprises effecting the oxidation at a redox potential of from about 300 to 600 millivolts, as measured with a platinum electrode against a silver-silver chloride electrode, at a temperature of from about 80.degree. to 250.degree. C and under a pressure of from about 30 to 200 bars. The redox potential may be maintained by an Fe.sup.2+ and/or Fe.sup.3+ ion system and the pH is advantageously below about 7.

    摘要翻译: 在用氧气在升高的温度下通过氧化流出物而在流出物中降解有机化合物,其改进包括用铂电极对银银测量的氧化还原电位为约300-600毫伏 氯化物电极,温度为约80-250℃,压力为约30至200巴。 氧化还原电位可以通过Fe 2+和/或Fe 3+离子系统保持,并且pH有利地低于约7。

    Diaminoalkyldiphenyl ethers, a process for their preparation and their
use
    4.
    发明授权
    Diaminoalkyldiphenyl ethers, a process for their preparation and their use 失效
    二氨基烷基二苯醚,其制备方法及其用途

    公开(公告)号:US4663484A

    公开(公告)日:1987-05-05

    申请号:US801527

    申请日:1985-11-25

    申请人: Walter Horstmann

    发明人: Walter Horstmann

    CPC分类号: C08G18/771

    摘要: New diaminoalkyldiphenyl ethers of the formula ##STR1## wherein R.sup.1 and R.sup.2 are identical or different and denote hydrogen or methyl, but R.sup.1 and R.sup.2 do not simultaneously represent methyl,are prepared by a process wherein alkyldiphenyl ethers of the formula ##STR2## wherein R.sup.1 and R.sup.2 have the above-mentioned meaning are acetylated, the diacetyl compounds obtained, in aqueous-alcoholic solution or suspension, are converted to the corresponding dioximes with hydroxylamine, the dried dioximes are subjected to a Beckmann rearrangement and thereafter the diacetylaminoalkyldiphenyl ethers formed are hydrolyzed by means of aqueous mineral acids or alkali metal hydroxide solutions to give the diamines.The new diaminoalkyldiphenyl ethers are used in the preparation of dyestuffs and polyurethanes and serve as monomers for the preparation of polymers.

    摘要翻译: 新的式(II)的二氨基烷基二苯基醚,其中R 1和R 2相同或不同并且表示氢或甲基,但R 1和R 2不同时表示甲基,其通式为其中R1和 R2具有上述含义是乙酰化的,在水溶液或悬浮液中获得的二乙酰基化合物用羟胺转化成相应的二肟,将干燥的二肟进行贝克曼重排,然后形成的二乙酰基氨基烷基二苯基醚被水解 含水无机酸或碱金属氢氧化物溶液的方法,得到二胺。 新的二氨基烷基二苯醚用于制备染料和聚氨酯,并用作制备聚合物的单体。