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公开(公告)号：US08624055B2
公开(公告)日：2014-01-07
申请号：US12598902
申请日：2008-05-01
申请人： Wayne P. Schammel , Bradley J. Huggins , Matthew A. Kulzick , Philip O. Nubel , Bryan M. Rabatic , Chengxiang Zhou , Victor A. Adamian , William H. Gong , Peter D. Metelski , Jeffrey T. Miller
发明人： Wayne P. Schammel , Bradley J. Huggins , Matthew A. Kulzick , Philip O. Nubel , Bryan M. Rabatic , Chengxiang Zhou , Victor A. Adamian , William H. Gong , Peter D. Metelski , Jeffrey T. Miller
IPC分类号： C07C51/16
CPC分类号： B01J23/6525 , B01J21/06 , B01J21/063 , B01J21/08 , B01J21/18 , B01J23/002 , B01J23/644 , B01J23/6445 , B01J23/686 , B01J35/0053 , B01J35/006 , B01J35/0066 , B01J37/0203 , B01J2523/00 , B01J2523/53 , B01J2523/68 , B01J2523/824 , C07C51/265 , C07C63/26 , B01J2523/19 , B01J2523/54
摘要： Catalytic compositions for conversion of substituted aromatic feed materials to oxidized products comprising aromatic carboxylic acid derivatives of the substituted aromatic feed materials comprise solid particles comprising palladium in combination with at least one of antimony, bismuth and gold, and optionally, an additional metal or metalloid component effective to promote activity or selectivity of the palladium and antimony, bismuth or gold for oxidation to aromatic carboxylic acids. A process for oxidizing substituted aromatic feed materials comprises contacting the feed material with oxygen in the presence of such catalytic compositions in a liquid reaction mixture.
摘要翻译： 用于将取代的芳族原料转化成包含取代的芳族原料的芳族羧酸衍生物的氧化产物的催化组合物包含与锑，铋和金中的至少一种结合的钯的固体颗粒，以及任选的另外的金属或准金属组分 有效地促进钯和锑，铋或金的氧化成芳族羧酸的活性或选择性。 用于氧化取代的芳族原料的方法包括在这种催化组合物存在下，在液体反应混合物中使进料与氧接触。
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公开(公告)号：US20100145094A1
公开(公告)日：2010-06-10
申请号：US12598902
申请日：2008-05-01
申请人： Wayne P. Schammel , Bradley J. Huggins , Matthew A. Kulzick , Philip O. Nubel , Bryan M. Rabatic , Chengxiang Zhou , Victor A. Adamian , William H. Gong , Peter D. Metelski
发明人： Wayne P. Schammel , Bradley J. Huggins , Matthew A. Kulzick , Philip O. Nubel , Bryan M. Rabatic , Chengxiang Zhou , Victor A. Adamian , William H. Gong , Peter D. Metelski
IPC分类号： B01J23/56 , B01J23/44 , B01J23/28 , B01J23/644 , C07C51/255 , C07C63/04 , C07C63/15
CPC分类号： B01J23/6525 , B01J21/06 , B01J21/063 , B01J21/08 , B01J21/18 , B01J23/002 , B01J23/644 , B01J23/6445 , B01J23/686 , B01J35/0053 , B01J35/006 , B01J35/0066 , B01J37/0203 , B01J2523/00 , B01J2523/53 , B01J2523/68 , B01J2523/824 , C07C51/265 , C07C63/26 , B01J2523/19 , B01J2523/54
摘要： Catalytic compositions for conversion of substituted aromatic feed materials to oxidized products comprising aromatic carboxylic acid derivatives of the substituted aromatic feed materials comprise solid particles comprising palladium in combination with at least one of antimony, bismuth and gold, and optionally, an additional metal or metalloid component effective to promote activity or selectivity of the palladium and antimony, bismuth or gold for oxidation to aromatic carboxylic acids. A process for oxidizing substituted aromatic feed materials comprises contacting the feed material with oxygen in the presence of such catalytic compositions in a liquid reaction mixture.
摘要翻译： 用于将取代的芳族原料转化成包含取代的芳族原料的芳族羧酸衍生物的氧化产物的催化组合物包含与锑，铋和金中的至少一种结合的钯的固体颗粒，以及任选的另外的金属或准金属组分 有效地促进钯和锑，铋或金的氧化成芳族羧酸的活性或选择性。 用于氧化取代的芳族原料的方法包括在这种催化组合物存在下，在液体反应混合物中使进料与氧接触。
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3.发明授权公开(公告)号：US07378544B2
公开(公告)日：2008-05-27
申请号：US10980718
申请日：2004-11-03
IPC分类号： C07C51/255 , B01J31/02 , B01J31/26
CPC分类号： B01J27/135 , B01J27/128 , C07C51/265 , C07C63/38 , C07C63/26 , C07C63/24 , C07C63/307
摘要： The present invention relates to the liquid phase oxidation of aromatic hydrocarbons in the presence of at least one heavy metal oxidation catalyst and bromine, which is activated by at least one of anthracene or another polycyclic aromatic compound to produce aromatic carboxylic acids.
摘要翻译： 本发明涉及在至少一种重金属氧化催化剂和溴的存在下芳族烃的液相氧化，其由至少一种蒽或其它多环芳族化合物活化以产生芳族羧酸。
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